High Pressure Liquids and Solutions (eBook)

Front Cover 1
High Pressure Liquids and Solutions 4
Copyright Page 5
Table of Contents 10
Foreword 6
Preface 8
List of Contributors 12
Chapter 1. High-pressure solubility of several organic and inorganic solutes in water 16
1. INTRODUCTION 16
2. HIGH-PRESSURE VESSELS 17
3. SOLUBILITY OF ALKYLBENZENES IN WATER 19
4. SOLUBILITY OF NAPHTHALENE IN WATER 26
5. SOLUBILITY OF INORGANIC COMPOUNDS IN WATER 28
REFERENCES 31
Chapter 2. Pressure effect on the mobility of ions in heavy and light water 34
1. INTRODUCTION 34
2. EXPERIMENTAL PROCEDURE 35
3. RESULTS AND DISCUSSION 37
4. CONCLUSIONS 45
REFERENCES 45
Chapter 3. High-pressure multinuclear magnetic resonance studies on the solvent exchange of first-row transition metal(II) ions in acetic acid, ethylenediamine, and nitriles. Effects of the bound ligand, solvent bulkiness, and chelate-ring strain 48
1. INTRODUCTION 48
2. EXPERIMENTAL 49
3. RESULTS AND DISCUSSION 53
REFERENCES 63
Chapter 4. High-pressure high-resolution NMR measurements on liquid solutions 64
1. INTRODUCTION 64
2. HIGH-PRESSURE GLASS CELL 65
3. APPLICATION OF GLASS CELL METHODS TO STUDY THE PRESSURE EFFECTS ON MOLECULAR CONFORMATION AND STRUCTURE 72
ACKNOWLEDGEMENTS 79
REFERENCES AND NOTES 79
Chapter 5. High-pressure study of the dynamic solvent effect on isomerization rate 82
1. INTRODUCTION 82
2. THEORETICAL BACKGROUND 84
3. INTRAMOLECULAR EXCIMER FORMATION OF "DPP" 86
4. GROUND-STATE ISOMERIZATION OF DODCI" 88
5. BARRIER CROSSING DATA FOR ISOMERIZATION 92
6. CONCLUDING REMARKS 93
Acknowledgments 93
REFERENCES 93
Chapter 6. Fluid structure and chemical reactions in low- and medium-density fluids 96
1. INTRODUCTION 96
2. OVERVIEW ON THE RELATIONSHIP BETWEEN THE FLUID STRUCTURE AND CHEMICAL EQUILIBRIUM 97
3. CHEMICAL EQUILIBRIUM IN LOW- AND MEDIUM-DENSITY FLUIDS 98
4. CHEMICAL KINETICS 104
5. CRITICAL ANOMALY IN THE CHEMICAL REACTION 106
6. CONCLUSION 107
REFERENCES 107
Chapter 7. Pressure studies on the phase-transition behavior in phospholipid/anesthetic suspensions 110
1. INTRODUCTION 110
2. EXPERIMENTAL PROCEDURE 111
3. RESULTS 113
4. DISCUSSION 115
ACKNOWLEDGEMENT 119
REFERENCES 120
Chapter 8. Pressure denaturation mechanism for proteins 122
1. INTRODUCTION 122
2. THERMODYNAMIC PROPERTIES OF PRESSURE DENATURATION 123
3. SECONDARY STRUCTURE OF PROTEINS 127
REFERENCES 131
Chapter 9. Synthetic applications of amino SNAr reactions under high-pressure 134
1. INTRODUCTION 134
2. CONSECUTIVE SNAr-DEQUATERNIZATION REACTIONS 134
3. SYNTHESIS OF Ag+ ION-SPECIFIC CROWN ETHERS 138
4. SYNTHESIS OF DIAZA-18-CROWN-6 THIOETHER 145
ACKNOWLEDGEMENTS 149
REFERENCES 149
Chapter 10. Thermophysical properties of water and alcohol mixtures 152
1. INTRODUCTION 152
2. EXPERIMENTAL PROCEDURE 153
3. EXPERIMENTAL RESULTS AND QUALITATIVE INTERPRETATION 155
4. SUMMARY 163
Acknowledgements 163
REFERENCES 163
Chapter 11. Measurement of the viscoelastic properties of lubricants under high pressure by DAC 164
1. INTRODUCTION 164
2. VISCOELASTIC MODEL 165
3. EXPERIMENTAL INSTRUMENTATION 167
4. VISCOSITY MEASUREMENT BY THE FALLING-SPHERE TECHNIQUE 169
5. DENSITY MEASUREMENT BY THE BRILLOUIN SCATTERING TECHNIQUE 173
6. VISCOELASTIC MEASUREMENT BY STRESS RELAXATION IN RUBIES 173
7. CONCLUDING REMARKS 181
REFERENCES 182
Chapter 12. Ultrasonic speed in trichloromethane and dichloromethane and their thermodynamic properties under high pressure 184
1. INTRODUCTION 184
2. EXPERIMENTAL PROCEDURE 185
3. RESULTS AND DISCUSSION 186
4. CONCLUSION 193
REFERENCES 193
Chapter 13. Static relative permittivity of some compressed fluids 196
1. INTRODUCTION 196
2. EXPERIMENTAL 198
3. RESULTS AND DISCUSSION 199
REFERENCES 211
Index 214