Annual Reports in Inorganic and General Syntheses-1972 (eBook)

Front Cover 1
Annual Reports in Inorganic and General Syntheses - 1972 4
Copyright Page 5
Table of Contents 6
Preface 20
CHAPTER 1. ALKALI AND ALKALINE EARTH ELEMENTS 24
THE ELEMENTS 24
COMPLEXES WITH HALOGENS 24
COMPOUNDS WITH GROUP VI ELEMENTS 25
NITROGEN-CONTAINING COMPOUNDS 30
ORGANOMETALLIC COMPOUNDS 31
COMPOUNDS WITH TRANSITION METALS 32
REFERENCES 33
CHAPTER 2. COPPER 35
ALLOYS AND INTERMETALLIC COMPOUNDS 35
INORGANIC COPPER COMPOUNDS 35
COMPLEXES OF COPPER(I) 36
COMPLEXES F COPPER(II) 37
COPPER(III) COMPOUNDS 41
REFERENCES 41
CHAPTER 3. SILVER AND GOLD 48
GENERAL 48
PHOSPHINE COMPLEXES AND RELATED DERIVATIVES 48
SIMPLE SALTS AND OTHER COMPLEXES 52
MISCELLANEOUS ORGANOMETALLIC COMPOUNDS 54
REFERENCES 54
CHAPTER 4. ZINC, CADMIUM AND MERCURY 57
GENERAL AND COORDINATION COMPOUNDS 57
COMPOUNDS WITH METAL-METAL BONDS 59
ORGMTOMETALLIC COMPOUNDS 61
REFERENCES 64
CHAPTER 5. BORON 67
GENERAL 67
NEW PROCEDURES 67
ORGANOBORANES 68
METAL-BORON COMPOUNDS 70
THREE COORDINATE BORON 71
FOUR COORDINATE BORON 72
REFERENCES 72
CHAPTER 6. ALUMINUM, GALLIUM, INDIUM AND THALLIUM 78
INTRODUCTION 78
PROCEDURES FOR SYNTHESIS 78
REACTION OF ALUMINUM DERIVATIVES WITH EPOXIDES AND CARBONYLS 80
REACTION WITH OLEFINS 82
REACTIONS OF THALLIUM COMPOUNDS 83
COMPOUNDS CONTAINING METAL-METAL BONDS 84
MISCELLANEOUS REACTIONS 85
REFERENCES 87
CHAPTER 7. YTTRIUM, SCANDIUM, LANTHANIDES AND ACTINIDES 90
HYDRIDES 90
OXIDES 90
FLUORIDES 90
BORIDES 91
CHACOGENIDES 91
ORGANO LANTHANIDES AND ACTINIDES 91
ß-DIKETONATO-COMPOUNDS 92
REFERENCES 95
CHAPTER 8. TITANIUM, ZIRCONIUM AND HAFNIUM 96
BORIDES 96
ALKOXIDES 96
PHOSPHONATO COMPLEXES 98
ORGANO TITANIUM, ZIRCONIUM AND HAFNIUM 99
REFERENCES 104
CHAPTER 9. GROUP V TRANSITION ELEMENTS 105
VANADIUM 105
NIOBIUM AND TANTALUM 106
REFERENCES 108
CHAPTER 10. GROUP VI TRANSITION ELEMENTS 112
CHROMIUM 112
MOLYBDENUM 113
TUNGSTEN 117
REFERENCES 119
CHAPTER 12. MANGANESE, TECHNETIUM AND RHENIUM 123
GENERAL 123
MANGANESE 123
TECHNETIUM 130
RHENIUM 131
REFERENCES 137
CHAPTER 13. IRON 142
GENERAL 142
HYDRIDES AND PHOSPHINE COMPLEXES 142
COMPOUNDS WITH IRON-CARBON BONDS 143
COMPOUND WITH NITROGEN DONORS 143
COMPOUND WITH OXYGEN DONORS 144
COMPLEXES WITH SULFUR LIGANDS 145
HALIDE COMPLEXES 145
MISCELLANEOUS 146
REFERENCES 146
CHAPTER 14. COBALT and NICKEL 150
LOW OXIDATION STATES - COBALT(-I), COBALT(0), and COBALT(I) 150
LOW-VALENT NICKEL COMPLEXES 153
COBALT(II) AND NICKEL(II) COMPLEXES 155
COBALT(III) COMPLEXES 157
NICKEL IN HIGHER OXIDATION STATES - NICKEL(III) AND NICKEL(IV) 161
COBALT(IV) 162
REFERENCES 162
CHAPTER 15. THE PLATINUM METALS PART I: RUTHENIUM, OSMIUM, RHODIUM AND IRIDIUM 168
INTRODUCTION 168
THE CHEMISTRY OF RUTHENIUM AND OSMIUM 168
THE CHEMISTRY OF RHODIUM AND IRIDIUM 176
REFERENCES 186
CHAPTER 16. THE PLATINUM METALS PART II: PALLADIUM AND PLATINUM 191
INTRODUCTION 191
REFERENCES 199
CHAPTER 17. SILICON 203
GENERAL 203
SILICON-HALOGEN 203
SILICON-NONMETAL 204
SILICON-METAL 206
SILICON-SILICON 207
REFERENCES 208
CHAPTER 18. Germanium, Tin, and Lead 210
GENERAL 210
METAL-METAL BONDED COMPOUNDS 212
COORDINATION COMPOUNDS OF Ge,Sn,Pb 216
REFERENCES 217
CHAPTER 19. NITROGEN 224
GENERAL 224
COMPOUNDS WITH NO N-N BONDS 224
COMPOUNDS WITH ONE N-N BOND 226
COMPOUNDS WITH THREE LINKED NITROGENS 227
COMPOUNDS WITH CHAINS OF FOUR NITROGENS 229
REFERENCES 230
CHAPTER 20. PHOSPHORUS 232
INTRODUCTION 232
NEW SYNTHESES 232
PHOSPHORUS-BORON CCMPOUNDS 234
PHOSPHORUS-HALOGEN COMPOUNDS 234
PHOSPHORUS-METAL DERIVATIVES 235
PHOSPHORUS-PHOSPHORUS BONDS 235
PHOSPHORUS-OXYGEN COMPOUNDS 236
PHOSPHORUS-NITROGEN COMPOUNDS 237
PHOSPHORUS -HYDROGEN COMPOUNDS 242
RADICALS IN PHOSPHORUS CHEMISTRY 242
PHOSPHORUS CONTAINING CAGE COMPOUNDS 242
COMPLEXES WITH PHOSPHORUS CONTAINING LIGANDS 243
REFERENCES 243
CHAPTER 21. ARSENIC, ANTIMONY AND BISMUTH 248
GENERAL 248
ORGANOMETALLIC COMPOUNDS OF ARSENIC, ANTIMONY- AND BISMUTH 248
INORGANIC As, Sb AND Bi COMPOUNDS 253
"ACCEPTOR COMPOUNDS" INVOLVING THE GROUP V ELEMENTS 254
REFERENCES 255
CHAPTER 22. THE CHALCOGENTIDES 259
OXYGEN 259
SULFUR 260
SELENIUM 266
TELLURIUM 267
POLONIUM 269
REFERENCES 269
CHAPTER 23. FLUORINE 273
GENERAL 273
NEW FLUORINATING AGENTS AND TECHNIQUES 273
XENON-FLUORINE COMPOUNDS 273
CHLORINE-PLUORINE COMPOUNDS 274
SULFUR-FLUORINE COMPOUNDS 274
NITROGEM-FLUORINE CHEMISTRY 275
CARBON-FLUORINE COMPOUNDS 276
FLUORO POLYMERS 277
SILICON-FLUORINE CHEMISTRY 278
REFERENCES 279
CHAPTER 24. HALOGENS AND PSEUDOHALOGENS 281
GENERAL 281
HALOGENS 281
PSEUDOHALOGEN COMPOUNDS OF MAIN GROUP ELEMENTS 287
COMPOUNDS WITH TRANSITION METALS 289
COMPOUNDS WITH INKER TRANSITION METALS 292
REFERENCES 292
CHAPTER 25. NOBLE GASES 297
GENERAL REMARKS 297
ARGON, KRYPTON 297
XENON 297
REFERENCES 299
CHAPTER 26. SIMPLE AND COMPLEX METAL HYDRIDES OF MAIN GROUPS I, II AND III 300
INTRODUCTION 300
SIMPLE HYDRIDES OF GROUPS I AND II 300
COMPLEX HYDRIDES OF GROUPS I AND II 301
ALUMINUM HYDRIDE 302
AMINE ADDUCTS OF ALUMINUM HYDRIDE 303
GROUP I METAL HYDRIDOALUMINATES 303
GROUP II METAL HYDRIDOALUMINATES 304
HYDRIDOGALLATES 305
REFERENCES 305
CHAPTER 27. NEW TECHNIQUES AND REAGENTS IN SYNTHETIC COORDINATION CHEMISTRY 307
SYNTHESIS OF LOW-VALENT METAL COMPLEXES 307
METAL COMPLEXES IN NORMAL OXIDATION STATES 310
METAL COMPLEXES IN HIGHER OXIDATION STATES 313
REFERENCES 313
CHAPTER 28. STABILIZING EFFECTS OF LARGE COUNTER-IONS 316
LARGE CATIONS 318
HYDROGEN BONDED COMPLEX IONS 320
ANIONIC BORON COMPLEXES 322
NITRATO COMPLEXES 323
THE POLYHALIDE IONS 324
TELLUROCYANATE SALTS 325
COUNTER-ION EFFECTS IN LINKAGE ISOMERISM 325
SILVER COMPLEXES 326
INDIUM COMPLEXES 326
TRICOORDIMTED GROUP IV METALS AND THEIR COMPLEXES 327
PENTACOORDINATED GROUP IV METALS 328
GROUP V 328
GROUP VI 329
LANTHANATE COMPLEXES 329
ACTINTDES 329
CARBONYL AND CYANO COMPLEXES 330
TRANSITION METAL COMPLEXES 330
CATIONIC COMPLEXES 332
STABILITY 332
REFERENCES 333