Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 19 4
Copyright Page 5
Contents 6
List of Contributors 8
Chapter 1. Recent Chemistry and Structure Investigation of Nitrogen Triiodide, Tribromide, Trichloride, and Related Compounds 10
I. Introduction 11
II. Nitrogen Triiodide 11
III. Nitrogen Trichloride 50
IV. Nitrogen Tribromide 63
References 68
Chapter 2. Aspects of Organo-Transition-Metal Photochemistry and Their Biological Implications 74
I. Introduction 74
II. Principles of Photochemistry 76
III. Primary Processes in Orgenometallic Photochemistry 78
IV. Main Reaction Pathways in the Photochemistry of Organo-Transition- Metal Complexes 107
V. Biological Applications of Organometallic Photochemistry 153
VI. Conclusions 171
References 173
Chapter 3. Nitrogen-Sulfur-Fluorine Ions 194
I. Introduction 194
II. Classification of Sulfur Compounds According to Their Coordination Numbers 195
III. Acyclic Nitrogen-Sulfur-Fluorine Anions. 196
IV. Acyclic Nitrogen-Sulfur-Fluorine Cations 219
V. Cyclic Nitrogen-Sulfur-Fluorine Ions 233
VI. Relationship between Isoelectronie Sulfur and Phosphorus Compounds 240
References 242
Chapter 4. lsopolymolybdates and lsopolytungstates 248
I. Introduction 248
II. Characterization of the Species 249
III. Experimental Methods for Characterizing Species 254
IV. Isopolymolybdates 274
V. Isopolytungstates 289
VI. Formation Mechanisms of Polymetalates 303
References 318
Subject Index 326
Contents of Previous Volumes 332