Yaws Handbook of Vapor Pressure -  Carl L. Yaws

Yaws Handbook of Vapor Pressure (eBook)

Antoine Coefficients

(Autor)

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2015 | 2. Auflage
336 Seiten
Elsevier Science (Verlag)
978-0-12-803002-8 (ISBN)
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Increased to include over 25,000 organic and inorganic compounds, The Yaws Handbook of Vapor Pressure: Antoine Coefficients, Second Edition delivers the most comprehensive and practical database source for today's petrochemical. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as pure components in storage vessels, pressure relief valve design, flammability limits at the refinery, as well as environmental emissions from exposed liquids, making data to efficiently calculate these daily challenges a fundamental need. Written by the world's leading authority on chemical and petrochemical data, The Yaws Handbook of Vapor Pressure simplifies the guesswork for the engineer and reinforces the credibility of the engineer's calculations with a single trust-worthy source. This data book is a must-have for the engineer's library bookshelf. - Increase compound coverage from 8,200 to over 25,000 organic and inorganic compounds, including sulfur and hydrocarbons - Solve process design questions quickly from a single reliable data source - Locate answers easily for multiple petrochemical related questions such as bubble point, dew point temperatures, and vapor-liquid equilibrium

Carl L. Yaws, PhD is Professor of chemical engineering (retired) at Lamar University, in Beaumont, Texas. He has industrial experience in process engineering, development, modeling, and design at Exxon, Ethyl, and Texas Instruments. He is the author of 36 books and more than 1000 technical publications (papers, presentations, and chapters in books) in process engineering, property data, and pollution prevention. He is a leading authority on property data of chemical compounds for use by practicing engineers and scientists.
Increased to include over 25,000 organic and inorganic compounds, The Yaws Handbook of Vapor Pressure: Antoine Coefficients, Second Edition delivers the most comprehensive and practical database source for today's petrochemical. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as pure components in storage vessels, pressure relief valve design, flammability limits at the refinery, as well as environmental emissions from exposed liquids, making data to efficiently calculate these daily challenges a fundamental need. Written by the world's leading authority on chemical and petrochemical data, The Yaws Handbook of Vapor Pressure simplifies the guesswork for the engineer and reinforces the credibility of the engineer's calculations with a single trust-worthy source. This data book is a must-have for the engineer's library bookshelf. - Increase compound coverage from 8,200 to over 25,000 organic and inorganic compounds, including sulfur and hydrocarbons- Solve process design questions quickly from a single reliable data source- Locate answers easily for multiple petrochemical related questions such as bubble point, dew point temperatures, and vapor-liquid equilibrium

Chapter 1

Vapor Pressure – Organic Compounds


Carl L. Yaws
Marco A. Satyro

Abstract


The results for Antoine coefficients for vapor pressure as a function of temperature are given in Table 1 for organic compounds. The tabulation is arranged by carbon number (C, C2, C3,…….., C100) to provide ease of use in quickly locating the data by using the chemical formula. The compound name, chemical abstracts registry number (CAS No), and Antoine coefficients are provided in the adjacent columns. The range of application is denoted by minimum and maximum temperatures (TMIN and TMAX). Temperatures outside the range of application should not be used. The next column provides the code for the tabulation, which is based on both experimental data and estimated values.

Keywords


organic compounds
Antoine coefficients for vapor pressure
chemical formula
compound name
CAS No (chemical abstracts registry number)
range of application
minimum and maximum temperatures (TMIN and TMAX)
experimental data
estimated values

Tabulation results


The tabulation is arranged by carbon number (C, C2, C3,…….., C100) to provide ease of use in quickly locating the data by using the chemical formula. The compound name, chemical abstracts registry number (CAS No), and Antoine coefficients are provided in the adjacent columns. The range of application is denoted by minimum and maximum temperatures (TMIN and TMAX). Temperatures outside the range of application should not be used. The next column provides the code for the tabulation, which is based on both experimental data and estimated values.
In preparing the tabulation, a literature search was conducted to identify data source publications (1–52). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened and copies of appropriate data were made. These data were then keyed into the computer to provide a database of values for compounds for which experimental data are available. The database also served as a basis to check the accuracy of the estimation methods. Upon completion of data collection, estimation of values for the remaining compounds was performed.
The estimates are primarily based on literature methods and empirical procedures developed by the author. If initial analysis using the estimates is favorable, follow-up experimental determination is recommended. This is especially true for highly polar and high molecular weight compounds.
A code of 1 in the tabulation is based on experimental data. A code of 2 indicates an estimate. The estimates with a code of 3 should be considered rough approximations. The estimates with a code of 2 are more accurate. For those substances which undergo decomposition (such as nitro compounds with explosive decomposition and very large compounds with thermal decomposition) prior to attaining the boiling point temperature, the boiling point temperature is a hypothetical value.
A comparison of calculated and data values is shown in Figure 1 for a representative compound. The graph discloses favorable agreement of equation and data.
Figure 1 Vapor Pressure of Acetone

Example


Calculate the vapor pressure of acetone (C3H6O) at 47.35°C.
Substitution of the Antoine coefficients from the table and temperature into the equation for vapor pressure yields:

g 10 ⁡ P = 7.31742 − 1315.6735 / 47.35 + 240.479 = 2.7464 P = 10 2.7646 = 557.70   mmHg

Table 1

Vapor Pressure – Organic Compounds

log10 P = A - B/(T + C) (P - mmHg, T - C)
NO FORMULA NAME CAS No A B C TMIN TMAX code
1 CAsCl2F3 dichloro(trifluoro-methyl)arsine 421-32-9 6.44199 1078.1800 222.610 -48.15 108.11 3
2 CBrClF2 bromochlorodifluoromethane 353-59-3 6.96434 1008.7093 249.569 -80.45 153.00 1,2
3 CBrCl2F bromodichlorofluoromethane 353-58-2 7.53163 1515.7000 273.150 -41.09 75.30 1,2
4 CBrCl3 bromotrichloromethane 75-62-7 7.17536 1468.7621 238.507 -21.00 131.16 1,2
5 CBrFO carbonic bromide fluoride 753-56-0 7.61850 1196.7000 273.150 -92.34 -3.42 3
6 CBrF3 bromotrifluoromethane 75-63-8 6.96895 800.4823 253.656 -119.55 67.00 1,2
7 CBrN cyanogen bromide 506-68-3 7.67970 1211.2170 190.995 -13.00 78.42 1,2
8 CBr2ClF dibromochlorofluoromethane 353-55-9 7.68319 1697.4000 273.150 -19.17 103.94 1,2
9 CBr2F2 dibromodifluoromethane 75-61-6 7.13810 1187.3002 254.436 -61.01 45.67 1,2
10 CBr3Cl tribromochloromethane 594-15-0 7.88553 1889.0287 273.150 1.20 128.49 1,2
11 CBr3F tribromofluoromethane 353-54-8 7.59674 1790.4000 273.150 -1.74 132.39 1,2
12 CBr4 carbon tetrabromide 558-13-4 8.36395 2539.1862 273.540 71.27 216.45 1,2
13 CClFO carbonyl chloride fluoride 353-49-1 8.10490 1187.2000 273.150 -108.15 -32.00 3
14 CClF2NO difluorocarbamoyl chloride 16847-30-6 7.91171 1347.3400 273.150 -84.15 11.71 3
15 CClF3 chlorotrifluoromethane 75-72-9 7.05630 746.7453 260.340 -137.04 28.85 1,2
16 CClF3O trifluoromethyl hypochlorite 22082-78-6 7.41310 1025.0000 273.150 -131.15 -30.90 3
17 CClF3O2 chloroperoxytrifluoromethane 32755-26-3 7.74210 1221.0000 273.150 -92.05 -5.40 3
18 CClF3O3S fluorosulphuric acid, chlorodifluoromethyl ester 6069-31-4 6.71727 965.4680 214.792 -46.15 58.29 3
19 CClF3O4 perchloric acid, trifluoromethyl ester 52003-45-9 7.48280 1301.0000 273.150 -72.47 29.34 3
20 CClF3S trifluoromethanesulfenyl chloride 421-17-0 6.13058 639.8900 197.500 -72.78 19.51 3
21 CClF4N difluoro(difluoro-chloromethyl)amine 13880-71-2 7.71462 1388.7700 273.150 -66.32 33.23 3
22 CClF4NO2S chloro(trifluoro-methyl)sulfamoyl fluoride 19419-95-5 7.77610 1503.0000 273.150 -51.34 54.00 3
23 CClF7S chlorotetrafluoro-(trifluoromethyl)sulfur 42179-04-4 7.49010 1352.0000 273.150 -64.83 40.67 3
24 CClN cyanogen chloride 506-77-4 7.04917 913.9610 206.412 -55.32 29.92 1,2
25 CCl2FI dichlorofluoroiodo-methane 420-48-4 7.71448 1708.8600 273.150 -18.65 103.86 3
26 CCl2F2 dichlorodifluoromethane 75-71-8 6.92200 865.3109 243.873 -97.75 111.97 1,2
27 CCl2F3N N,N-dichloro-1,1,1-trifluoromethylamine 13880-73-4 7.53148 1347.3700 273.150 -66.86 36.62 3
28 CCl2F3NS trifluoromethyl-imidosulfurous...

Erscheint lt. Verlag 12.3.2015
Sprache englisch
Themenwelt Naturwissenschaften Chemie Technische Chemie
Naturwissenschaften Physik / Astronomie Thermodynamik
Technik Elektrotechnik / Energietechnik
Technik Maschinenbau
ISBN-10 0-12-803002-X / 012803002X
ISBN-13 978-0-12-803002-8 / 9780128030028
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