Time-Dependent Reactivity of Species in Condensed Media
Springer Berlin (Verlag)
978-3-540-16796-9 (ISBN)
1. Introduction.- 2. Reaction kinetics of species trapped in glassy matrices.- Excess electrons.- Hydrogen atoms.- Alkyl radicals.- Disproportionation of Cl?2.- 3. Kinetic behaviour of water radiolysis products in polycrystalline ice.- Trapped electrons.- Hydrogen atoms.- Hydroxyl radicals.- Structural relaxation in polycrystalline ice.- Some other polycrystalline systems.- 4. Decay of radicals in polymer matrices.- Allyl radicals in polyethylene.- Propagating radicals in poly(methyl methacrylate).- ITL of X-irradiated polystyrene.- 5. Lifetime distributions of photoproduced cation-radicals in micelles.- Time-dependent reactivity of species embedded in micelles.- Solvent isotope effect.- Effect of micellar interface modification on reactivity of embedded species.- Distribution of activation energy for decay of embedded species.- Kinetic behaviour of photoe jected electrons.- 6. Molecular origins of reactivity distribution in condensed media.- Time-dependent rate constant in CTRW model.- CTRW model of nonexponential relaxation.- Barrier dispersion model of waiting-time distribution function.- 7. Appendices.- A. Kinetics with time-dependent rate constant.- B. Inverse Laplace transform of Kohlrausch relaxation function.
Erscheint lt. Verlag | 1.9.1986 |
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Reihe/Serie | Lecture Notes in Chemistry |
Zusatzinfo | VI, 152 p. |
Verlagsort | Berlin |
Sprache | englisch |
Maße | 170 x 244 mm |
Gewicht | 271 g |
Themenwelt | Naturwissenschaften ► Chemie ► Physikalische Chemie |
Schlagworte | Atom • Behavior • Crystal • data treatment • Dispersion • Dynamics • electron • Electrons • Energy • Fields • Hydrogen • Isotope • Kinetics • Kondensat • Polymer • Radiation |
ISBN-10 | 3-540-16796-X / 354016796X |
ISBN-13 | 978-3-540-16796-9 / 9783540167969 |
Zustand | Neuware |
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