Ternary Chalcopyrite Semiconductors: Growth, Electronic Properties, and Applications -  J. L. Shay,  J. H. Wernick

Ternary Chalcopyrite Semiconductors: Growth, Electronic Properties, and Applications (eBook)

International Series of Monographs in The Science of The Solid State

, (Autoren)

B. R. Pamplin (Herausgeber)

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2013 | 1. Auflage
254 Seiten
Elsevier Science (Verlag)
978-1-4831-5792-4 (ISBN)
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Ternary Chalcopyrite Semiconductors: Growth, Electronic Properties, and Applications covers the developments of work in the I-III-VI2 and II-IV-V2 ternary chalcopyrite compounds. This book is composed of eight chapters that focus on the crystal growth, characterization, and applications of these compounds to optical communications systems.
After briefly dealing with the status of ternary chalcopyrite compounds, this book goes on describing the crystal growth of II-IV-V2 and I-III-VI2 single crystals. Chapters 3 and 4 examine the energy band structure of these semiconductor compounds, illustrating that these compounds are the simplest ternary analogs of II-VI zincblende compounds. Chapter 5 discusses the spontaneous luminescence, stimulated emission and laser action, and light-emitting diodes employing ternary chalcopyrite compounds. Chapter 6 discusses some of the fundamental principles of nonlinear optical interactions and the properties of the chalcopyrite crystals. This text also highlights the nonlinear optical devices available. Chapter 7 describes the electrical properties of chalcopyrite crystals, whereas the concluding chapter deals with the other physical properties of these compounds, such as lattice vibrational spectra, optical activity, and linear thermal expansion.
This book is of great value to researchers and workers in the semiconductor field.
Ternary Chalcopyrite Semiconductors: Growth, Electronic Properties, and Applications covers the developments of work in the I-III-VI2 and II-IV-V2 ternary chalcopyrite compounds. This book is composed of eight chapters that focus on the crystal growth, characterization, and applications of these compounds to optical communications systems. After briefly dealing with the status of ternary chalcopyrite compounds, this book goes on describing the crystal growth of II-IV-V2 and I-III-VI2 single crystals. Chapters 3 and 4 examine the energy band structure of these semiconductor compounds, illustrating that these compounds are the simplest ternary analogs of II-VI zincblende compounds. Chapter 5 discusses the spontaneous luminescence, stimulated emission and laser action, and light-emitting diodes employing ternary chalcopyrite compounds. Chapter 6 discusses some of the fundamental principles of nonlinear optical interactions and the properties of the chalcopyrite crystals. This text also highlights the nonlinear optical devices available. Chapter 7 describes the electrical properties of chalcopyrite crystals, whereas the concluding chapter deals with the other physical properties of these compounds, such as lattice vibrational spectra, optical activity, and linear thermal expansion. This book is of great value to researchers and workers in the semiconductor field.

Front Cover 1
Ternary Chalcopyrite Semiconductors: Growth, Electronic Properties, and Applications 4
Copyright Page 5
Table of Content 6
ACKNOWLEDGEMENTS 9
EDITORS PREFACE 10
CHAPTER 1. INTRODUCTION 12
References 13
CHAPTER 2.THE CHALCOPYRITE STRUCTURE AND CRYSTA GROWTH 14
2.1 The Chalcopyrite Structure 14
2.2 Phase Transitions in Chalcopyrite Crystals 21
2.3 Tetrahedrally Coordinated Compounds with more than Three Components 24
2.4 Dissociation Pressures of Chalcopyrite Compounds 26
2.5 Phase Relationships in I-III-VI Systems 30
2.6 Phase Relationships in Mixed I - III - VI2- Systems 35
2.7 Phase Relationships in (I- III-VI2)-(II-VI) and (I-III-VI2)-(III-V) Systems 36
2.8 Phase Relationships in II-IV -V Systems 49
2.9 Phase Relationships in Mixed II- IV -V Systems 55
2.10 Phase Relationships in Mixed (II-IV-V2)(III-V) Systems 56
2.11 Crystal Growth, General Considerations 60
2.12 Glass Formation in Chalcopyrite Systems 88
2.13 Effect of High Pressure and Temperature on Ternary Compounds 89
2.14 Mechanical Behavior of Chalcopyrite Compounds 89
References 91
CHAPTER 3. ELECTRONIC STRUCTURE OF II-IV-V2 COMPOUNDS 96
3.1 Theoretical Concepts 96
3.2 Lowest Direct Energy Gaps 99
3.3 Pseudodirect Energy Gaps 107
3.4 Optical Anisotropy of II-IV-V2 Compounds 113
3.5 Higher Lying Energy Gaps 120
References 125
CHAPTER 4. ELECTRONIC STRUCTURE OF I-III-VI2 SEMICONDUCTORS 127
4.1 Introduction 127
4.2 Experimental Results 127
4.3 p-d Hybridization 133
4.4 Exciton Optical Properties 138
References 145
CHAPTER 5. LUMINESCENCE 146
5.1 Luminescence Spectra of II-IV-V2 Compounds 146
5.2 Luminescence Spectra of I-III-VI2 Compounds 153
5.3 Stimulated Emission Spectra of I-III-VI2 Compounds 159
5.4 CdSnP2-InP Heterodiodes 162
5.5 CdS-CuGaS2 Electroluminescent Diodes 165
References 168
CHAPTER 6. NONLINEAR OPTICAL APPLICATIONS 169
6.1 Nonlinear Optical Phenomena 169
6.2 The Optical Parametric Oscillator 178
6.3 Phase-matched Upconversion of 10.6 µ Radiation 186
6.4 Difference Frequency Generation of Submillimeter Waves 189
References 191
CHAPTER 7. ELECTRICAL PROPERTIES 192
7.1 Electrical Properties of II-IV-V2 Compounds 192
7.2 Band Parameters of II-IV-V2 Compounds 200
7.3 Electrical Properties of I-III-VI2 Compounds 204
7.4 Glassy II-IV-V2 Compounds 219
7.5 Current Oscillations 223
7.6 Thermoelectric Properties 225
References 229
CHAPTER 8. MISCELLANEOUS PHYSICAL PROPERTIES 232
8.1 Lattice Vibrational Spectra 232
8.2 Optical Activity in AgGaS2 239
8.3 E.S.R. of Fe3+ in I-III-VI2 Crystals 69 241
8.4 N. M.R. of Cu63 and Ga69 242
8.5 Properties of Quaternary Alloys 242
8.6 Linear Thermal Expansion of CdGeAs2 246
References 247
APPEND I X: Tabulated Refractive Index Data 248
INDEX 260

Erscheint lt. Verlag 22.10.2013
Sprache englisch
Themenwelt Naturwissenschaften Physik / Astronomie Elektrodynamik
Technik
ISBN-10 1-4831-5792-X / 148315792X
ISBN-13 978-1-4831-5792-4 / 9781483157924
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