Multicomponent Interfacial Transport

Described by the Square Gradient Model during Evaporation and Condensation
Buch | Hardcover
XVIII, 174 Seiten
2011 | 2011
Springer Berlin (Verlag)
978-3-642-15265-8 (ISBN)
106,99 inkl. MwSt
This excellent and novel scientific work has given an area of key research a significant step forward. The systematic documentation of the approach to describing phase transitions will facilitate further applications of the theory to important problems.

A thermodynamically consistent description of the transport across interfaces in mixtures has for a long time been an open issue. This research clarifies that the interface between a liquid and a vapor in a mixture is in local equilibrium during evaporation and condensation. It implies that the thermodynamics developed for interfaces by Gibbs can be applied also away from equilibrium, which is typically the case in reality. A description of phase transitions is of great importance for the understanding of both natural and industrial processes. For example, it is relevant for the understanding of the increase of CO2 concentration in the atmosphere, or improvements of efficiency in distillation columns. This excellent work of luminescent scientific novelty has brought this area a significant step forward. The systematic documentation of the approach will facilitate further applications of the theoretical framework to important problems.

Introduction.- Equilibrium square gradient model.- Non-equilibrium continuous description.- Numerical solution for the binary mixture.- Local equilibrium of the Gibbs surface for the two-phase.- Binary mixture.- From continuous to discontinuous description.- Surface transfer coefficients for the binary mixture.- Integral relations for the surface transfer coefficients.- Conclusions and perspectives.

Erscheint lt. Verlag 27.1.2011
Reihe/Serie Springer Theses
Zusatzinfo XVIII, 174 p.
Verlagsort Berlin
Sprache englisch
Maße 155 x 235 mm
Gewicht 425 g
Themenwelt Naturwissenschaften Chemie Physikalische Chemie
Schlagworte Analytical description of the interface/surface • evaporation and condensation • Heat and mass transport through the interface/surf • Heat and mass transport through the interface/surface • Non-equilibrium Gibbs surface • non-equilibrium thermodynamics • Phase separation at the interface/surface
ISBN-10 3-642-15265-1 / 3642152651
ISBN-13 978-3-642-15265-8 / 9783642152658
Zustand Neuware
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