Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 8 4
Copyright Page 5
Contents 8
List of Contributors 6
Chapter 1. Metal Carbonyls, Forty Years of Research 10
I. Introduction 10
II. Substitution And Disproportionation Reactions of the Metal Carbonyls 13
III. Metal Carbonyl Hydrides 15
IV. Organometal Carbonyls 18
V. Metal Derivatives of Carbonyl Hydrides 19
VI. Halogenometal Carbonyls 22
VII. Synthesis of Metal Carbonyls 24
VIII. Other Developments Originating from the Study of Metal Carbonyls 27
IX. Metal Carbonyl Nitrosyls 30
X. Physicochemical Studies 31
XI. Conclusion 32
References 33
Chapter 2. p-Allylnickel Intermediates in Organic Synthesis 38
I. Introduction 38
II. Coupling Reactions 39
III. Insertion Reactions 49
IV. Nickel-Catalyzed Synthesis of Cyclic Compounds 57
References 92
Chapter 3. Transition Metal– Carborane Complexes 96
I. Introduction 96
II. Complexes With Eleven-Atom Ligands 98
III. Physical Properties of Eleven-Atom Ligand Complexes 113
IV. Complexes of The B7C2H92-Ligand 118
V. Complex of The B6C2H82=Ligand 120
VI. Multifunctional Transition Metal Ligands 121
References 122
Chapter 4. ChapterMetal Carbonyl Cations 126
I. Introduction 126
II. Syntheses of The Cationic Metal Carbonyls 128
III. Survey of The Cationic Metal Carbonyls And Their Properties By Groups 140
References 168
Chapter 5. Fast Exchange Reactions of Group I, II, and III Organometallic Compounds 176
I. Introduction 176
II. Organolithium Compounds,(Lir)n 177
III. Group II Organometallic Derivatives 179
IV. Group III Organometallic Derivatives 188
V. Reactions of MRnX3-n Derivatives 202
VI. Reactions of The MR4- Group 205
VII. Addition Compounds 208
VIII. Summary And Conclusions 213
References 214
Chapter 6. Muss Spectra of Metullocenes and Related Compounds 220
I. Introduction 220
II. Titanium, Zirconium, And Hafnium 222
III. Vanadium and Niobium 225
IV. Chromium , Molybdenum, And Tungsten 227
V. Group VIIB Metals 243
VI. Group VIII Metals 250
VII. Apperance Potentials, Bond Dissociation Energies, and Heats of Formation 292
VIII. Tabular Summary of Mass Spectral Data For Transition-Metal Organometallic Compounds Since 1967 296
References 336
Author lndex 344
Subject Index 362
Cumulative List of Contributors 368
Cumulative List of Titles 369