Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 9 4
Copyright Page 5
Contents 6
List of Contributors 10
Chapter 1. Of Time and Carbon-Metal Bonds 12
I. Salad Days 12
II. Ceramics and Silicones 14
III. Other Metals and Methods of Research 21
IV. And Now? 28
References 29
Chapter 2. Applications of 119mSn Mössbauer Spectroscopy to the Study of Organotin Compounds 32
I. Introduction 33
II. The Mössbauer Effect 34
III. 119mSn Mossbauer Spectroscopy 61
IV. Applications of 119mSn Mössbauer Spectroscopy to Problems in Organotin Chemistry 90
Appendix I: A Bibliography of 119mSn Mössbauer Spectroscopy 99
Appendix II: 119mSn Mössbauer Data for Organotin Compounds 117
Chapter 3. Organic Complexes of Lower-Valent Titanium 146
I. Introduction 147
II. Addition Complexes of Titanium Trihalides 148
III. Complexes of Type TiXn.(3-n)L 159
IV. Organometallic Compounds of Titanium (III) 163
V. Addition Complexes of Titanium Dihalides 183
VI. Complexes of Type TiXn.(2-n)L 184
VII. Organometallic Compounds of Titanium (II) 186
VIII. Complexes of Titanium in Valencies Lower than Two 191
IX. Lower-Valent Titanium Complexes in Catalysis 193
References 199
Chapter 4. Organoberyllium Compounds 206
I. Introduction 206
II. Beryllium Dialkyls 207
III. Beryllium Diaryls 215
IV. Bis(cyclopentadienyl)beryllium and Other Unsaturated Derivatives 216
V. Coordination Complexes of the Dialkyls, Diaryls, and Dialkynyls 218
VI. Haloberyllium Alkyls, RBeX 230
VII. Aminoberyllium Alkyls, R2NBeR' 233
VIII. Oxyberyllium Alkyls, ROBeR' 241
IX. Thioberyllium Alkyls, RSBeR' 247
X. Anionic Organoberyllium Complexes 250
XI. Beryllium Hydride Derivatives 254
References 264
Chapter 5. lsoelectronic Species in the Organophosphorus, Organosilicon, and Organoaluminum Series 270
I. Introduction 271
II. Fluoro, Hydroxy, Amino, and Methyl Silanes 273
III. Organophosphine Oxides, Imines, Methylenes, Boranes, and Related Compounds 289
IV. Organosiloxanes, R3Si—O—SiR3, and Related Compounds 313
V. Silyl Phosphine Imines, R3Si—N-PR3, and Related Compounds 319
VI. Disilazanes and Trisilylamines 327
VII. The Organosilicon Chemistry of Phosphorus Ylids 332
VIII. Bis(phosphoranylidene)methanes, R3P=C=PR3, and Related Compounds 337
IX. Isoelectronic Small Ring Systems 340
X. Six- and Eight-Membered Ring Systems 351
References 359
Chapter 6. OrganoIanthanides and Organoactinides 372
I. Introduction 372
II. The Rare Earths 373
III. Organolanthanides 376
IV. Organic Derivatives of Divalent Lanthanides 389
V. Organoactinides 391
References 402
Chapter 7. a-Heterodiazoalkanes and the Reactions of Diazoalkanes with Derivatives of Metals and Metalloids 408
I. Introduction 408
II. a-Heterosubstituted Diazoalkanes 410
III. Reactions of Diazoalkanes with Derivatives of Metals and Metalloids 426
IV. Tabular Survey 440
References 440
Author Index 448
Subject Index 480
Cumulative List of Contributors 487
Cumulative List of Titles 488