Chemistry of Manganese, Technetium and Rhenium (eBook)

Front Cover 1
Technetium and Rhenium 4
Copyright Page 5
Table of Contents 6
PREFACE 8
CHAPTER 37. MANGANESE 10
HISTORY 10
OCCURRENCE OF MANGANESE 10
METALLURGY OF MANGANESE 13
MANGANESE ALLOYS AND THE USE OF MANGANESE IN STEEL 15
NON-METALLURGICAL USES OF MANGANESE 16
THE ELEMENT 17
THE CHEMISTRY OF MANGANESE 19
ANALYSIS OF MANGANESE 21
MANGANESE HYDRIDES 22
MANGANESE HALIDES 22
MANGANESE FLUORIDES 22
MANGANESE CHLORIDES 27
MANGANESE BROMIDES 32
MANGANESE IODIDES 34
OXIDE HALIDES 34
MANGANESE CYANIDES 35
OXIDES 37
COMPLEX MANGANESE OXIDES 44
PEROXY COMPOUNDS OF MANGANESE 45
HYDROXIDES AND OXYHYDROXIDES OF MANGANESE 45
MANGANESE HYDROXIDE HALIDES 46
MANGANESE OXYANIONS 47
MANGANESE SULPHIDES, SELENIDES AND TELLURIDES 52
MANGANESE NITRIDES, PHOSPHIDES, ARSENIDES AND ANTIMONIDES 54
MANGANESE CARBIDES AND SILICIDES 55
MANGANESE BORIDES 56
MANGANESE AZIDES 57
MANGANESE FULMINATES, CYANATES, THIOCYANATES AND SELENOCYANATES 57
MANGANESE BORATES 59
MANGANESE CARBONATE 59
MANGANESE SALTS OF SIMPLE CARBOXYLIC ACIDS 60
MANGANESE NITRITES AND NITRATES 64
MANGANESE SALTS OF PHOSPHORUS OXYACIDS 66
MANGANESE SULPHITES AND SULPHATES 70
MANGANESE HALITES, HALATES AND PERHALATES 74
MANGANESE CARBONYL 76
SUBSTITUTION REACTIONS OF MANGANESE CARBONYL 78
ORGANOMETALLIC COMPOUNDS OF MANGANESE 90
MANGANESE BORANE AND CARBORANE COMPLEXES 97
MANGANESE DINITROGEN COMPLEXES 98
NITROSYL COMPOUNDS OF MANGANESE 98
MANGANESE ISOCYANIDE COMPLEXES 100
MANGANESE PHTHALOCYANINE AND PORPHYRIN COMPLEXES 102
PHTHALOCYANINE COMPLEXES 102
PORPHYRIN COMPLEXES 104
MANGANESE 1,2-DITHIOLENE COMPLEXES 105
COMPLEXES OF MANGANESE 105
CHAPTER 38. TECHNETIUM 116
1. DISCOVERY, ISOLATION AND GENERAL PROPERTIES 116
2. HYDRIDIC COMPOUNDS, HALIDES, OXIDE HALIDES, CYANIDE AND THIOCYANATE COMPLEXES 125
3. OXIDES, OXOAC1DS AND SALTS, CHALCOGENIDES, REFRACTORIES 132
4. CARBONYLS AND ORGANOMETALLIC COMPOUNDS, COMPLEXES 137
CHAPTER 39. RHENIUM 144
1. DISCOVERY, ISOLATION, PHYSICAL AND CHEMICAL PROPERTIES, MISCELLANEOUS 144
2. HYDRIDIC COMPOUNDS, HALIDES AND OXIDE HALIDES 151
3. CYANIDE AND THIOCYANATE COMPLEXES 170
4. OXIDES 177
5. PERRHENIC ACID AND THE PERRHENATES, CHALCOGENIDES AND REFRACTORY COMPOUNDS 184
6. CARBONYLS AND ORGANOMETALLIC DERIVATIVES 191
7. COMPLEX COMPOUNDS 199
INDEX 218
Contents of Comprehensive Inorganic Chemistry 222
INDEPENDENT OPINION 224