Chemistry of Microporous Crystals (eBook)

Front Cover 1
Chemistry of Microporous Crystals 4
Copyright Page 5
Contents 16
List of Contributors 8
Preface 20
Part I: Synthesis 22
Chapter 1. Clay–like and Zeolite–like Structures Built of Polymeric Cyanocadmate 24
Chapter 2. 129Xe–NMR Study of the Crystallization of SAPO–37 32
Chapter 3. Application of RDF to Synthesis of Zeolite 42
Chapter 4. Synthesis of Zeolite ZSM–48 with Different Organic and Inorganic Cations 50
Chapter 5. Synthesis and Characterization of Zeolites 58
Chapter 6. Synthesis and Characterisation of Ferrisilicate Zeolites 64
Chapter 7. Further Studies on the Synthesis of VPI–5 74
Chapter 8. New Families of M(III)X(V)O4–Type Microporous Crystals and Inclusion Compounds 84
Chapter 9. Molecular Design of Two-Dimensional Zirconium Phosphonate Catalysts 94
Chapter 10. Mesoporous Materials Produced from Hydrothermally Synthesized Hectorites 102
Chapter 11. Clays Pillared with Ceramic Oxides 110
Chapter 12. Zirconium Pillared Montmorillonite: Influence of Reduced Charge of the Clay 118
Part II: Structure 126
Chapter 13. Crystal Chemistry of Si-A1 Distribution in Natural Zeolites 128
Chapter 14. NMR Studies of Cation Location in Zeolites 144
Chapter 15. Developments in X-ray and Neutron Diffraction Methods for Zeolites 154
Chapter 16. Effects of Structural Disorder on the Generation of Acidic Sites in Zeolite L 162
Part III: Modification 170
Chapter 17. Growth of Silica and its Controlling of Pore-opening Size on CVD Zeolites 172
Chapter 18. New Method of Modifying Y–type Zeolite—Fe Supported Zeolite 180
Chapter 19. Modification of HZSM-5 by Diazomethane 186
Chapter 20. Preparation of Metallosilicates with MFI Structure by Atom- Planting Method 192
Chapter 21. Chemical Interactions of Aluminophosphate Molecular Sieve with Vanadium Oxide 200
Chapter 22. Optical Properties of Dyes Incorporated into Clay 210
Part IV: Diffusion 218
Chapter 23. Molecular Mobility of Single Components and Mixtures on Zeolites 220
Chapter 24. Investigation of Diffusion and Counter-diffusion of Benzene and Ethylbenzene in ZSM-5-type Zeolites by a Novel IR Technique 234
Part V: Catalysis 244
Chapter 25. Zeolites as Partial Oxygenation Catalysts 246
Chapter 26. Kinetics and Mechanism of Paraffin Cracking with Zeolite Catalysts 276
Chapter 27. Dual Function Mechanism of Alkane Aromatization over H- ZSM-5 Supported Ga, Zn, Pt Catalysts: Respective Role of Acidity and Additive 288
Chapter 28. Autocatalysis, Retardation, Reanimation and Deactivation during Methanol Conversion on Zeolite HZSM5 302
Chapter 29. Shape Selective Reactions of Alkylnaphthalenes in Zeolite Catalysts 312
Chapter 30. Alkylation of Biphenyl Catalyzed by Zeolites 324
Chapter 31. Correlation between Energy Characteristics of Aprotic Acid Sites in ZSM-5 Zeolites and Selectivity of Conversion of Alkylbenzenes 332
Chapter 32. N– and C–Methylanilines Formation on Zeolites with Different Structural and Acidic Properties 340
Chapter 33. Copper Ion- exchanged Zeolites as Active Catalysts for Direct Decomposition of Nitrogen Monoxide 348
Chapter 34. Ship-in-Bottle Synthesis of Sterically Crowded Fe–Phthalocyanines in NaY Zeolite Hosts and Their Catalytic Behavior in Regioselective Oxidation of Alkanes 356
Chapter 35. Titanium Silicalite: A New Selective Oxidation Catalyst 364
Chapter 36. The Effects of Iron Impurities on the Cracking Properties of Pillared Clays 374
Chapter 37. Catalysis by Hydrotalcite in Liquid-phase Organic Reactions 384
Chapter 38. Iron-exchanged Montmorillonite as an Efficient Acid Catalyst in Liquid-Phase Organic Synthesis 392
Chapter 39. Influence of Pore Structure on the Catalytic Behavior of Clay Compounds 398
Studies in Surface Science and Catalysis 406