Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 23 4
Copyright Page 5
Contents 6
Contributors 8
Chapter 1. The Electron-Transfer Reactions of Mononuclear Organotransition Metal Complexes 10
I. Introduction 11
II. Carbonyl Complexes and Their Derivatives 13
III. Alkyl and Aryl Complexes 43
IV. .2-Alkene Complexes 45
V. .3-Allyl Complexes 46
VI. .4-Bonded Complexes 47
VII. .5-Cyclopentadienyl Complexes 50
VIII. .6-Arene Complexes 72
IX. .7- and .8-Bonded Complexes 74
X. Sandwich Compounds 75
XI. Addendum 86
References 88
Chapter 2. Redistribution Reactions of Transition Metal Organometallic Complexes 104
I. Introduction 104
II. The Thermodynamics of Redistribution Reactions 106
III. Experimental Techniques 108
IV. Transfers by Ligand Type 112
V. Conclusions and Future Directions 135
References 136
Chapter 3. Silyl, Germyl, and Stannyl Derivatives of Azenes, NnHn: Part I. Derivatives of Diazene, N2H2 140
I. Introduction 140
II. Preparation 142
III. Properties 147
IV. Thermolysis 152
V. Hydrolysis 161
VI. Reactivity 165
VII. BSD Complexes 190
References 198
Chapter 4. Polarization Transfer NMR Spectroscopy for Silicon-29: The INEPT and DEPT Techniques 202
I. Introduction 202
II. Polarization Transfer Techniques 204
III. Application of INEPT and DEPT to 29Si NMR 207
IV. Theory of INEPT and DEPT Spectroscopy 218
References 226
Chapter 5. C- and O-Bonded Metal Carbonyls: Formation, Structures, and Reactions 228
I. Introduction 228
II. S—CO— Compounds: Formation, Structures, and Spectra 236
III. .—CO Compounds: Formation, Structures, and Spectra 277
IV. Influence of —CO— Bonding on Reactivity 288
V. Concluding Remarks 306
References 306
Index 316
Cumulative List of Contributors 326
Cumulative List of Titles 330