Nanotechnology in Mesostructured Materials (eBook)

Cover 1
Contents 6
Preface 20
Organizing committee 22
International advisory board 23
Local advisory board 23
Supporting organizations 24
Financial support 24
Part I: Synthesis and materials 26
Chapter 1. A new family of organic-bridged mesoporous materials 26
Chapter 2. Strategies to fabricate large-pore three-dimensional mesoporous materials with versatile applications 34
Chapter 3. Mesostructured solid acids 40
Chapter 4. Template synthesis and catalysis of metal nanowires in mesoporous silicas 48
Chapter 5. Mesostructured silica films with crystalline domains and structural features on multiple length scales 54
Chapter 6. Synthesis of mesoporous carbons with various pore diameters via control of pore wall thickness of mesoporous silicas 58
Chapter 7. Ordered mesoporous carbon molecular sieves with functionalized surfaces 62
Chapter 8. Characterisation of ordered mesoporous carbons and their MCM-48 silica templates obtained by the replication technique using different carbon infiltration processes 66
Chapter 9. Morphological control of highly ordered mesoporous carbon 70
Chapter 10. Thermally induced structural changes in SBA-15 and MSU-H silicas and their implications for synthesis of ordered mesoporous carbons 74
Chapter 11. Regeneration of mesoporous inorganic materials using ordered mesoporous carbon as the template 78
Chapter 12. A novel preparation route for palladium-carbon composite materials - pore filling of SBA-15 mesoporous molecular sieve 82
Chapter 13. Structure of ultra-thin RbBr "Solution" in carbon nanospace 86
Chapter 14. Synthesis and characterization of mesoporous silica films by spin-coating on silicon: photoionization of methylphenothiazine and photoluminescence of erbium 8-Hydroxyquinolinate in mesoporous silica films 90
Chapter 15. Synthesis of 2D hexagonal mesoporous silica thin films via phase transition from lamellar structure 94
Chapter 16. Nanostructured silicate film templated by discotic CT-complex column 98
Chapter 17. Mesoporous titania thin film with cubic mesostructure using photocalcination 102
Chapter 18. Preparation of tin modified silica mesoporous film 106
Chapter 19. Novel non-lithographic large area fabrication method to generate various polymeric nanostructures 110
Chapter 20. Mesoporous anodic alumina mbembrane with highly ordered arrays of uniform nanohole 114
Chapter 21. Preparation and characterization of poly(ester)-silver and nylon-silver nanocomposites 118
Chapter 22. Synthesis of ordered three-dimensional large-pore mesoporous silica and its replication to ordered nanoporous carbon 122
Chapter 23. Morphology control of mesoporous SBA-16 using microwave irradiation 126
Chapter 24. One-Step synthesis of mesoporous silica SBA-15 with ultra-high microporosity 130
Chapter 25. Controlling the pore sizes of SBA-15 mesoporous silica by the addition of poly(propylene oxide) 134
Chapter 26. Synthesis of mesoporous silicas with different pore size by using EOmMAn diblock copolymers of tunable block length as the templates 138
Chapter 27. Polypropylene glycol as a swelling agent for the synthesis of mesoporous silica (SBA-15) by amphiphilic block copolymer templating 142
Chapter 28. Thermal decomposition-precipitation inside the nanoreactors high loading of W-oxide nanoparticles into the nanotubes of SBA-15 146
Chapter 29. Phase transition of SBA-1 induced by embedded heteropoly acids 150
Chapter 30. A further investigation on effect of basic media on the synthesis of MCM-41 154
Chapter 31. Cationic templating with organic counterion for superstable mesoporous silica 158
Chapter 32. The synthesis of mesoporous materials with semicrystalline microporous walls 162
Chapter 33. Synthesis of a mesoporous molecular sieve with hydrothermal stability 166
Chapter 34. Diffusive characterization of large pore mesoporous materials with semi-crystalline zeolitic framework 170
Chapter 35. Synthesis of cubic mesoporous aluminosilicates with enhanced acidity 174
Chapter 36. Synthesis and characterization of supersurface MCM-41 zeolite using additives 178
Chapter 37. Preparation of large pore high quality MCM-48 silica by a simple post-synthesis hydrothermal treatment 182
Chapter 38. Synthesis and properties of aluminosilicate mesoporous material with adjustable pore structure 186
Chapter 39. Variation of the pore properties of mesoporous silica after washing by water and ethanol-water solutions 190
Chapter 40. Sythesis of ordered lamella mesophase from helix layered silicate (HLS) 194
Chapter 41. Sythesis of monolithic nanostructured silicate family materials through the lyotropic liquid crystalline mesophases of non-ionic surfactant 198
Chapter 42. Synthesis and characterization of a new mesoporous molecular sieve 202
Chapter 43. Direct- and post-hydrothermal treatments in ammoniated solution for the morphogenesis of mesoporous silica nanotubes 206
Chapter 44. Generalized homogeneous precipitation method for precisely controlled synthesis of mesoporous silicas 210
Chapter 45. Synthesis of mesoporous silica particles preapared by using multiple emulsion 214
Chapter 46. Preparation and characterization of mesoporous silica spheres by polymerization induced colloid aggregation method 222
Chapter 47. Preparation of mesoporous solids by agglomeration of silica nanospheres 222
Chapter 48. Ordered mesostructured materials with composite walls of decavanadate and silica 226
Chapter 49. Nanoporous alumina formation using mulit-step anodization and cathodic electrodeposition of metal oxides on its structure 230
Chapter 50. Synthesis of mesoporous .-aluminas of controlled pore properties using alkyl carboxylate assisted method 234
Chapter 51. Synthesis and characterization of mesoporous alumina molecular sieves using cationic surfactants 238
Chapter 52. Synthesis and characterization of mesoporous alumina molecular sieves with cationic surfactants in the presence of formamide 242
Chapter 53. Structure and properties of porous mesostructured zirconium oxo-phosphate with cubic(Ia-3d) symmetry 246
Chapter 54. Synthesis and characterization of mesoporous titanium oxide 252
Chapter 55. Improvement of thermal stability of Ti-Zr mesoporous oxides using CTAB surfactant templates mixed with auxiliary organic additives 256
Chapter 56. Synthesis and characterization of mesoporous zirconia 260
Chapter 57. A novel method to prepare mesoporous nano-zirconia 264
Chapter 58. Control of ordered mesoporous molecular sieves synthesis using non-ionic surfactants by incorporation of transition metal ions in the micellar solution 268
Chapter 59. Texture of chromia aerogels and structure of their nanocrystals 272
Chapter 60. Preparation of ordered mesoporous NbTa mixed oxide with crystallized wall 276
Chapter 61. Compositional effects of bimodal mesopore silica synthesized by a base-catalyzed ambient pressure sol-gel processing 280
Chapter 62. A direct template synthesis of highly ordered mesostructured carbons using as-synthesized MCM- 48 as template 284
Part II: Characterization 288
Chapter 63. Gas adsorption: a valuable tool for the pore size analysis and pore structure elucidation of ordered mesoporous materials 288
Chapter 64. Three-dimensional transmission electron microscopy of disordered and ordered mesoporous materials 296
Chapter 65. Structures of silica-mesoporous crystals and novel mesoporous carbon-networks synthesized within the pores 300
Chapter 66. Phase transformations involved during silica, modified silica, and non-silica mesoporous organized thin films deposition. The role of evaporation 306
Chapter 67. Comparison of the mechanical stability of cubic and hexagonal mesoporous molecular sieves with different pore sizes 310
Chapter 68. Fs-time-resolved diffuse reflectance and resonance Raman spectroscopic studies on MCM-41 as microchemical reactor 314
Chapter 69. Detailed investigation of the microporous character of mesoporous silicas as revealed by small- angle scattering techniques 320
Chapter 70. X-ray diffraction analysis of mesostructured materials by continuous density function technique 324
Chapter 71. Influence of aluminium, lanthanum and cerium on the thermal and hydrothermal stability of MCM- 41-type silicates 328
Chapter 72. Enhanced acidity and hydrothermal stability of mesoporous aluminosilicate with secondary building units characteristic of zeolite beta 332
Chapter 73. Chemical coating of the aluminum oxides onto mesoporous silicas by a one-pot grafting method 336
Chapter 74. Acidity and temperature effect on the synthesis of SBA-1 340
Chapter 75. HMS materials with high Al loading: a joint FT-IR and microcalorimetric study of their acidic/basic properties 344
Chapter 76. Effect of cations addition for the highly ordered mesoporous niobium oxide 348
Chapter 77. Synthesis of zirconium-containing mesoporous silica Zr-MCM-48 membranes with high alkaline resistance for nanofiltration 352
Chapter 78. Synthesis of siliceous MCM-41 grafted with transition metal carbonyls 356
Chapter 79. Surface and pore structures of CMK-5 ordered mesoporous carbons studied by nitrogen adsorption and surface spectroscopic methods 360
Chapter 80. A comparison of the sorption properties of mesoporous molecular sieves MCM-41 and MCM-48 364
Chapter 81. Argon and nitrogen adsorption on ordered silicas with channel-like and cage-like mesopores: implications for characterization of porous solids 368
Chapter 82. Mesopores developed in KL zeolite dealuminated with (NH4)2SiF6 solution 372
Chapter 83. Time-resolved in situ grazing incidence small angle x-ray scattering experiment of evaporation induced self-assembly 376
Chapter 84. Small angle neutron scattering study on the formation mechanism of mesostructures during sol-gel processing 380
Chapter 85. Preparation of mesoporous silica anchored Mo catalysts and in-situ XAFS characterization under propene photometathesis reaction 384
Chapter 86. In-situ XAFS observation of formation of Pd-Pt bimetallic particles in a mesoporous USY zeolite 388
Chapter 87. Investigation of the internal pore structures of Beta/MCM-41 and ZSM-5/MCM-41 composites by 129Xe NMR 392
Chapter 88. Study of chromium species in the Cr-MCM-48 mesoporous materials by Raman spectroscopy 396
Chapter 89. Covalent bonding of Disperse Red 1 in HMS silica: synthesis and characterization 400
Chapter 90. Accessibility of dye-molecules embedded in the micellar phase of hybrid mesostructured MCM41- type materials 404
Chapter 91. Influence of surface properties of MCM-48 on the formation of a nanocomposite structure based on MCM-48 and PVA 408
Chapter 92. A study on the structure of Si-O-C thin films with nano size pore by ICPCVD 412
Chapter 93. Template effects on low k materials made from spin-on mesoporous silica 416
Chapter 94. Porosity tuning of single-wall carbon nanohoms with gaseous activation 420
Part III: Modification and composite 424
Chapter 95. Expanding horizons of mesoporous materials to non-siliceous systems 424
Chapter 96. Structure and shape control in functional mesostructured materials from block copolymer mesophases 432
Chapter 97. Strategies for spatially separating photoactive molecules in mesostructured sol-gel silicate films 438
Chapter 98. Design of supported catalysts by surface functionalization of micelle-templated silicas 444
Chapter 99. Proteosilica-mesoporous silicates densely filling amino acid and peptide assemblies in their nanoscale pores – 452
Chapter 100. Counteranion effect on the formation of mesoporous materials under acidic synthesis process 456
Chapter 101. Influence of alumination pathway on the steam stability of Al-grafted MCM-41 460
Chapter 102. Macroporous titanium oxides: from highly aggregated to isolated hollow spheres 464
Chapter 103. Nanostructured mesoporous TiO2, ZrO2 and SiO2 synthesis by using the non-ionic Cm(EO)n inorganic alkoxyde system : toward a better understanding on the formation mechanism 468
Chapter 104. Morphology control of hierarchically ordered ceramic materials prepared by surfactant-directed sol-gel mineralization of wood cellular structures 472
Chapter 105. A NH3-responding material based on Reichardt's dye-impregnated mesoporous silica 478
Chapter 106. Preparation and redox behavior of ordered porous zirconium oxide loaded with cerium 482
Chapter 107. Direct synthesis of bi-fimctionalized organo-MSU-X silicas 486
Chapter 108. High-density modification of mesoporous silica inner walls with amino acid function by residue transfer from template 490
Chapter 109. The synthesis of optically active amino acid over Pd catalysts impregnated on mesoporous support 494
Chapter 110. Sulfonic acid-functionalized periodic mesoprous organosilicas 498
Chapter 111. Functionalized periodic mesoporous organosilicas with sulfonic acid group 502
Chapter 112. Exclusive incorporation of aluminum into tetrahedral site of the framework of periodic mesoporous organosilica 506
Chapter 113. Functionalization of hexagonal mesoporous silica and their base-catalytic performance 510
Chapter 114. Microstructure of the organo-modified SBA-15 (Vinyl-SBA 15) prepared under different pH 514
Chapter 115. Surface coating of MCM-48 via a gas phase reaction with hexamethyldisilazane (HMDS) 518
Chapter 116. Reacitvity of silica walls of mesoporous materials towards benzoyl chloride 522
Chapter 117. Catalytic activitiy of chiral phosphinooxazolidine ligands immobilized on SBA-15 for the asymmetric allylic substitution 526
Chapter 118. Preparation of guanidine bases immobilized on SBA-15 mesoporous material and their catalytic activity in Knoevenagel condensation 530
Chapter 119. MCM-41-supported norephedrine ligand for ruthenium-catalyzed asymmetric transfer hydrogenation of ketones 534
Chapter 120. Synthesis of silica support for biocatalyst immobilization 538
Chapter 121. Mesostructured materials for controlled macromolecular and supramolecular architectures 542
Chapter 122. Nanocomposites of MCM-41 and SBA-15 with polyaniline for electrorheological fluid 548
Chapter 123. Functionalized mesoporous adsorbents for Pt(II) and Pd(II) adsorption from dilute aqueous solution 552
Chapter 124. Environmentally benign removal of pollutant oxyanions by Fe adsorption center in functionalized mesoporous silica 556
Chapter 125. How can nanoparticles change the mechanical resistance of ordered mesoporous thin films? 560
Chapter 126. Nanoporous SiO2 films prepared by surfactant templating method - a novel antireflective coating technology 564
Chapter 127. Textural and structural properties of Al-SBA-15 directly synthesized at 2.9 < pH <
Chapter 128. Fabrication of nanostructured SiC and BN from templated preceramic polymers 572
Part IV: Application and catalysis 576
Chapter 129. Mesoporous solids for green chemistry 576
Chapter 130. Ultrastable acidic MCM-48-S assembled from zeolite seeds 582
Chapter 131. Acidic zeolite coated mesoporous aluminosilicates 586
Chapter 132. Stable ordered mesoporous titanosilicates with active catalytic sites 590
Chapter 133. W/Zr mixed oxide supported on mesoporous silica as catalyst for n-pentane isomerization 594
Chapter 134. Au and Au-Pt bimetallic nanoparticles in MCM-41 materials: applications in CO preferential oxidation 598
Chapter 135. Effective inclusion of chlorophyllous pigments into mesoporous silica for the energy transfer between the chromophores 602
Chapter 136. Biological applications of organically functionalised mesoporous molecular sieves and related materials 606
Chapter 137. One pot synthesis of mesoporous ternary V2O5-TiO2-SiO2 catalysts 610
Chapter 138. Photocatalytic hydroxylation of benzene on Ti-modified MCM-41 with both framework and non framework Ti- centers 614
Chapter 139. The relationship between the local structures and photocatalytic reactivity of Ti-MCM-41 catalysts 618
Chapter 140. Photocatalytic epoxidation of propene with molecular oxygen under visible light irradiation on V ion-implanted Ti-HMS and Cr-HMS mesoporous molecular sieves 622
Chapter 141. Mesostructured TiO2 films as effective photocatalysts for the degradation of organic pollutants 626
Chapter 142. Comparisons of the structural and catalytic properties of Ti-HMS synthesized using the hydrothermal and molecular designed dispersion methods 630
Chapter 143. Oxidation of methyl-propyl-thioether with hydrogen peroxide using Ti-SBA-15 as catalyst 634
Chapter 144. Direct synthesis of hydrothermally stable mesoporous Ti-MSU-G and its catalytic properties in liquid-phase epoxidation 638
Chapter 145. Mesoporous V-containing MCM-41 molecular sieves: synthesis, characterization and catalytic oxidation 642
Chapter 146. Catalytic oxidation of H2S to elemental sulfur over mesoporous Nb/Fe mixed oxides 646
Chapter 147. Fe-MCM-41 catalyzed epoxidation of alkenes with hydrogen peroxide 650
Chapter 148. Highly selective oxidation of styrene with hydrogen peroxide catalyzed by mono- and bimetallic (Ni, Ni-Cr and Ni-Ru) incorporated MCM-41 silicas 654
Chapter 149. Mixed (Al-Cu) pillared clays as wet peroxide oxidation catalysts 658
Chapter 150. Finely-dispersed Ni/Cu catalysts supported on mesoporous silica for the hydrodechlorination of chlorinated hydrocarbons 662
Chapter 151. New SO2 resistant mesoporous mixed oxide catalysts for methane oxidation 666
Chapter 152. Decomposition of VOCs using mesoporous TiO2 in a silent plasma 670
Chapter 153. Preparation of mesoporous 12-tungstophosphoric acid HPW/Si02 and its catalytic performance 674
Chapter 154. Catalytic properties of heteropolyacids supported on MCM-41 mesoporous silica for hydrocarbon cracking reactions 678
Chapter 155. Preparation, characterization and catalytic activity of heteropolyacids supported on mesoporous silica and carbon 682
Chapter 156. Novel SBA-15 supported heteropoly acid catalysts for benzene alkylation with 1-dodecene 686
Chapter 157. Aluminum containing periodic mesoporous organosilicas: synthesis and etherification 690
Chapter 158. Friedel-crafts alkylation over Al-incorporated mesoporous honeycomb 694
Chapter 159. Heterogenization of AICI3 on mesoporous molecular sieves and its catalytic activity 698
Chapter 160. Asymmetric dihydroxylation catalyzed by MCM-41 silica-supported bis-cinchona alkaloid 702
Chapter 161. Roles of pore size and Al content on the catalytic performance of Al-MCM-41 during hydrocracking reaction 706
Chapter 162. HDS of FCC gasoline: Mesoporous modified support catalyst and its effects on the hydrogenolysis reaction selectivity 710
Chapter 163. Synthesis of mesoporous carbon nanotubes and their application in gas phase benzene hydrogenation 714
Chapter 164. Characteristics and reactivities of cobalt based mesoporous silica catalysts for Fischer-Tropsch synthesis 718
Chapter 165. Physicochemical characteristics of Ti-PILC as a catalyst support for the reduction of NO by NH3 722
Chapter 166. Performance of double wash-coated monolith catalyst in selective catalytic reduction of NOx with propene 726
Chapter 167. Copper loaded MCM-41. An alternative catalyst for NO reduction in exhaust gases ? - Study of its acidic and redox properties 730
Chapter 168. Studies on synthesis and activity for selective catalytic reduction of NO over Pt supported MCM-48 734
Chapter 169. Synthesis of titania-pillared clays and their application as catalyst supports for selective catalytic reduction of NO with ammonia 738
Chapter 170. Hydrogenation of aromatics on Pt/Pd bimetallic catalyst supported by Al-containing mesoporous silica 742
Chapter 171. High loading of short W(Mo)S2 slabs inside the nanotubes of SBA-15. Promotion with Ni(Co) and performance in hydrodesulfurization and hydrogenation 746
Chapter 172. Cr-MCM-41 for selective dehydrogenation of lower alkanes with carbon dioxide 750
Chapter 173. Methane reforming on molybdenum carbide on Al-FSM-16 754
Chapter 174. Preparation of carbided WO3/FSM-16 and Al-FSM-16 and its catalytic activity 758
Chapter 175. AMI study on the catalytical isomerization of 1-hexene to 2-hexene on the surface of aluminosilicate molecular sieves 762
Chapter 176. Isomerization and hydrocracking of n-decane over Pt/MCM-41//MgAPO-n composite catalysts 766
Chapter 177. Catalytic properties of mesoporous aluminosilicates and lanthanum containing mesoporous aluminosilicates studied by m-xylene isomerisation 770
Chapter 178. Diels-Alder reaction catalyzed by ordered micro- and mesoporous silicates 774
Chapter 179. Isospecific polymerization of propylene with metal-MCM-41 778
Chapter 180. A possibility of block-copolymer templated mesoporous silica films applied to surface photo voltage (SPV) type NOx gas sensor 808
Chapter 181. Proton conducting silica mesoporous/heteropolyacid-PVA/SSA nano-composite membrance for polymer electrolyte membrane fuel cell 812
Chapter 182. Hydrothermal synthesis of titania nanotube and its application for dye- sensitized solar cell 816
Chapter 183. Preparation of hydrophobic Ti-containing mesoporous silica by the F-modification and their photocatalytic degradation of organic pollutant diluted in water 820
Chapter 184. Synthesis of functionalised silicas for immobilisation of homogeneous catalysts 824
Author index 828
Subject index 836
Other volumes in the series 840