Annual Reports on NMR Spectroscopy (eBook)

Front Cover 1
Annual Reports on NMR Spectroscopy, Volume 37 4
Copyright Page 5
Contents 10
List of Contributors 6
Preface 8
Chapter 1. Dynamic NMR Spectroscopy in Inorganic and Organometallic Chemistry 12
1. Introduction 12
2. One-dimensional methods 13
3. Two-dimensional methods 50
Acknowledgements 78
References 78
Chapter 2. Solid-state NMR Studies of Wood and Other Lignocellulosic Materials 86
1. Introduction 86
2. Solid-state NMR of the components of wood 88
3. Solid-state NMR of natural wood 99
4. Solid-state NMR of wood pulping and pulp bleaching 113
5. Solid-state NMR of non-woody lignocellulosic materials 120
6. Solid-state NMR of wood composites 123
References 124
Chapter 3. NMR Structural Studies of Iron–Sulfur Proteins 130
1. Introduction 130
2. Iron–sulfur proteins 131
3. Paramagnetism and NMR 133
4. NMR experiments for spin assignment 139
5. Structure calculation from NMR data 141
6. NMR structural studies of iron–sulfur proteins 145
7. Conclusions 179
Acknowledgements 183
Note added in proof 183
References 183
Chapter 4. NMR Studies of Wine Chemistry and Wine Bacteria 190
1. Introduction 190
2. NMR studies of wine chemistry 192
3. NMR studies of wine bacteria 200
4. Concluding remarks 210
Acknowledgements 210
References 210
Chapter 5. Proton Phase-sensitive Pulsed Field Gradient Double-quantum Spectroscopy 214
1. Introduction 215
2. Creation of DQ coherence 216
3. Selection of DQC with gradients 221
4. Flip angle dependence 224
5. Solvent suppression 229
6. Sensitivity considerations 241
7. Refocused 1H PFG DQ 247
8. Integrated strategy for analysis of samples in LC-NMR 250
9. Diffusion weighted DQ 258
10. X-filter DQ 264
11. Extension of the 1H PFG 2D DQ to three dimensions 269
12. e-PHOGSY-DQ 274
13. Concluding remarks 276
Acknowledgements 276
References 276
Index 284