Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 20 4
Copyright Page 5
Contents 6
List of Contributors 8
Chapter 1. Recent Advances in the Chemistry of the Less-Common Oxidation States of the Lanthanide Elements 10
I. Scope of the Atticle 10
II. Introduction 12
III. Compounds in Lower Oxidation States 13
IV. Tetrapositive Oxidation States 72
V. Interpretation of Redox Stability 88
VI. Extension to Other Systems 118
VII. Conclusion 125
References 125
Appendix 140
Chapter 2. Ferrimagnetic Fluorides 142
I. Introduction 142
II. Magnetic Interactions in Insulators 143
III. Ferrimagnetic Fluorides 152
References 191
Note Added in Proof 197
Chapter 3. Hydride Complexes of Ruthenium, Rhodium, and Iridium 198
I. Introduction 199
II. Synthesis of Transition Metal–Hydride Complexes 200
III. Chemical Properties and Chemical Reactions of Transition Metal–Hydride Complexes 203
IV. Physical Properties and Methods of Characterization 206
V. Hydride Complexes of Ruthenium 211
VI. Hydride Complexes of Rhodium 239
VII. Hydride Complexes of Iridium 244
References 291
Chapter 4. Structures and Physical Properties of Polynuclear Carboxylates 300
I. Introduction 300
II. Structures 301
III. Magnetic Susceptibility Measurements 316
IV. Electron Paramagnetic Resonance Spectroscopy 333
V. Electronic Spectroscopy 339
VI. Vibrational Spectra 346
VII. Nuclear Magnetic Resonance Spectroscopy 354
VIII. Mass Spectrometry 356
IX. Mössbauer Spectroscopy 359
X. Heatcapacity Measurements 360
XI. Molecular Weight Determinations 361
XII. Conclusions 361
XIII. Appendix 362
References 363
Subject Index 372
Contents of Previous Volumes 379