Molecular Beam Epitaxy -

Molecular Beam Epitaxy (eBook)

Brian R. Pamplin (Herausgeber)

eBook Download: PDF
2017 | 1. Auflage
180 Seiten
Elsevier Science (Verlag)
978-1-4831-5533-3 (ISBN)
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Molecular Beam Epitaxy introduces the reader to the use of molecular beam epitaxy (MBE) in the generation of III-V and IV-VI compounds and alloys and describes the semiconductor and integrated optics reasons for using the technique. Topics covered include semiconductor superlattices by MBE; design considerations for MBE systems; periodic doping structure in gallium arsenide (GaAs); nonstoichiometry and carrier concentration control in MBE of compound semiconductors; and MBE techniques for IV-VI optoelectronic devices. The use of MBE to fabricate integrated optical devices and to study semiconductor surface and crystal physics is also considered.
This book is comprised of eight chapters and opens with an overview of MBE as a crystal growth technique. The discussion then turns to the deposition of semiconductor superlattices of GaAs by MBE; important factors that must be considered in the design of a MBE system such as flux uniformity, crucible volume, heat shielding, source baffling, and shutters; and control of stoichiometry deviation in MBE growth of compound semiconductors, along with the effects of such deviation on the electronic properties of the grown films. The following chapters focus on the use of MBE techniques for growth of IV-VI optoelectronic devices; for fabrication of integrated optical devices; and for the study of semiconductor surface and crystal physics. The final chapter examines a superlattice consisting of a periodic sequence of ultrathin p- and n-doped semiconductor layers, possibly with intrinsic layers in between.
This monograph will be of interest to chemists, physicists, and crystallographers.
Molecular Beam Epitaxy introduces the reader to the use of molecular beam epitaxy (MBE) in the generation of III-V and IV-VI compounds and alloys and describes the semiconductor and integrated optics reasons for using the technique. Topics covered include semiconductor superlattices by MBE; design considerations for MBE systems; periodic doping structure in gallium arsenide (GaAs); nonstoichiometry and carrier concentration control in MBE of compound semiconductors; and MBE techniques for IV-VI optoelectronic devices. The use of MBE to fabricate integrated optical devices and to study semiconductor surface and crystal physics is also considered. This book is comprised of eight chapters and opens with an overview of MBE as a crystal growth technique. The discussion then turns to the deposition of semiconductor superlattices of GaAs by MBE; important factors that must be considered in the design of a MBE system such as flux uniformity, crucible volume, heat shielding, source baffling, and shutters; and control of stoichiometry deviation in MBE growth of compound semiconductors, along with the effects of such deviation on the electronic properties of the grown films. The following chapters focus on the use of MBE techniques for growth of IV-VI optoelectronic devices; for fabrication of integrated optical devices; and for the study of semiconductor surface and crystal physics. The final chapter examines a superlattice consisting of a periodic sequence of ultrathin p- and n-doped semiconductor layers, possibly with intrinsic layers in between. This monograph will be of interest to chemists, physicists, and crystallographers.

Front Cover 1
Molecular Beam Epitaxy 4
Copyright Page 5
Table of Contents 6
CHAPTER 1. INTRODUCTION 8
REFERENCES 9
CHAPTER 2. SEMICONDUCTOR SUPERLATTICES BY MBE AND THEIR CHARACTERIZATION 10
ABSTRACT 10
1. INTRODUCTION 10
2. SUPERLATTICES BY MBE 11
3. ELECTRONIC PROPERTIES 13
ACKNOWLEDGMENT 17
REFERENCES 17
THE AUTHORS 20
CHAPTER 3. DESIGN CONSIDERATIONS FOR MOLECULAR BEAM EPITAXY SYSTEMS 22
ABSTRACT 22
1. INTRODUCTION 22
2. THE MBE PROCESS 22
3. THE MBE SYSTEM 24
REFERENCES 37
THE AUTHORS 38
CHAPTER 4. NONSTOICHIOMETRY AND CARRIER CONCENTRATION CONTROL IN MBE OF COMPOUND SEMICONDUCTORS 40
ABSTRACT 40
1. THERMODYNAMIC FOUNDATIONS 41
2. II-VI COMPOUNDS 46
3. III-V COMPOUNDS 46
4. IV-VI COMPOUNDS 48
5. CONCLUSIONS 52
ACKNOWLEDGEMENT 52
REFERENCES 52
THE AUTHOR 54
CHAPTER 5. MBE TECHNIQUES FOR IV-VI OPTOELECTRONIC DEVICES 56
ABSTRACT 56
1. INTRODUCTION 57
2. TECHNIQUES FOR MOLECULAR-BEAM EPITAXY 58
3. THE CRYSTAL PERFECTION OF IV-VI EPITAXIAL LAYERS 62
4. PHOTODIODE PERFORMANCE AS A CRITERION FOR CRYSTAL QUALITY 70
5. THIN-FILM VI-VI SEMICONDUCTOR PHOTODIODES 72
6. UNCONVENTIONAL THIN-FILM IV-VI PHOTODIODES 79
7. OPTICAL WAVEGUIDES 82
8. INJECTION LASERS 85
9. CONCLUSIONS 96
REFERENCES 97
THE AUTHORS 101
CHAPTER 6. INTEGRATED OPTICAL DEVICES FABRICATED BY MBE 102
1. INTRODUCTION 102
2. GaAs AND RELATED ALLOYS 103
3. MOLECULAR BEAM EPITAXY 104
4. WAVEGUIDES 104
5. DISCRETE LASERS 110
6. LASER INTEGRATION 112
7. COUPLERS 114
8. SWITCHES, MODULATORS AND DETECTORS 115
9. MULTI-COMPONENT INTEGRATION 115
10. CONCLUSIONS 115
REFERENCES 117
THE AUTHORS 119
CHAPTER 7. SEMICONDUCTOR SURFACE AND CRYSTAL PHYSICS STUDIED BY MBE 122
Abstract 122
1. Introduction 122
2. Substrate preparation 124
3. Surface structures 126
4. Adsorption and Desorption 130
5. Surface and Interface States on Semiconductors 143
References 148
THE AUTHOR 151
CHAPTER 8. PERIODIC DOPING STRUCTURE IN GaAs 152
ABSTRACT 152
1. INTRODUCTION 152
2. ELECTRONIC PROPERTIES OF nipi CRYSTALS 153
3. MBE GROWTH OF DOPING STRUCTURES IN GaAs 162
REFERENCES 173
THE AUTHORS 175
SUBJECT INDEX 176
COMPOUND INDEX 180

Erscheint lt. Verlag 31.8.2017
Sprache englisch
Themenwelt Naturwissenschaften Chemie
Naturwissenschaften Physik / Astronomie Elektrodynamik
Technik
ISBN-10 1-4831-5533-1 / 1483155331
ISBN-13 978-1-4831-5533-3 / 9781483155333
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