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The Chemistry of Amidines and Imidates

Saul Patai, Zvi Rappoport (Herausgeber)

Buch | Hardcover
934 Seiten
1991 | Volume 2 ed.
John Wiley & Sons Ltd (Verlag)
978-0-471-92457-9 (ISBN)
709,95 inkl. MwSt
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One in the series "The Chemistry of Functional Groups" devoted to the preparation, properties and reactions of the group under consideration and on the effects which it exerts, both in the immediate vicinity of the group and in the whole molecule. This volume treats amidines and related compounds.
This volume addressing amidines and related compounds is one of a series "The Chemistry of Functional Groups". Each volume aims to cover all aspects of the chemistry of one of the important functional groups in organic chemistry. The emphasis is laid on the preparation, properties and reactions of the functional group treated and on the effects which it exerts both in the immediate vicinity of the group in question and in the whole molecule. Each of the authors is asked not to give an encyclopaedic coverage of the subject, but to concentrate on the most important recent developments and mainly on material that has not been adequately covered by reviews or other secondary sources by the time of writing of the chapter, and to address himself to the reader who is assumed to be at a fairly advanced postgraduate level. It is realized that no plan can be devised for a volume that would give a complete coverage of the field with no overlap between chapters, while at the same time preserving the readability of the text. The editor set himself the goal of attaining reasonable coverage with moderate overlap, with a minimum of cross-references between chapters.
In this manner, sufficient freedom is given to the authors to produce readable quasi-monographic chapters. An introductory chapter dealing with the general and theoretical aspects of the group. It also includes chapters discussing the characterization and characteristics of the functional groups, (eg qualitative and quantitative methods of determination including chemical and physical methods, MS, UV, IR, NMR, ESR and PES), as well as the activating and directive effects exerted by the group, and its basicity, acidity or complex-forming ability.

General and theoretical aspects, G.Hafelinger; structural chemistry, T.M.Krygowski and K.Wozniak; stereochemical aspects of amidines, imidates and related derivatives, C.L.Perrin; analysis, J.Oszczapowicz and I.Oszczapowicz; mass spectra, S.Fornarini; thermochemistry, K.Pihiaja; synthesis of amidines, G.Boyd; synthetic uses of amidines and related compounds, G.Boyd; imidates, D.G.Nielson; synthesis, chemistry and uses of guanidine derivatives, K.Akiba; rearrangements, V.Minkin and I.E.Mikhailov; tautomerism, H-bonding and basicity, J.Oszczapowicz; directing and activating effects, J.Shorter; biochemistry, pharmacology and toxicology of amidines and related compounds, R.J.Grout; isotopically substituted amidines, P.J.Smith; photochemistry and radiation chemistry of amidines and related compounds, Z.B.Alfassi; catalysis by amidines, P.N.Ahlberg; electrochemistry, J.Jaworski and M.Kalinowski.

Erscheint lt. Verlag 11.9.1991
Reihe/Serie Chemistry of Functional Groups
Zusatzinfo index
Verlagsort Chichester
Sprache englisch
Maße 158 x 236 mm
Gewicht 1120 g
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
ISBN-10 0-471-92457-1 / 0471924571
ISBN-13 978-0-471-92457-9 / 9780471924579
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