Chemical Kinetics of Gas Reactions (eBook)
826 Seiten
Elsevier Science (Verlag)
978-1-4832-2518-0 (ISBN)
This book is composed of 10 chapters, and begins with the presentation of general kinetic rules for simple and complex chemical reactions. The next chapters deal with the experimental methods for evaluating chemical reaction mechanisms and some theories of elementary chemical processes. These topics are followed by discussions on certain class of chemical reactions, including unimolecular, bimolecular, and termolecular reactions. The remaining chapters examine gas reactions, such as molecular collisions, photochemical reactions, chemical reactions in electrical discharge, chain reactions, and combustion.
This book will be of value to reaction kinetics engineers and researchers.
Chemical Kinetics of Gas Reactions explores the advances in gas kinetics and thermal, photochemical, electrical discharge, and radiation chemical reactions. This book is composed of 10 chapters, and begins with the presentation of general kinetic rules for simple and complex chemical reactions. The next chapters deal with the experimental methods for evaluating chemical reaction mechanisms and some theories of elementary chemical processes. These topics are followed by discussions on certain class of chemical reactions, including unimolecular, bimolecular, and termolecular reactions. The remaining chapters examine gas reactions, such as molecular collisions, photochemical reactions, chemical reactions in electrical discharge, chain reactions, and combustion. This book will be of value to reaction kinetics engineers and researchers.
Front Cover 1
Chemical Kinetics of Gas Reactions 4
Copyright Page 5
Table of Contents 6
Foreword 14
CHAPTER 1. GENERAL KINETIC RULES FOR CHEMICAL REACTIONS 16
§1. Rate of reaction. Kinetic types of simple reactions 16
§2. Chemical equilibrium 23
§3. Complex reactions 32
CHAPTER 2. CHEMICAL MECHANISM OF REACTIONS 59
§4. Experimental methods for studying chemical reaction mechanisms 59
§5. Intermediate substances 81
§6. Reactions of free atoms 99
§7. Free radical reactions 124
CHAPTER 3. THEORY OF ELEMENTARY CHEMICAL PROCESSES 135
§8. Elements of the statistical theory of elementary chemical processes 136
§9. Gas-kinetic collision theory 157
§10. Potential energy of a system of atoms 170
§11. Qualitative consideration of energy changes in three-atom reactions 185
§12. Transition-state (activated-complex) method
193
§ 13. Quantum-mechanical treatment of the rate of elementary processes 219
CHAPTER 4. BIMOLECULAR REACTIONS 245
§14. Addition reactions A +B = AB 246
§15. Metathetical or transfer reactions A + BC = AB + C, and exchange (double transfer) reactions AB + CD = AC + BD
271
§16. Bimolecular dissociation reactions 290
§17. Dependence of the rate of transfer reactions on the structure of the reacting molecules
295
CHAPTER 5. UNIMOLECULAR AND TERMOLECULAR REACTIONS 302
§18. Theory of unimolecular reactions 302
§19. Experimental data 322
§20. Termolecular reactions 340
CHAPTER 6. ENERGY CONVERSION DURING MOLECULAR COLLISIONS 365
§21. Transformation of translational and rotational energy 365
§22. Transformation of vibrational energy 381
CHAPTER 7. PHOTOCHEMICAL REACTIONS 427
§23. Photochemical activation of molecules 427
§24. Secondary processes during photochemical reactions 443
§25. Photochemical sensitization 460
§26. Quantum yield of photochemical reactions 473
§27. Temperature coefficient and mechanism of photochemical reactions 477
CHAPTER 8. CHEMICAL REACTIONS IN ELECTRICAL DISCHARGE 488
§28. Activation in electrical discharge 488
§29. Activation by bombardment with fast ions and atoms 513
§30. Types of electrical discharge 540
§31. Chemical reactions in electrical discharge and yields of these reactions
550
§32. Chemical reactions taking place under the action of penetrating radiations (radiation-induced chemical reactions)
564
CHAPTER 9. CHAIN REACTIONS 584
§33. Simple chain reactions 584
§34. Formal kinetics of chain reactions 595
§35. Chain initiation 600
§36. Chain breaking 610
§37. Branching chains 615
§38. Macroscopic stages in chain reactions 628
§39. The combustion of hydrogen as a model reaction 632
CHAPTER 10. COMBUSTION PROCESSES 657
§40. Spontaneous combustion 657
§41. Flames burning without preliminary mixing of the gases 680
§42. Flames burning in previously prepared mixtures 698
§43. Flame propagation 725
§44. Detonation 782
References 797
Name index
832
Subject index 842
| Erscheint lt. Verlag | 22.1.2016 |
|---|---|
| Sprache | englisch |
| Themenwelt | Naturwissenschaften ► Chemie ► Physikalische Chemie |
| Technik | |
| ISBN-10 | 1-4832-2518-6 / 1483225186 |
| ISBN-13 | 978-1-4832-2518-0 / 9781483225180 |
| Haben Sie eine Frage zum Produkt? |
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