Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 6 4
Copyright Page 5
List of Contributors 6
Preface 8
Contents 10
Contents of Previous Volumes 12
Chapter 1. A Forty Years' Stroll through the Realms of Organometallic Chemistry 18
Text 18
References 33
Chapter 2. Aliphatic Organopolysilanes 36
I Introduction 36
II Silicon-Functional Organopolysilanes 37
III Peralkylated Polysilanes 62
IV Carbon-Functional Organopolysilanes 82
V Ultraviolet and NMR Spectra 97
VI List of Aliphatic Organopolysilanes 105
References 128
Chapter 3. Catalysis by Cobalt Carbonyls 136
I Introduction 136
II Hydroformylation 139
III Hydrogenation and Hydrogenolysis 164
IV Hydrosilation 168
V Isomerization 170
VI Carboxylation 174
VII Carbonylation 175
VIII Polymerization 180
References 182
Chapter 4. Redistribution Equilibria of Organometallic Compounds 188
I Introduction 188
II Theory of Redistribution Equilibria 190
III Experimental Methods 202
IV Rates and Mechanisms of Redistribution Reactions 210
V Redistributions in Compounds of Main Group Elements 218
VI Redistributions in Compounds of Transition Metals 273
References 279
Chapter 5. Mass Spectra of Organometallic Compounds 290
I Introduction 290
II Metal Carbonyls and Nitrosyls 292
III Metal Carbonyl Halides 300
IV Complexes Containing p-Bonded Ligands 301
V Fluorocarbon Complexes 309
VI Sulfur, Nitrogen, and Phosphorus Complexes 311
VII Organic Derivatives of Metallocenes and Related Compounds 321
VIII Main Group Organometallic Compounds 329
IX Appearance Potentials 332
References 341
Errata for Previous Volumes 352
Author Index 356
Subject Index 377