Sonochemistry in Water Organic Solutions
Seiten
2010
Nova Science Publishers Inc (Verlag)
978-1-61761-175-9 (ISBN)
Nova Science Publishers Inc (Verlag)
978-1-61761-175-9 (ISBN)
Exploits the power ultrasound, reaction kinetics and linear free-energy relationships to study ionic reactions in water and aqueous-organic binary solvents, and discusses the importance of hydrophobic ground-state stabilisation of reagents in aqueous solutions.
Sonochemistry and solution chemistry have been explicitly brought together by analysing the effect of ultrasound on kinetics of ester hydrolysis and benzoin condensation, measured by the authors, and similar kinetic data for the solvolysis of tert-butyl chloride, compiled from literature. For the first time the power ultrasound, reaction kinetics and linear free-energy relationships were simultaneously exploited to study ionic reactions in water and aqueous-organic binary solvents and the importance of hydrophobic ground-state stabilisation of reagents in aqueous solutions was discussed. This book presents and discusses this approach, which has opened novel perspectives for wider understanding of the effect of sonication on chemical reactions in solution, as well as on solvation phenomena in general.
Sonochemistry and solution chemistry have been explicitly brought together by analysing the effect of ultrasound on kinetics of ester hydrolysis and benzoin condensation, measured by the authors, and similar kinetic data for the solvolysis of tert-butyl chloride, compiled from literature. For the first time the power ultrasound, reaction kinetics and linear free-energy relationships were simultaneously exploited to study ionic reactions in water and aqueous-organic binary solvents and the importance of hydrophobic ground-state stabilisation of reagents in aqueous solutions was discussed. This book presents and discusses this approach, which has opened novel perspectives for wider understanding of the effect of sonication on chemical reactions in solution, as well as on solvation phenomena in general.
Introduction; Current Views of the Sonochemistry in Solutions; Ionic Reactions Accelerated by Ultrasound; Water & Hydrophobic Interactions; Sonochemical Effects in Reaction Kinetics; Mode of Action of Ultrasound on Reactions in Solutions; Inferences from Sonication Effects; Some Quantitative Considerations; The Solvent Structure & Sonication Effects; The Domino Effect in Understanding of Solvation Phenomena; Conclusion.
Erscheint lt. Verlag | 22.9.2010 |
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Verlagsort | New York |
Sprache | englisch |
Maße | 215 x 140 mm |
Gewicht | 204 g |
Themenwelt | Naturwissenschaften ► Chemie |
ISBN-10 | 1-61761-175-1 / 1617611751 |
ISBN-13 | 978-1-61761-175-9 / 9781617611759 |
Zustand | Neuware |
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