Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 11 4
Copyright Page 5
Contents 8
List of Contributors 6
Contents of Previous Volumes 10
Chapter 1. Technetium 16
Introduction 17
I. Nuclear Properties of Technetium 22
II. Physical Properties of Technetium 31
III. Chemical Properties of Technetium 34
IV. Methods of Isolating Technetium 60
V. Analytical Chemistry of Technetium 86
VI. Uses of Technetium 93
References 99
Chapter 2. Transition Metal Complexes with Group IVB Elements 106
I. Introduction 107
II. The General Chemistry of Group IVB 107
III. Tetravalent Compounds 115
IV. Complexes of Divalent Tin 132
V. Catalytic Behavior of Group IVB Complexes 141
VI. Bonding in Group IVB Complexes 144
VII. Conclusions 156
References 160
Chapter 3. Metal Carbides 168
I. Introduction 168
II. General Methods of Carbide Preparation 173
III. Simple Carbides with Important Applications 178
IV. Binary Carbides of the Other Metals 209
V. Carbides Containing Three or More Elements 228
VI. Properties of Carbides 235
VII. Available Phase Diagrams 237
VIII. Property Correlations 242
IX. Summary 251
References 252
Chapter 4. Silicon Hydrides and Their Derivatives 264
I. Introduction 264
II. General Aspects of the Behavior of Silane Derivatives 265
III. The Silanes, SinH2n+2 286
IV. Halogen and Pseudohalogen Derivatives of Silanes 290
V. Silane Derivatives with Group V Elements 296
VI. Silane Derivatives with Group VI Elements 305
VII. Silicon-Metal Derivatives 309
VIII. Other Miscellaneous Derivatives 313
IX. Conclusion 314
References 314
Chapter 5. Some General Aspects of Mercury Chemistry 324
I. The Mercury Atom 324
II. Mercury Metal and Its Interaction with Other Metals 327
III. Bond Energies of Mercury Hydrides, Halides, and Alkyls 330
IV. Redistribution Equilibria of Mercury(II) Compounds 334
V. Compounds in Which Mercury Is Bonded to Nonmetallic Elements 336
VI. Bond Energies and Equilibria in Aqueous Media 346
References 353
Chapter 6. Alkyl Derivatives of the Group II Metals 356
I. Introduction 357
II. Compounds Containing the System C—M—C the Dialkyl Derivatives of the Metals
III. Compounds Containing the System C—M—U the Alkylmetallic Hydrides
IV. Compounds Containing the System C—M—Halogen the Alkylmetallic Halides
V. Compounds Containing the System C—M—O the Alkylmetallic Alkoxides and Alkylperoxides
VI. Compounds Containing the System C—M—N the Alkylmetallic Amides
VII. Compounds Containing Other C—M—X Groupings 421
VIII. Salts of Aromatic Radical Anions 425
References 426
Author Index 442
Subject Index 472