Hydrosilylation (eBook)
XXIV, 408 Seiten
Springer Netherland (Verlag)
978-1-4020-8172-9 (ISBN)
For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century.
The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.
For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century.The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.
Preface 7
Biographical Note 9
Abbreviations 11
Contents 14
Introduction 18
Part I Hydrosilylation of Carbon - CarbonMultiple Bonds in Synthesis of MolecularOrganosilicon Compounds 24
Hydrosilylation of Alkenes and Their Derivatives 25
Hydrosilylation of Alkynes and Their Derivatives 74
Hydrosilylation of Carbon----Carbon Multiple Bonds in Organic Synthesis 108
Asymmetric Hydrosilylation of Prochiral Alkenes and Their Derivatives 145
Part II Hydrosilylation of Carbon - Carbon Multiple Bonds in Polymer Chemistry andMaterials Science 177
Functionalisation and Cross-Linking of Organosilicon Polymers 178
Hydrosilylation Polymerisation 209
Functionalised (Poly)silsesquioxanes and Silicon- Containing Dendrimers 233
Organosilicon – Organic Hybrid Polymers and Materials 259
Part III Chemo- and Enantio-Selective Hydrosilylation of Unsaturated Carbon–Heteroatom Bonds 305
Hydrosilylation of Unsaturated Carbon---- Heteroatom Bonds 306
Asymmetric Hydrosilylation of Unsaturated Carbon– Heteroatom Bonds 357
Index 415
| Erscheint lt. Verlag | 9.11.2008 |
|---|---|
| Reihe/Serie | Advances in Silicon Science | Advances in Silicon Science |
| Zusatzinfo | XXIV, 408 p. |
| Verlagsort | Dordrecht |
| Sprache | englisch |
| Themenwelt | Naturwissenschaften ► Biologie |
| Naturwissenschaften ► Chemie ► Organische Chemie | |
| Naturwissenschaften ► Chemie ► Physikalische Chemie | |
| Technik ► Maschinenbau | |
| Schlagworte | Alkenes • Alkynes • Carbon-Carbon multiple bonds • Chemistry • Cross-linking of polymers • Dendrimers • Hydrosilylation • Organosilicon compounds • Prochiral Alkenes • Silsesquioxanes • synthesis • Unsaturated Carbon-Heteroatom Bonds |
| ISBN-10 | 1-4020-8172-3 / 1402081723 |
| ISBN-13 | 978-1-4020-8172-9 / 9781402081729 |
| Haben Sie eine Frage zum Produkt? |
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