Handbook on Synchrotron Radiation (eBook)

Front Cover 1
Handbook on Synchrotron Radiation 4
Copyright Page 5
Table of Contents 8
Preface 6
Contributors to Volume 2 12
Chapter 1. Synchrotron radiation sources 14
1. Introduction 16
2. Synchrotron radiation sources in the soft X-ray (SXR) and vacuum ultraviolet (VUV) regions 19
3. The prospects for increasing the brilliance of SR sources in the soft X-ray region 27
4. Synchrotron radiation source installations 32
References 33
Chapter 2. Optical engineering 34
1. Introduction 36
2. The synchrotron radiation source 37
3. Mirrors 48
4. Diffraction grating optics 69
5. Beam line layout 97
6. Optical components 112
7. Beam line auxiliary equipment 122
8. Conclusion 129
References 130
Chapter 3. Data aquisition and analysis systems 134
1. Introduction 136
2. Data aquisition electronics 137
3. Local computer systems 161
4. Data processing facilities 170
Acknowledgements 182
References 183
Chapter 4. High resolution spectroscopy of atoms and molecules including Faraday rotation effects 188
1. Introduction 190
2. High resolution spectra of atoms 190
3. High resolution spectra of molecules 225
4. SR experiments with polarised radiation 243
5. Conclusion 249
Acknowledgements 250
References 250
Chapter 5. Resonances in molecular photoionization 254
1. Introduction 256
2. Shape resonances 258
3. Autoionization 276
4. Triply differential photoelectron measurements - experimental aspects 288
5. Case studies 293
6. Survey of related work 343
7. Prospects for future progress 347
Appendix. A bibliography on shape resonances in molecular photoionization through early 1985 349
References 355
Chapter 6. Molecular photodissociation and photoionization 368
1. General introduction 370
2. Experimental methods 374
3. Selected examples 395
4. Miscellaneous and future trends 468
Acknowledgments 471
References 471
Chapter 7. Surface science with synchrotron radiation 480
1. Introduction 482
2. Techniques 482
3. Clean surfaces 489
4. Surfaces with adsorbates 513
5. Interfaces 534
6. Conclusions 546
References 546
Chapter 8. Metal–semiconductor interface studies by synchrotron radiation techniques 554
1. Introduction 556
2. Metal–semiconductor interactions and electronic properties 557
3. Soft X-ray photoemission spectroscopy for microscopic interface characterization 560
4. Chemical bonding at metal-semiconductor interfaces 562
5. Metal–semiconductor interdiffusion 589
6. Fermi level pinning and semiconductor band bending 595
7. Other synchrotron radiation techniques for interface analysis 607
8. Conclusions and future directions 613
Acknowledgement 616
References 616
Chapter 9. Inner shell photoelectron process in solids 624
1. Introduction 626
2. Fundamental theory of many-body effects in inner shell photoelectron process 627
3. Simple metals 636
4. Rare earth metals and compounds 640
5. Transition metals and compounds 652
6. Related topics 663
7. Concluding remarks 669
Acknowledgements 670
Appendix. Derivation of basic photoemission formulae 670
References 673
Chapter 10. Surface core level shift 676
1. Introduction 678
2. Surface–bulk core level shift for clean surfaces 679
3. Applications 706
4. Conclusion 731
Acknowledgements 732
References 732
Chapter 11. Optical constants 736
1. Introduction 738
2. Definitions 739
3. Sample characteristics 751
4. Measurement methods 755
5. Summary 775
6. Some examples 777
7. Comments on data collections and recent literature 783
Appendix: Recent literature reference to optical data for E = 6eV 785
References 788
Author index 798
Subject index 842