Novel Selenium-Mediated Rearrangements and Cyclisations

Buch | Hardcover
XX, 192 Seiten
2012 | 2013
Springer Berlin (Verlag)
978-3-642-33172-5 (ISBN)
106,99 inkl. MwSt
This book investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. Details electrophilic selenium-mediated reactions and strategies using selenium catalysts and more.
In his thesis, Sohail Shahzad carefully investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. After a comprehensive introduction to the element selenium, the author goes on to report the synthesis of several substrates for carbocyclisation reactions and the use of selenium reagents for the preparation of dihydronaphthalenes. Further chapters detail electrophilic selenium-mediated reactions, and novel strategies using selenium catalysts together with stoichiometric amounts of hypervalent iodine reagents as oxidants to convert stilbene carbosylic acids into the corresponding isocoumarins. This thesis outlines some excellent new synthetic routes which will be useful tools for synthetic organic chemistry in the future.

General Introduction on Selenium.- The Synthesis of Novel Dihydronaphthalenes and Benzofluorenes.- The Synthesis of Naphthalenes and Biaryls.- Synthesis of Isocoumarins and Dihydroisocoumarins.- Experimental Section.

Erscheint lt. Verlag 11.10.2012
Reihe/Serie Springer Theses
Zusatzinfo XX, 192 p.
Verlagsort Berlin
Sprache englisch
Maße 155 x 235 mm
Gewicht 454 g
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
Naturwissenschaften Chemie Organische Chemie
Schlagworte Benzoflueorenes • Biaryls • Carobocyclizations • Dihydroisocoumarins • Dihydronaphthalenes • Diselenide • Diselenide Catalyzed O-Cyclizations • Friedel-Crafts Acylations • Selenium Electrophiles • Selenium-Mediated Rearrangements
ISBN-10 3-642-33172-6 / 3642331726
ISBN-13 978-3-642-33172-5 / 9783642331725
Zustand Neuware
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