Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 23 4
Copyright Page 5
Contents 6
List of Contributors 10
Chapter 1. Recent Advances in Organotin Chemistry 14
I. Introduction 14
II. Preparation and Reactions of Organotin Compounds 15
III. Structural Organotin Chemistry 41
IV. Biological and Environmental Aspects 54
V. Industrial Applications 64
References 75
Chapter 2. Transition Metal Vapor Cryochemistry 92
I. Introduction 93
II. Atomic, Diatomic, and Cluster Species 94
III. New Cluster Techniques 114
IV. Cluster Complexes 127
V. Classical Inorganic Ligands 143
VI. Organometallic Complexes 158
VII. Conclusion 179
Addendum 179
Addendum References 181
References 182
Chapter 3. New Methods for the Synthesis of Trifluoromethyl Organometallic Compounds 190
I. Introduction 191
II. Plasma-Generated Trifluoromethyl Radicals as a Synthetic Reagent 194
III. Bis(trifluoromethyl)mercury as a Synthetic Reagent 205
IV. Synthesis of Trifluoromethyl Organometallic Compounds by Direct Fluorination 210
V. A New General Synthesis for Trifluoromethyl Organometallic Compounds and Other Sigma-Bonded Metal Compounds Based on Metal Vapor as a Reagent 216
References 221
Chapter 4. 1.1–Dithiolato Complexes of the Transition Elements 224
I. Introduction 224
II. The Ligands 225
III. Transition-Metal Complexes 228
References 282
Chapter 5. Graphite Intercalation Compounds 294
I. Introduction 294
II. Covalent Compounds of Graphite 296
III. Lamellar Compounds 298
IV. Residue Compounds 327
V. Applications of Intercalation Compounds 328
References 332
Chapter 6. Solid-state Chemistry of Thio-, Seleno-, and Tellurohalides of Representative and Transition Elements 342
I. Introduction 343
II. Group IB 345
III. Group IIB 364
IV. Group IIIB and Lanthanides 370
V. Group IVB 377
VI. Group VB 377
VII. Group VIB 383
VIII. Group VIIB 392
IX. Group VIIIB 394
X. Group IIIA 395
XI. Group IVA 402
XII. Group VA 413
Appendix 425
References 426
Appendix References 438
Subject Index 440
Contents of Prevous Volumes 449