Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 9 4
Copyright Page 5
Contents 8
List of Contributors 6
Contents of Previous Volumes 10
Chapter 1. Liquid-Liquid Extraction of Metal Ions 16
I. Introduction 16
II. Single-Stage Extraction 19
III. Multiple Extraction and Multiple Scrubbing 22
IV. System Involving Neutral Phosphorus-Based Extractants 40
V. Systems Involving Acidic Phosphorus-Based Extractants 49
VI. Systems Involving Sulfonic Acids, (G)SO2(OH), as Extractants 63
VII. Systems Involving Amines and Amine Oxides as Extractants 64
VIII. Miscellaneous System 71
IX. Synergism and Antisynergism 79
X. Investigation of Complexes 83
XI. Concluding Comments 86
References 87
Chapter 2. Nitrides of Metals of the First Transition Theory 96
I. Introduction 96
II. Binary Compounds 97
III. Ternary Compounds 131
References 142
Chapter 3. Pseudohalides of Group IIIB and IVB Elements 148
I. Introduction 148
II. Azides 149
III. Cyanides and Isocyanides 157
IV. Isocyanates 167
V. Isothiocyanates 180
References 193
Chapter 4. Stereoselectivity in Coordination Compounds 200
I. Introduction 200
II. Complexes of Diamines 203
III. Complexes of Amino Acids 219
IV. Other Ligands 226
V. Conclusion 227
References 228
Chapter 5. Heterocations 232
I. Introduction 232
II. Cations of Nontransition Elements 248
III. The Proton in Heterocations 294
IV. Cations with Metal-Carbon and Metal-Metal Bonding 302
V. Ions in the Gas Phase 307
VI. Heterocations in Aqueous Solution 313
VII. Concluding Remarks 320
References 321
Chapter 6. The Inorganic Chemistry of Tungsten 330
I. Introduction 330
II. Halides, Oxyhalides, and Their Derivatives 331
III. Cyano Complexes 347
IV. Thiocyanato Complexes 351
V. Oxides and Tungstates 352
VI. Aromatic and Carbonyl Complexes 353
VII. Other Compounds 359
VIII. Metal-Metal Bonds 360
References 362
Author Index 370
Subject Index 396