Silver Catalysis in Organic Synthesis
Wiley-VCH Verlag GmbH (Hersteller)
978-3-527-34282-2 (ISBN)
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Silver Catalysis in Organic Synthesis begins with an introduction to Silver Chemistry before moving on to chapters covering: Silver-Catalyzed Cycloaddition Reactions;
Silver-Catalyzed Cyclizations; Silver-Mediated Radical Reactions; Silver-Mediated Fluorination, Perfluoroalkylation and Trifluoromethylthiolation Reactions; Coupling Reactions and C-H Functionalization; Silver-Catalyzed CO2 Incorporation; Silver-Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions; Asymmetric Silver-Catalyzed Reactions; Silver-Catalyzed Reduction and Oxidation of Aldehydes and Their Derivatives; Silver Complexes in Organic Transformations; and Silver Nanoparticles in Organic Transformations.
-Covers recently developed organic reactions catalyzed by silver, along with their reaction mechanism
-Introduces many new reactions and mechanisms related to silver catalysis
-Offers professionals and newcomers in the related fields a survey of new advances in silver catalysis in organic synthesis
Silver Catalysis in Organic Synthesis will appeal to a wide readership including chemists, biochemists, pharmaceutical scientists, biomedical researchers, agriculture scientists, and graduate students in the related fields.
Chao-Jun Li, PhD, is E. B. Eddy Professor and Canada Research Chair in the Department of Chemistry at McGill University, Canada. Xihe Bi, PhD, is a Professor at Northeast Normal University, China, where he and his research team focus on making innovations in organic reactions by silver catalysis.
1. Introduction
This chapter is to introduce the development of silver catalysis and its history.
2. Radical reactions
2.1 Introduction
2.2 Radical phosphinylation
2.3 Radical cyclization
2.4 Radical addition
2.5 Radical Azidation
2.6 Conclusion
3. Activation of carbon-carbon triple bonds
3.1 Introduction
3.2 Formation of Carbon-Carbon Bonds
3.2.1 Alkynylation
3.2.1.1 Formation of Csp-Csp bonds
3.2.1.2 Formation of Csp2-Csp bonds
3.2.1.3 Formation of Csp3-Csp bonds
3.2.2 Cycloaddition and cyclization
3.2.3 Reactions via arynes
3.2.4 Cycloisomerization
3.2.5 Carbenoids
3.3 Formation of Carbon-Nitrogen Bonds
3.3.1 Intermolecular hydroamination
3.3.2 Intramolecular hydroamination
3.3.3 Cyclization
3.3.4 Cycloaddition
3.3.5 Azidation
3.3.6 Multicomponent Reactions
3.4 Formation of Carbon-Oxygen Bonds
3.4.1 Hydrofunctionalization
3.4.2 Carbonyl-yne cycloisomerization
3.4.3 CO2 incorporation
3.4.4 Miscellaneous reactions
3.5 Formation of carbon-X bonds
3.5.1 Formation of carbon-halogen bonds
3.5.2 Formation of Carbon-Sulfur Bonds
3.5.3 Formation of Carbon-Phosphorus Bonds
3.5.4 Formation of Carbon-Boron Bonds
3.6 Conclusion
4. C-H bond functionalization
4.1 Introduction
4.2 bond arylation
4.3 C-H Bond Phosphorylation
4.4 C-H bond sulfenylation
4.5 C-H Fluorination and C-H trimethylfluorination
4.6 Enantioselective C-H Activation
4.7 Conclusion
5. Aldol reactions
5.1 Introduction
5.2 Aldol Reactions of Isocyanoacetates
5.3 Mannich reaction
5.4 Nitroso Aldol reaction
5.5 Conclusion
6. Coupling reactions
6.1 Introduction
6.2 C-C bond coupling
6.2.1 Homocoupling
6.2.2 Cross coupling
6.2.3 Oxidative cross coupling
6.2.4 Sonogashira coupling
6.3 C-heteroatom coupling
6.3.1 C-N bond coupling
6.3.2 C-O bond coupling
6.3.3 C-S , C-Se bond coupling
6.3.4 C-P bond coupling
6.4 Conclusion
7. Cycloaddition reactions
7.1 Introduction
7.2 [3+2] cycloaddition
7.2.1 [3+2] Cycloaddition of Azomethine Ylides
7.2.2 Other [3+2] Cycloadditions
7.2.3 1,3-Dipolar Cycloaddition
7.3 [2+2] Cycloadditions
7.4 [3+3] Cycloaddition
7.5 [4+2] Cycloaddition
7.6 Conclusion
8. Rearrangement reactions
8.1 Introduction
8.2 Wolff rearrangement
8.3 Ring rearrangement
8.4 Enolate Claisen Rearrangement
8.5 [1,2]-Sigmatropic rearrangement
8.5.1 1,2-Migration
8.5.2 1,4-Migration
8.6 Conclusion
9. Asymmetric synthesis
9.1 Introduction
9.2 Asymmetric Reactions
9.2.1 Cycloaddition Reactions
9.2.1.1 [3+2] Cycloaddition
9.2.1.2 Hetero-Diels-Alder Reaction
9.2.1.3 [2+2] Cycloaddition
9.2.2 BINAP-Ag(I) Catalytic System
9.2.2.1 Allylation Reaction
9.2.2.2 Mukaiyama-Aldol Reaction
9.2.2.3 Nitroso-Aldol Reaction
9.2.2.4 Protonation of Silyl Enolates
9.2.3 Amino Acid Derived Phosphine-Ag(I) Catalyst
9.2.3.1 Mannich Reaction
9.2.4 Group-Transfer Reactions
9.2.4.1 Carbene-Transfer Reactions
9.2.4.2 Nitrene-Transfer Reaction
9.2.4.3 Silylene-Transfer Reaction
9.3 Conclusion
10. Carbene, nitrene, silylene transfer reactions
10.1 Introduction
10.2 Carbene transfer reactions
10.2.1 Carbene Transfer Reactions to p Bonds
10.2.1.1 Aziridination
10.2.1.2 Cyclopropanation
10.2.2 Formation and Reactions of Ylides
10.2.2.1 C-Hal Addition-Rearrangement Reactions
10.2.2.2 C-S Addition-Rearrangement Reactions
10.2.3 C-H Insertion
10.2.4 N-H Insertion
10.2.5 Ring Expansion Reactions
10.2.6 Intermediacy of Silver Carbenes
10.2.7 Miscellaneous Reactions Involving Silver Carbenoids
10.3 Nitrene transfer reactions
10.3.1 Aziridination
10.3.1.1 Iminoiodanes as Nitrene Precursors
10.3.1.2 Chloramine-T as Nitrene Precursor
10.3.2 Sulfide and Sulfoxide Imination
10.3.3 Amidation
10.3.3.1 Intramolecular Amidation
10.3.3.2 Intermolecular Amination with Phenanthroline Ligands
10.3.3.3 Intermolecular Amination Based on Pyrazolylborate Ligands
10.4 Silylene transfer reactions
10.4.1
| Verlagsort | Weinheim |
|---|---|
| Sprache | englisch |
| Maße | 150 x 250 mm |
| Gewicht | 666 g |
| Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
| ISBN-10 | 3-527-34282-6 / 3527342826 |
| ISBN-13 | 978-3-527-34282-2 / 9783527342822 |
| Zustand | Neuware |
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