On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes

Terrance completed his undergraduate degree (MChem (Hons)) at the University of Bath, England, in May 2011. His Masters project was carried out under the supervision of Prof. Micheal Hill, where his interest in the development of earth-abundant element complexes as catalyts was born. During his PhD studies with Prof. Cameron Jones at Monash University, Australia, Terrance briefly worked with Prof. Simon Aldridge, University of Oxford, as a visiting student. After completing his PhD in August 2015, he moved to work with Prof. Matthias Driess, TU Belin, as a postdoctoral Fellow of the UniCat Cluster of Excellence.

General Introduction.- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides.- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands.- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes.- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives.- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.