Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 28 2
Copyright Page 5
Contents 6
Chapter 1. Interaction of Ketenes with Organometallic Compounds: Ketene, Ketenyl, and Ketenylidene Complexes 8
I. Introduction 8
II. Reactions of Ketenes with Organometallic Complexes 10
III. Complexes Possessing Ketene Ligands 23
IV. Ketenyl Complexes 62
V. Ketenylidene Complexes 73
VI. Summary 83
References 83
Chapter 2. Graphite–Metal Compounds 92
I. Introduction 92
II. Structure of Graphite and Its Lamellar Compounds 93
III. Synthetic Applications 106
References 137
Chapter 3. Nucleophilic Activation of Carbon Monoxide: Applications to Homogeneous Catalysis by Metal Carbonyls of the Water Gas Shift and Related Reactions 146
I. Introduction 146
II. Preparation and Properties of Nucleophile–Carbonyl Adducts 147
III. Equilibria and Kinetics of Adduct Formation 167
IV. Reactivities of Adducts 178
V. Homogeneous Catalysis of the Water Gas Shift and Related Reactions 194
VI. Concluding Remarks 212
References 213
Chapter 4. Organopalladium and Platinum Compounds with PenfahalophenyI Ligands 226
I. Introduction 226
II. Complexes of Palladium(II) or Platinum(II) 227
III. Platinum(III) Complexes 284
IV. Complexes of Pd(IV) and Pt(IV) 285
V. Palladium(I) and Platinum(I) Compounds 287
VI. Appendix. Infrared Spectra of the Pentahalophenyl Metal Compounds 295
References 300
Chapter 5. H–H, C–H, and Sigma-Bonded Related Groups as Ligands 306
I. Introduction 306
II. Dihydrogen Complexes 308
III. C–H Bonds as Ligands 324
IV. Addendum 339
References 340
Chapter 6. Organometallic Compounds Containing Oxygen Atoms 346
I. Introduction 346
II. Preparation of Organometallic Oxo Compounds 349
III. Metal Oxoalkyl and-Aryl Compounds 354
IV. Oxo Alkylidene, Alkylidyne, Olefin, Acetylene, And Carbonyl Compounds 358
V. Metal Cyclopentadienyl Complexes Containing Oxygen Atoms 363
VI. Organometallic Clusters Containing Oxygen Atoms 376
VII. Organometallic Polyoxometallates 389
References 395
Chapter 7. Recent Developments in NMR Spectroscopy of Organometallic Compounds 404
I. Introduction 404
II. One-Dimensional NMR Spectroscopy 405
III. Two-Dimensional NMR Spectroscopy 431
IV. Multinuclear NMR Spectroscopy 449
V. Magnetization Transfer Measurements 452
VI. Relaxation Measurements 457
VII. Solid-State NMR Spectroscopy 458
References 462
Index 466
Cumulative List of Contributors 476