Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 7 4
Copyright Page 5
Contents 8
List of Contributors 6
Chapter 1. Halides of Phosphorus, Arsenic, Antimony, and Bismuth 10
I. Introduction 10
II. Halides with Oxidation State +5 11
III. Halides with Oxidation State +3 23
IV. Halides with Oxidation States < +3
V. Isomerism and Bonding 28
References 31
Chapter 2. The Phthalocyanines 36
I. Introduction 37
II. Methods of Preparation and Molecular Structure 37
III. Phthalocyanine Complexes of the Non-Transition Elements 46
IV. Phthalocyanine Complexes of the Transition Elementas 59
V. Electronic Structure and Spectra 74
VI. Physical Studies 95
VII. The Metal-Ligand Bond 112
References 114
Chapter 3. Hydride Complexes of the Transition Metals 124
I. The General Chemistry of Transition Metal Hydride Complexes 124
II. Physical Properties of the Metal-Hydrogen Bond 131
III. The Chemistry of Particular Hydride Complexes 144
IV. The Role of Transition Metal Hydrides in Homogeneous Catalysis 181
References 184
Chapter 4. Reactions of Chelated Organic Ligands 194
I. Introduction 194
II. Electrophilic Substitution Reactions 196
III. Electrophilic Displacement Reactions 221
IV. Nucleophilic Reactions 222
V. Rearrangement Reactions 242
VI. Decarboxylation and Carboxylation 243
VII. Free Radical Reactions 247
VIII. Oxidation-Reduction Reactions 248
IX. Deprotonation Reactions 254
X. Synthetic Applications of Chelated Ligand Reactions 261
References 265
Chapter 5. Organoaluminum Compounds 272
I. Introduction 272
II. Preparation of Organoaluminum Compounds 273
III. Properties of Organoaluminum Compounds 278
IV. Complex Compounds of Alkyl and Aryl Alanes 292
V. Reactions of Organoaluminum Compounds 308
References 348
Chapter 6. Carbosilanes 358
I. Introduction 358
II. Formation of Carbosilanes 359
III. Spectroscopic Investigation of Carbosilanes 400
IV. Conclusion 424
References 424
Author Index 428
Subject Index 453