Dissociative Recombination

Proceedings of a NATO ARW held in Saint Jacut de la Mer, Brittany, France, May 3-8, 1992

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InMay1988,theFirstInternationalConferenceonDissociativeRecombination:Theory, ExperimentandApplicationswasheldatChateauLakeLouise,Alberta,Canada. Thismeeting gaveaconsiderableimpetustothissubject,whichisofparticularinterestforalargevarietyof fieldsincludinginterstellarclouds,planetaryatmospheres,gaslasers,plasmaprocessing,ion sourcesandthermonuclearplasmas. Sincethen,indeed,severalcollaborationswereinitiated betweenexperimentalistsworkingwithdifferenttechniques,betweentheoreticiansdealingwith molecularstructureononehandanddynamicsontheotherhandandalsobetween experimentalistsandtheoreticians. Duringthelastfouryears,therefore,alargenumberof studieswerecarriedoutandraisedanewsetofquestions. Moreparticularly,theresultsthat wereobtainedconcerningcontroversialspeciessuchasH!andHeir,castingsomedoubton theverymechanismsbywhichdissociativerecombinationproceeds. The Second International Conference on Dissociative Recombination: Theory, ExperimentandApplications heldat"I'AbbayedeSaintJacutdelaMer",Brittany,France, May3-8,1992,camethereforeattherighttimetosurveythecurrentstateofthesubject.
The symposiumbroughttogetherleadinginvestigatorsinthefieldsofmolecularionrecombination research,atomicandmoleculartheoryandexperiment,plasmasphysics,astrochemistryand aeronomy. Speakerspresentedtalksreviewingtheirownworkandthesewerefollowedby livelydiscussionsessions. Freetimeperiodsallowedparticipantstodiscoveranenchanting peninsulaofNorthBrittanywhilepursuingstimulatingscientificdiscussions. Thepapersinthis volumearebasedonthesetalksandfurtherdiscussions,withtheexceptionofcontributions fromT. AmanoandB. M. McLaughlinwhowereunabletoattend. Alistofparticipantsas wellasasouvenirgroupphotoisgivenattheendofthebook. WeareindebtedtoNATOforitsfinancialsupportwhichcontributedtothegreat successofthissecondmeeting. TheUniversityofRennesIandtheBalzerscompanyarealso acknowledgedfortheiradditionalsupportManythankstothewholestaffoftheabbeyforits kindnessandeffortsinprovidinguswithapropitiousenvironmentforsuchaworkshop. We arealsogratefultoL. Caubetforhervaluableadministrativeassistanceduringthepreparation ofthemeeting. Finallyaspecialmentionmustbegiventoallthesessionchairpersonsfortheir skillinorchestratingthediscussions. Lookingforwardtoattendingthethirdmeeting. TheEditors Bertrand R. Rowe J.
Bria/l A. Mitchell Andre Callosa DepartementdePhysique DepartmentofPhysics DepartementdePhysique AtomiqueetMoleculaire TheUniversityofWesternOntario AtomiqueetMoleculaire UniversitedeRennesI London,Canada,N6A3K7 UniversitedeRennesI CampusdeBeaulieu CampusdeBeaulieu 35042RennesCedex, 35042RennesCedex, France France v CONTENTS ORALCONTRIBUTIONS PolyatomicIonDissociativeRecombination . 1 D. R. Bates RecentDevelopmentsandPerspectivesintheTreatmentofDissociative RecombinationandRelatedProcesses...11 A. Giusti-Suzor, I. F Schneider, and 0. Dulieu CharacteristicsofSuperexcitedStatesofMoleculesandMQDTStudiesofNO+ DissociativeRecombination...25 H. Sun, K. Nakashima, and H. Nakamura CalculationsforAr +Xe*andArXe+ +e 35 A. P. Hickman, DL Huestis, and R. P. Saxon Electron-IonContinuum-ContinuumMixinginDissociativeRecombination 47 s. L. Guberman ATheoreticalStudyoftheHCO+andHCS+ElectronicDissociativeRecombinations. . 59 D. Talbi, and Y Ellinger DissociativeRecombinationofCH;:SomeBasicInformationfromElectronic 2 StructureCalculations. 67 WP. Kraemer TheoreticalProblemsintheDissociativeRecombinationofH~ +e...75 H. Takagi RecentMergedBeamsInvestigationsofHydrogenMolecularIonRecombination...87 J B.
A. Mitchell, F B. Yousif, P. Van der Donk, and T. J Morgan vii FlowingAfterglowStudiesofElectron-IonRecombinationusingLangmuirProbesand OpticalSpectroscopy...99 NG. Adams RecentFlowingAfterglowMeasurements . 113 B. R. Rowe InfraredSpectroscopicStudiesoftheDissociativeRecombinationProcessesofH...127 3 T. Amano RecombinationofClusterIons . 135 R. Johnsen PredissociationofExcitedStatesofH . . 145 3 H. Helm AStudyofHe e,3I,;)BoundandContinuumStates...155 2 CJ Gillan, B. M McLaughlin. and P. G. Burke ElectronCollisionInducedExcitationsandDissociationofHeH+usingthe R-MatrixMethod . . 163 BK Sarpal, J Tennyson, and L. A. Morgan AssociativeIonisationofHydrogen:ExperimentswithFastMergedBeams...173 F Brouillard, andX Urbain TheoryoftheAsssociativeIonisationReactionbetweenTwoLaser-Excited . 187 SodiumAtoms 0. Du!ieu, A. Giusti-Suzor, andF Masnou-Seeuws ResonantTheoryofDissociativeAttachment...195 J. J. Fabrikant MicroscopicandMacroscopicTheoriesofTermolecularRecombinationbetween AtomicIons...205 MR. Flannery DissociativeRecombinationinPlanetaryIonospheres . . 219 JL. Fox ChemistryofSupernova1987a . 243 A. Dalgarno DissociativeRecombinationinInterstellarClouds . .