Silicon-mediated Transformations of Functional Groups (eBook)

Introduction
Techniques of Preparative Silylation and Desilylations
Preparation and Properties of Siliconoxy-Leaving Groups
Reactions of Free and Derivatized Carboxylic Acids and Carbonates
Reactions of Aldehydes and Ketones
Reactions of Alcohols, Ethers and Epoxides
Reactions of N-O Systems
Reactions of S-O and Se-O Systems
Cyclizations and Ring Enlargements
Acid- and Base (Fluoride) Catalyzed Eliminations of Trimethylsilanol and Trimethylsilyl Fluoride
Formation of Carbon-Phosphorous Double- and Triple Bonds
Reductions and Oxidations
Dehydration-Activation as well as Silylation of Metalorganic Compounds and of Inorganic Salts
Formation of Polymers Introduction
Techniques of Preparative Silylation and Desilylations
Preparation and Properties of Siliconoxy-Leaving Groups
Reactions of Free and Derivatized Carboxylic Acids and Carbonates
Reactions of Aldehydes and Ketones
Reactions of Alcohols, Ethers and Epoxides
Reactions of N-O Systems
Reactions of S-O and Se-O Systems
Cyclizations and Ring Enlargements
Acid- and Base (Fluoride) Catalyzed Eliminations of Trimethylsilanol and Trimethylsilyl Fluoride
Formation of Carbon-Phosphorous Double- and Triple Bonds
Reductions and Oxidations
Dehydration-Activation as well as Silylation of Metalorganic Compounds and of Inorganic Salts
Formation of Polymers

"This handbook is a clear, compact compilation ... an essential practical and reference book for the research chemist." Applied Organometallic Chemistry

"This monograph contains a lot of valuable information and stimulating ideas, which show how the chemist engaged in synthesis can profitably use silyl groups not only as protecting groups but also as activating groups in organic transformations." Angewandte Chemie I.E.

"...very informative and should be of great interest to practicing organic chemists."
Journal of the American Chemical Society

"In summary, this book represents a very valuable reference for the covered fields. It is recommended for every good library collection and will surely find a place on the shelves of the scientists acting in that area." Synthesis

"Das vorliegende Buch vermittelt einen sehr umfassenden, breiten Überblick über unterschiedliche Reagenzien und Reaktionen und ihre Anwendungsgebiete. ... ein sehr gutes Nachschlagewerk, das etliche, alternative Umsetzungen für viele Synthese-Probleme zeigt."
www.organische-chemie.ch

"Für Synthesechemiker birgt das Buch eine Vielzahl an wertvollen Informationen und Anregungen, die aufzeigen, wie Silylgruppen nicht nur als Schutzgruppen, sondern auch als aktivierende Gruppen in organisch-chemischen Transformationen gewinnbringend einzusetzen sind."
Angewandte Chemie