Organosilicon Derivatives of Phosphorus and Sulphur

I. Organosilicon Derivatives of Phosphorus.- 1. Compounds containing the grouping Si-O-P.- 1.1. Preparation methods.- 1.1.1. Reactions of Halosilanes with Oxygen Acids of Phosphorus, and Their Acid and Neutral Esters and Salts.- 1.1.2. Reactions of Alkoxysilanes and Acyloxysilanes with Oxygen Acids of Phosphorus and Their Esters and Anhydrides.- 1.1.3. Reactions of Alkoxysilanes and Acyloxysilanes with Phosphorus Halides and Acid Halides of Phosphorus Acids.- 1.1.4. Reactions of Silanols and Sodium Silanolates with Phosphorus Compounds.- 1.1.5. Cleavage of Siloxanes by Phosphorus Compounds.- 1.1.6. Reactions of Phosphorus Compounds with Aminosilanes and Silazans.- 1.1.7. Reactions of Hydrosilanes with Phosphorus Acids.- 1.1.8. Synthesis of Alumaphosphonasiloxanes.- 1.2. Physical Properties.- 1.3. Chemical Properties.- 1.4. Analysis Methods.- 1.5. Practical Application.- 2. Compounds Containing the Groupings Si-O-S-P and Si-S-P.- 3. Compounds Containing the Grouping Si-N-P.- 3.1. Preparation Methods.- 3.2. Physical Properties.- 3.3. Chemical Properties.- 4. Compounds Containing the Bond Si-P.- 4.1. Preparation Methods.- 4.2. Physical Properties.- 4.3. Chemical Properties.- 5. Compounds Containing the Grouping Si-(C)n -P.- 5.1. Preparation Methods.- 5.1.1. Reactions of Organosilicon Grignard Reagents with Halogen-Containing Phosphorus Compounds.- 5.1.2. Reactions of Haloalkylsilanes with Salts and Esters of Phosphorus Acids.- 5.1.3. Hydrophosphorylation and Hydrosilylation of Unsaturated Organic Compounds of Silicon and Phosphorus.- 5.1.4. Reactions of Tetraorganosilanes, Organochlorosilane s, and (Chloroalkyl)silanes with Phosphorus Halides.- 5.1.5. Synthesis of Organosilicon Ylides of Phosphorus.- 5.1.6. Other Preparation Methods.- 5.2. Physical Properties.- 5.3. Chemical Properties.- 5.4. Practical Application.- 6. Compounds Containing the Groupings Si- (C)n-O-P, Si-(C)n-S-P, Si-(C)n-N-P, and Si-O-(C)n-P.- 6.1. Preparation Methods.- 6.2. Physical and Chemical Properties.- 6.3. Practical Application.- 7. Complex Compounds Containing Si and P Atoms.- Literature Cited in Chapter 1.- 1. Publications of Soviet Authors.- 2. Publications of Foreign Authors.- II. Organosilicon Derivatives of Sulfur.- 1. Compounds Containing the Grouping Si-S-H (Silanethiols).- 1.1. Preparation Methods.- 1.2. Physical Properties.- 1.3. Chemical Properties.- 2. Compounds Containing the Grouping Si-S-C (Organothiosilanes).- 2.1. Preparation Methods.- 2.2. Physical Properties.- 2.3. Chemical Properties.- 3. Compounds Containing the Grouping Si-S-Si (Silthianes).- 3.1. Silicon Disulfide and its Application in the Synthesis of Organosilicon Compounds.- 3.2. Methods of Preparing Organosilicon Compounds containing the Grouping Si-S-Si.- 3.3. Physical Properties.- 3.4. Chemical Properties.- 4. Compounds Containing the Grouping Si-O-S.- 4.1. Preparation Methods.- 4.1.1. Reactions of Organosilicon Compounds with Sulfuric Acid.- 4.1.2. Reactions of Organosilicon Compounds with Sulfur Trioxide.- 4.1.3. Synthesis from Arenesulfonic Acids.- 4.1.4. Synthesis from Halosulfonic Acids.- 4.1.5. Synthesis from Salts of Oxygen Acids of Sulfur.- 4.1.6. Other Synthesis Methods.- 4.2. Physical Properties.- 4.3. Chemical Properties.- 5. Compounds Containing the Grouping Si-N-S.- 6. Compounds Containing the Grouping Si-NCS (Isocyanatosilanes).- 6.1. Preparation Methods.- 6.2. Physical Properties.- 6.3. Chemical Properties.- 6.4. Biological Action.- 7. Compounds with the Grouping Si-(C)n -S.- 7.1. Compounds Containing the Grouping Si- (C)n -SH (Organosilicon Thiols).- 7.1.1. Preparation Methods.- 7.1.2. Physical Properties.- 7.1.3. Chemical Properties.- 7.2. Compounds Containing the Grouping Si- (C)n -S-C (Organosilicon Sulfides and Their Derivatives).- 7.2.1. Preparation Methods.- 7.2.2. Physical Properties.- 7.2.3. Chemical Properties.- 7.3. Organosilicon Derivatives of Sulfur-Containing Heterocyclic Compounds.- 7.3.1. Preparation Methods.- 7.3.2. Physical Properties.- 7.3.3. Chemical Properties.- 7.4. Compounds Containing the Groupings Si-(C)n -SCN and Si-(C)n - NCS (Organosilicon Thiocyanates and Isothiocyanates).- 7.4.1. Preparation Methods.- 7.4.2. Physical Properties.- 7.4.3. Chemical Properties.- 7.5. Organosilicon Sulfonic Acids and Their Derivatives.- 7.5.1. Preparation Methods.- 7.5.2. Physical Properties.- 7.5.3. Chemical Properties and Application.- 8. Compounds Containing the Groupings Si-(C)n -O-S and Si-O-(C)n - S.- 8.1. Preparation Methods.- 8.2. Physical and Chemical Properties.- 9. Organosilicon Compounds of Sulfur Containing Inorganic Elements and Phosphorus.- Literature Cited in Chapter 2.- 1. Publications of Soviet Authors.- 2. Publications of Foreign Authors.- 3. Supplement to Literature for Chapter II.