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Catalyzed Direct Reactions of Silicon

K. M. Lewis, D.G. Rethwisch (Herausgeber)

Buch | Hardcover
664 Seiten
1993
Elsevier Science Ltd (Verlag)
978-0-444-81715-0 (ISBN)
209,95 inkl. MwSt
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Includes a presentation of the state of commercial practice on the direct synthesis of chlorosilanes and methylchlorosilanes; the use of FTIR for real-time analysis of methylchlorosilane vapours exiting the direct reaction; and direct synthesis of tri(dimethylamino)silane.
There has been a scarcity of authoritative, published information on the direct reactions of silicon. Nevertheless, the need for up-to-date information on the reactions and their silane products persists across a broad range of scientists. Recent progress warrants documentation of the state-of-the-art, and identification of the areas for future research. Some of the highlights of the book are: An authoritative presentation of the state of commercial practice on the direct synthesis of chlorosilanes and methylchlorosilanes in more depth and breadth than can be found elsewhere in a single volume; the use of in-line FTIR for real time analysis of methylchlorosilane vapors exiting the direct reaction shortens the analysis time from 30 minutes to 20 seconds and provides information comparable to gas chromatography; the first comprehensive publication on the direct synthesis of tri(dimethylamino)silane; chemical engineering modelling of the direct synthesis of chlorosilanes and methylchlorosilanes.

Commercial production of silanes by the direct synthesis, B. Kanner and K.M. Lewis; production of silicon for the methyl chloride direct synthesis, J.H. Downing et al; quality criteria for silicon used for organo-silicon industry, H.M. Rong et al; some considerations of the direct synthesis of methylchlorosilanes, W.F. Banholzer et al; selection of copper formate catalysts for the direct synthesis of methylchlorosilanes, K.M. Lewis et al; catalyst preparation for the direct synthesis of methylchlorosilanes - practical, theoretical, and reactor design considerations, L.K. Doraiswamy and A.N. Gokarn; kinetics of the methyl chloride-silicon direct reaction, I.R. Moore and J.A. Nelson; gas chromatographic analysis of methylchlorosilanes produced by the direct reaction, L.G. Hawkins; gas chromatographic analysis in the manufacture of chlorosilanes, H. Rotzsche et al; in-line Fourier transform infrared spectroscopic analysis of methylchlorosilanes produced by the direct reaction, H.B. Friedrich et al; copper-catalyzed etching of silicon, J.A. Mucha et al; model reaction studies of the direct synthesis of methylchlorosilanes, K.A. Magrini et al; selective formation of dimethylchlorosilane on Si surfaces, K.A. Magrini and J.L. Falconer; effects of promoters on the catalytic synthesis of methylchlorosilanes, L.D. Gasper-Galvin et al; chemisorption and catalytic activity of Cu and Ag atoms on Si(111) surfaces, S.H. Chou et al; surface-chemical studies of the mechanism of the direct synthesis of methylchlorosilanes, K.M. Lewis et al; direct synthesis of chlorosilanes and silane, W.C. Breneman; by-products from waste treatment for a bench scale trichlorosilane/tetrachlorosilane direct process, J.A. Cervantes et al; mathematical modelling of diffusion and microkinetics in direct reactions of silicon and in the processing of electronic components, S.S.E.H. Elnashaie; copper-catalyzed reaction of dimethylamine with silicon, K.M. Lewis et al; author index; subject index.

Reihe/Serie Studies in Organic Chemistry ; v.49
Zusatzinfo indexes
Verlagsort Oxford
Sprache englisch
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
Naturwissenschaften Chemie Organische Chemie
Naturwissenschaften Chemie Physikalische Chemie
ISBN-10 0-444-81715-8 / 0444817158
ISBN-13 978-0-444-81715-0 / 9780444817150
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