Acidity and Basicity of Solids

Historical Perspectives of Acidity and Basicity. Part 1: 4000 B.C. – 1800 A.D..- Historical Perspectives of Acidity and Basicity. Part 2: 1800 A.D. -.- Theory of Acids and Bases. I. Relationships between Structure and Acidity and Basicity. II. Theory of Medium Effects on Acidity and Basicity.- Quantum Mechanical Study of Acid Base Reactions in the Solid State.- Acidity and Basicity Concepts: The Density Functional Viewpoint Based on an Atoms-in-Molecules Sensitivity Analysis - a Tutorial.- The Acid Function in Zeolites.- Basicity in Zeolites.- The Nature of Lewis Acid Sites of Aluminium Oxide and in Zeolites as Studied by IR Spectra of Adsorbed Hydrogen.- Structure and Composition Factors in the Acidity and Basicity of Inorganic Molecular Metal-Oxygen Cluster Catalysts and Their Influence on the Surface and Catalytic Properties.- The Acidity and Basicity of Solids: Intrinsic Properties of the surface, Its Structure and Composition.- Characterization of Brönsted and Lewis Acidity by Nuclear Magnetic Resonance Spectroscopy.- Characterization of Brönsted Acidity of Solids by Rigid-Lattice Broad-Line 1H-NMR. Part 1: Methodology.- Comparison of Different Zeolites Studied by two Proton NMR Techniques: Broad-Line at 4 K and High Resolution Mas at 300 K.- Catalytic Chemistry of Perfluorinated Resinsulfonic Acids: Reactions, Mechanistic Aspects and Superelectrophilic Activation.- The Mechanism of Proton Transfer and the Nature of Protonated Intermediates in Heterogeneous Acid Catalysis.- Acid-Base Bifunctional Catalysis.- Generation of Acidity (Amount and Strength) in Silicoaluminophosphates (SAPO Zeolites). Examples of SAPO-5, -11, -34 and -37.- Determination of Silicon Coordination Spheres in SAPO-37 Molecular Sieve with MS-EXCEL.- Importance of Preparation of Acidic andBasic Solid Materials.- Regulation of Surface Acidity of Oxidic Carriers used for the Preparation of Supported Catalysts.- Industrial Catalytic Applications of Acidic Molecular Sieves.- Application of Solid Acids and Bases to Various Fields.- Characterization of Brönsted Acidity of Solids by Rigid-Lattice Broad-Line 1H-NMR. Part 2: Applications.- Closing Remarks.