Spectroscopy (eBook)

Cover 1
Dedication 3
Imprint 6
Preface 7
Foreword 9
Content 11
1 Introduction 13
1.1 Definitions and Systematics 13
1.2 Structure_Property Relations, Synthesis, and Process Planning 14
1.3 Development of Computers, Dynamics of Analytical Methods, and Process Control 18
1.4 Economic Significance of Analytical Methods 21
1.5 On the Conception of the Book 24
2 The Electromagnetic Spectrum 27
2.1 Its Regions and Present-Day Comprehension 27
2.2 The Instrumentation 33
3 The Absorption Processes and their Energies 43
3.1 The UV and Visible Region 45
3.2 The IR and Near IR (NIR) Region 54
3.3 The ESR Region 62
3.4 The NMR Region 71
3.5 A Comparative View 97
4 The Absorption Intensities: Prerequisites and Consequences 107
4.1 The UV and Visible Region 108
4.2 The IR and Near IR (NIR) Region 117
4.3 The ESR Region 122
4.4 The NMR Region 124
4.5 A Comparative View 136
5 Spectroscopy of Analytes in the four Phases 143
5.1 The Gas Phase 144
5.2 The Liquid Phase 145
5.3 Liquid Crystalline Phases 148
5.4 Solid-State Phases 151
5.5 Sample Preparation and Sample Purity 169
5.6 Internal and External Standards 177
6 The Measuring Techniques: CW and FT Spectroscopy 181
6.1 CW Spectroscopy 181
6.2 FT Spectroscopy 185
7 Spectroscopy in Two and Three Dimensions 199
7.1 1D Pulse Sequences in NMR Spectroscopy 200
7.2 Two-Dimensional (2D) and Three-Dimensional (3D)Spectroscopy 210
8 Application Areas and Limits 219
8.1 Structure Analyses 220
8.1.1 The Positions of Absorption Bands 221
8.1.2 Scalar Couplings, NOEs, and Relaxation Times 251
8.1.3 Solid-State Spectroscopy 267
8.1.4 Two- and Three-Dimensional Spectroscopy 277
8.2 Concentration and Kinetic Measurements 283
8.3 Dynamic Aspects 296
8.4 Diffusion Measurements and Imaging Spectroscopy 306
8.5 Opt(r)odes and Sensors, Tandem or Combined Methods 317
8.6 Chemometry 320
9 The Communication of Spectroscopic Data 323
10 Literature 329
10.1 A Selection of Textbooks and Standard Works 329
10.2 My Favorite Books 330
Addendum 331
Acronym, Name, and Keyword Index 337