Oxygen Complexes and Oxygen Activation by Transition Metals
Springer-Verlag New York Inc.
978-1-4612-8263-1 (ISBN)
Opening Remarks.- Dioxygen Complexes with Transition Metals.- Bonding of Dioxygen to Transition Metals.- Oxygen Binding by the Metalloproteins Hemerythrin, Hemocyanin, and Hemoglobin.- Metal Oxo Complexes and Oxygen Activation.- Kinetics of Formation of Biological Oxygen Carriers.- Synthetic Dioxygen Carriers for Dioxygen Transport.- Formation and Degradation of Cobalt Dioxygen Complexes.- Reversible Complexes for the Recovery of Dioxygen.- Summary - Dioxygen Complexes with Transition Metals.- Oxygen Activation by Transition Metals.- Summary - Oxygen Activation by Transition Metals.- The Chemistry and Activation of Dioxygen Species (02, 02-., and H00H) in Biology.- Oxygen Activation by Neutrophils.- Mechanisms of Dioxygen Activation in Metal-Containing Monooxygenases: Enzymes and Model Systems.- Radical Cation Pathways for Selective Catalytic Oxidation by Molecular Oxygen.- Vanadium Catalyzed Autoxidation of Hydrogen Sulfide.- Copper Catalyzed Oxidative Carbonylation of Methanol to Dimethyl Carbonate.- Dependence of Reaction Pathways and Product Distribution on the Oxidation State of Palladium Catalysts for the Reactions of Olefinic and Aromatic Substrates with Molecular Oxygen.- Oxygen Activation and Oxidation Reactions on Metal Surfaces.- Methane Oxidation at Metal Oxide Surfaces.- The Activation of Oxygen by Metal Phosphorus Oxides - The Vanadium Phosphorus Oxide Catalyst.- The Oxidation of Organic Compounds by Metal Complexes in Zeolites.- Abstracts of Posters.- Kinetics and Mechanisms of Degradation of Binuclear Cobalt Dioxygen Complexes.- Methane Activation over Lanthanide Oxides.- Dioxygen Affinities of Some Synthetic Cobalt Schiff Base Complexes.- Temporal Analysis of Products (TAP): A Unique Catalyst Evaluation System with Sub-Millisecond Time Resolution.- Dioxygen Insertion into Metal-Carbon Bonds of Metalloporphyrins: Formation and Characterization of Alkylperoxy Metalloporphyrins.- Iron Porphyrin Catalyzed Air Oxidation of Aldehydes and Alkenes.- Oxidative Dimerization of Methane over Sodium-Promoted Calcium Oxides.- Synthesis and Metal Ion Affinities of a Binucleating Polyamine: Reversible Formation of a Cobalt Dioxygen Complex.- Potentiometric Determination of Stabilities of Cobalt(II) Complexes of Polyamine Schiff Bases and Their Dioxygen Adducts.- Catalysis of Cobalt Schiff Base Complexes for the Oxygenation of Olefins. Mechanisms for the Ketonization Reaction.- Selective Oxidation of Saturated Hydrocarbons by the Gif and Gif-Orsay Systems.- The Formation, Characterization, and Reactivity of the Oxene Adduct of Tetrakis(2,6-dichlorophenyl)porphinato-Iron(III) Perchlorate in Acetonitrile.- Preparation and Characterization of a Binuclear Iron(III)- Hydroxo-y-hydroperoxy Complex [(Ph3PO)4(HO)FeIII(HOOH)FeIII(OH)(OPPh3)4](C1O4)4.- Autoxidation of FeII(dihydroxyphenanthroline)3.- Phosphine-Ruthenium(II)-Aquo Redox Chemistry: The Aerobic Catalytic Oxidation of Cyclohexene.- The Oxidation of Organic Substrates by Molecular Oxygen; Catalysis by Ru(III) and Ru(III)-EDTA.- Oxygenation of Tryptophane Catalyzed by Polyamine Cobalt Dioxygen Complexes.- Resonance Raman Spectroscopy of the Fe(IV)=0 Group in Peroxidase Intermediates.- Reaction of Dioxygen with Synthetic Copper(I) Compounds of Biological Relevance.- Thorough Elucidation of Oxygenation- and Oxidation-Mechanisms of Iron(II) Porphyrin on the Basis of a New Hypothesis for an Electron-Transfer Pathway.- IUCCP Description.
Erscheint lt. Verlag | 12.10.2011 |
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Zusatzinfo | X, 342 p. |
Verlagsort | New York, NY |
Sprache | englisch |
Maße | 170 x 244 mm |
Themenwelt | Naturwissenschaften ► Biologie ► Biochemie |
Naturwissenschaften ► Chemie ► Anorganische Chemie | |
ISBN-10 | 1-4612-8263-2 / 1461282632 |
ISBN-13 | 978-1-4612-8263-1 / 9781461282631 |
Zustand | Neuware |
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