Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 22 4
Copyright Page 5
Contents 6
List of Contributors 10
Chapter 1. Lattice Energies and Thermochemistry of Hexahalometallate (IV) Complexes, A2MX6, which Possess the Antifluorite Structure 14
I. Introduction 15
II. Rigorous Lattice-Energy Calculation for A2MX6 Salts 23
III. Estimated Lattice Energies 30
IV. Thermochemical Data 35
V. Computations of Lattice Energies and Associated Data 37
VI. Summary Tabulation of Rigorous Calculations 106
VII. Summary Tabulation of Derived Estimates 106
VIII. Discussion 106
IX. Concluding Remarks 117
References 118
X. Appendix 120
Appendix References 124
Chapter 2. Reaction Mechanisms of Inorganic Nitrogen Compounds 126
I. Introduction 127
II. Sulfamic Acid 128
III. Nitrogen Trihalides 129
IV. Hydrazine 131
V. Diimide and Tetrazene 134
VI. Hydroxylamine 135
VII. The Sulfonic Acids of Hydroxylamine and Derived Species 141
VIII. Hydrazoic Acid 144
IX. Hyponitrous Acid and Nitroxyl 148
X. Nitramide 151
XI. Nitric Oxide 152
XII. Trioxodinitrate (II) 154
XIII. Nitrous Acid 156
XIV. Dinitrogen Tetroxide and Nitrogen Dioxide 169
XV. Nitric Acid 173
References 178
Chapter 3. Thio–, Seleno–, and Tellurohalides of the Transition Metals 184
I. Introduction 184
II. Group IIIA 187
III. Group IVA 189
IV. Group VA 190
V. Group VIA 193
VI. Group VIIA 205
VII. Group VIII 206
VIII. Group IB 206
References 208
Note Added in Proof 211
Chapter 4. Correlations in Nuclear Magnetic Shielding, Part II 212
I. Introduction 212
II. Diamagnetic and Paramagnetic Currents 212
III. Shielding Terms 214
IV. Patterns of Shielding in Inorganic Molecules 225
V. Main Group Elements 234
VI. Transition Metals 238
VII. Correlations with Spectroscopic and Other Properties 243
References 244
Note Added in Proof 249
Chapter 5. Cyclic Sulfur-Nitrogen Compounds 252
I. Introduction 253
II. Three-Membered Rings 253
III. Description of Sulfur-Nitrogen Compounds with Coordination Number Two at the Sulfur and Nitrogen Atom 255
IV. Four-Membered Rings 256
V. Five-Membered Rings 261
VI. Six-Membered Rings 277
VII. Seven-Membered Rings 293
VIII. Eight-Membered Rings 294
IX. Ten-Membered Rings 305
X. Twelve-Membered Rings 306
References 307
Chapter 6. 1,2-Dithiolene Complexes of Transition Metals 316
I. Introduction 316
II. 1, 2.Dithiolate Ligands and Synthetic Routes 317
III. Transition-Metal Complexes 323
IV. Physical Studies 348
References 356
Chapter 7. Some Aspects of the Bioinorganic Chemistry of Zinc 362
I. Introduction 362
II. Carbonic Anhydrase 369
III. Zinc-Based Alcohol Dehydrogenases 403
IV. Carboxypeptidase A 422
V. Conclusions 434
VI. Glossary 436
References 444
Subject Index 454
Contents of Previous Volumes 466