Advances in Inorganic Chemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 28 4
Copyright Page 5
Contents 6
Contributors 10
Chapter 1. Fast-Atom Bombardment Mass Spectrometry and Related Techniques 12
I. Introduction 12
II. The Fast-Atom Bombardment Method 13
III. Applications to Organometallic Compounds 18
IV. Applications to Coordination Compounds 24
V. Applications to Other Inorganic Systems 28
VI. Applications of Secondary Ion Mass Spectrometry 30
VII. Applications of Other Related Techniques 32
VIII. Summary 33
IX. Addendum 33
References 33
Chapter 2. The Chemistry of Berkelium 40
I. Introduction 40
II. Nuclear Properties, Availability, and Applications 41
III. Separation and Purification 43
IV. Atomic Properties 45
V. Metallic State 52
VI. Compounds 58
VII. Solution Chemistry 66
VIII. Concluding Remarks 74
References 75
Chapter 3. Preparations and Reactions of Oxide Fluorides of the Transition Metals, the Lanthanides, and the Actinides 84
I. Introduction 84
II. The Oxide Fluorides of the Transition Metals 85
III. The Oxide Fluorides of the Lanthanide Elements 96
IV. The Oxide Fluorides of the Actinide Elements 97
References 102
Chapter 4. Chemical Effects of Nuclear Transformations 112
I. Introduction 112
II. Reactions of Thermalized Recoil Atoms 113
III. Stereochemistry in Substitution Reactions 123
IV. Muonium Chemistry 130
References 141
Chapter 5. Homocyclic Selenium Molecules and Related Cations 146
I. General 146
II. Neutral Selenium Ring Molecules 147
III. Homocyclic Selenium Cations 163
IV. Selenium Iodide Cations, SenI+ 172
V. Conclusions and Outlook 173
References 174
Chapter 6. The Element Displacement Principle: A New Guide in p-Block Element Chemistry 178
I. Introduction 179
II. The Element Displacement Principle 180
III. Application of the Element Displacement Principle to Recent Chemical Problems 183
IV. Halogen-Like Properties of Parahalogens of Different Derivation 187
V. Interchangeability of Elements and Paraelements in Known Structures 205
VI. Electronegativities 208
References 210
Chapter 7. Compounds of Pentacoordinated Arsenic(V) 214
I. Introduction 214
II. As—C-Containing Compounds 215
III. As—N-Containing Compounds 227
IV. As—O- and As—S-Containing Compounds 234
V. As—Halogen-Containing Compounds 249
VI. Conclusion 259
References 260
Chapter 8. Perchlorate Ion Complexes 266
I. Introduction 266
II. Perchlorate Ion Coordination and Methods of Identification 267
III. Complexes of Early Transition Metals 271
IV. Complexes of Iron Group Metals 274
V. Complexes of Cobalt Group Metals 276
VI. Complexes of Nickel Group Metals 279
VII. Complexes of Copper Group Metals 284
VIII. Complexes of Zinc Group Metals 294
IX. Complexes of Lanthanides 298
X. Complexes of Other Metals 299
XI. Conclusion 301
XII. Abbreviations 302
References 305
Index 312
Contents of Previous Volumes 316