Organosilicon Chemistry

Part 1 Tetravalent Organosilicon Compounds: Chemistry and Structure: Introduction, N. Auner, J. Weis; structures of small silicon containing compounds - why and how?, D.W.H. Rankin; sterically overcrowded organosilicon compounds and their properties, H. Bock, J. Meuret, et al; synthesis of functionally substituted oligosilanes based on silyltriflate derivatives, W. Uhlig; electroreductive formation of Di- and polysilanes, E. Hengge, Ch. Jammegg; linear tetrasilanes with internal substituents: oligosilanes with optical activity, H. Stuger; a new way to Si-Ge and Si-Sn bonds - hexachlorodisilane cleavage of organometal phosphanes, R. Martens, W.W. du Mont; 29Si29Si coupling constants of bromo-and iododisilanes and -trisilanes - XnSi2H6n and XnSi3H8n (X = Br,1), U. Katzenbeisser, K. Hassler; calculation of the 29Si NMR chemical shifts in molecules with SiN, SiCl, and SiSi Bonds, R. Wolff, R. Radeglia; reactivity of very electron-rich organosilyl amines, W. Kaim, A. Lichtblau, et al; lithiated aminofluorosilanes as precursors for monometic and dimeric iminosilanes, K. Dippel, U. Klingebiel, et al; fluorofunctional silylamines and -hydrazines - precursors for (Si-N) ring systems, C. Drost, I. Hemme, et al; new approaches to (fluoromethyl) silanes, H. Burger, P. Moritz; homo- and heterocyclic Si-O systems - rings and cages, U. Klingebiel; silaheterocycles from intramolecular reactions of silicon-functionalized diazoacetic esters, F. Krebs, S. Bender, et al; synthesis and reaction behaviour of organoalkoxysilylphenols, E. Nietzschmann, O. Boge, et al; n-silylation: new possibilities for long-known amines, K. Paulini, H. -U Reibig; on the acid-catalyzed reaction of siloxanes with alcohols, H. Kelling, D. Lange, et al; on the reactivity of chlorosiloxanes, K. Kappler, U. Scheim, et al; chlorosilanols - more stable than you think - shown with 29Si NMR, R. Lehnert; diorganosilyl-bis (o-alkylphosphonates), K. Kellner, L. Rodewald. Part 2 Subvalent and unsaturated organosilicon compounds - formation and reactivity: introduction, N. Auner, J. Weis; basic principles of the theory of bonding in silicon compounds, R. Janoschek; expectations from an unusual compound - the chemistry of decamethylsilicocene, P. Jutzi; Cp2Si (CO) and Cp2Si(N2): complexes of decamethylsilicocene, M. Tacke, Ch. Klein, et al; silicon and phosphinomethanides - a novel entry to hypervalent and low valent organosilicon chemistry, H.H. Karsch. Part contents.