Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 14 4
Copyright Page 5
Contents 6
List of Contributors 8
Chapter 1. The Phosphazotrihalides 10
I. Introduction 10
II. Nomenclature 11
III. General Remarks Concerning the Synthesis of Phosphonitrile Chlorides 14
IV. Ionic P—N Compounds Containing -N=PX3 Groups in the Cation 15
V. N-Phosphorylated Phosphazotrihalides 33
VI. Sulfonylphosphazotrihalides 42
VII. Carbonylphosphazotrichlorides 53
VIII. Aryl- and Alkylphosphazotrihalides 64
IX. Miscellaneous Compounds 90
X. Applications 99
References 101
Chapter 2. Low Temperature Condensation of High Temperature Species as a Synthetic Method 130
I. Introduction 130
II. Species and Reaction Conditions 132
III. Experimental Methods 139
IV. Reactions of High Temperature Species of Main Group Elements 151
V. Reactions of High Temperature Species of Transition Elements 167
VI. The Method in Perspective 173
References 176
Chapter 3. Transition Metal Complexes Containing Bidentate Phosphine Ligands 182
I. Introduction 182
II. Bonding in Metal–Phosphine Complexes 183
III. Techniqucs Used to Study Metal–Phosphine Complexes 185
IV. X-Ray Crystallographic Studies 192
V. Syntheses of Diphosphines 194
VI. Diphosphine Complexes 194
VII. Appendix : Ligand Abbreviations 249
References 253
References Added in Proof 260
Chapter 4. Beryllium Halides and Pseudohalides 264
I. Introduction 264
II. Beryllium Fluorides 266
III. Beryllium, Chlorides, Bromides, and Iodides 287
IV. Beryllium Pseudohalides 318
V. Spectroscopic Studies 319
VI. Thermodynamic Properties 325
References 326
Chapter 5. SuIfur–Nitrogen–Fluorine Compounds 342
I. Introduction 342
II. Acyclic Compounds 342
III. Cyclic Compounds 381
IV. Bonding Relationships of the S-N Group 390
References 392
Author Index 400
Subject Index 433
Contents of Previous Volumes 438