Analytical Applications of 1,10-Phenanthroline and Related Compounds (eBook)
202 Seiten
Elsevier Science (Verlag)
978-1-4831-5656-9 (ISBN)
Organized into eight chapters, this volume begins with an overview of the planar structure of 1,10-phenanthroline. This text then examines the relative inertness of phenanthroline towards chemical reaction other than chelation or salt-formation, which is an essential asset in its analytical applications. Other chapters consider the coordination chemistry of phenanthroline and bipyridine in detail. This book discusses as well the metal ions chelated, the features of the chelates, and the influence of substituent groups or other changes in the ligands on the properties of the chelates. The final chapter examines the scientific and commercial uses for 1,10-phenanthroline and related compounds, which have increased in number and importance.
This book is a valuable resource for analytical chemists.
Analytical Applications of 1,10-Phenanthroline and Related Compounds, Volume 32 presents the significance of 1,10-phenanthroline in chemical analysis. This book discusses the varied other uses for 1,10-phenanthroline or of the distinctive advantages afforded by certain related compounds. Organized into eight chapters, this volume begins with an overview of the planar structure of 1,10-phenanthroline. This text then examines the relative inertness of phenanthroline towards chemical reaction other than chelation or salt-formation, which is an essential asset in its analytical applications. Other chapters consider the coordination chemistry of phenanthroline and bipyridine in detail. This book discusses as well the metal ions chelated, the features of the chelates, and the influence of substituent groups or other changes in the ligands on the properties of the chelates. The final chapter examines the scientific and commercial uses for 1,10-phenanthroline and related compounds, which have increased in number and importance. This book is a valuable resource for analytical chemists.
Front Cover 1
Analytical Applications of 1,10-Phenanthroline and Related Compounds 4
Copyright Page 5
Table of Contents 6
Preface 9
CHAPTER 1. INTRODUCTION 10
Historical Perspective 10
Terms and Nomenclature 12
Properties of 1,10-Phenanthroline 12
Properties of 2,2'-Bipiridine 14
Related Compounds 16
References 17
CHAPTER 2. METAL CHELATES 19
Group 1 Metals 19
Group 2 Metals 22
Group 3 Metals 23
Group 4 Metals 25
Group 5 Metals 26
Group 6 Metals 27
Group 7 Metals 28
Group 8 Metals 30
Stabilities of Metal Chelates 35
Labilities of Metal Chelates 36
Spectral Characteristics 43
Influence of Substituent Groups and Other Modifications 46
References 55
CHAPTER 3. COLORIMETRIC REAGENTS 63
Determination of Iron 65
Determination of Copper 78
Simultaneous Determination of Copper and Iron 84
CHAPTER 4. OXIDATION- REDUCTION INDICATORS 111
Ferroin 112
Substituted Ferroin Derivatives 121
Bipyridine and Terpyridine Analogs of Ferroin 127
Other Metal Chelates of the Ferroin Type 128
Mixed Ligand Complexes of Iron, Ruthenium, and Osmium 133
References 138
CHAPTER 5. METATHESIS INDICATORS 141
Indicators for Non-aqueous Acid-base Titrations 141
Fluorescent Precipitation Indicators for lodimetry 144
Precipitation and Complexation I ndicators 148
References 151
CHAPTER 6. PRECIPITANTS 152
Precipitation of Anions with Ferroin or Ferroin-like Cations 152
Precipitation of Metal Ions as Phenanthroline Complexes 159
Precipitation of Metal Cations with Complex Anions 165
References 168
CHAPTER 7. MISCELLANEOUS ANALYTICAL APPLICATIONS 170
Masking and Scavenger Reagents 170
Fluorescimetric Reagents 172
Oxidation-reduction Reagents 175
Aids in Separations 178
Some Special or Unusual Applications 179
References 181
CHAPTER 8. DETERMINATION AND RECOVERY OF 1,10-PHENANTHROLINE AND 2,2'-BlPYRIDINE
183
AUTHOR INDEX 188
SUBJECT INDEX 198
| Erscheint lt. Verlag | 22.10.2013 |
|---|---|
| Sprache | englisch |
| Themenwelt | Naturwissenschaften ► Chemie ► Analytische Chemie |
| Naturwissenschaften ► Chemie ► Anorganische Chemie | |
| Technik | |
| ISBN-10 | 1-4831-5656-7 / 1483156567 |
| ISBN-13 | 978-1-4831-5656-9 / 9781483156569 |
| Haben Sie eine Frage zum Produkt? |
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