Spatial-Energy Principles of the Processes for Complex Structure Formation
VSP International Science Publishers (Verlag)
978-90-6764-423-5 (ISBN)
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The methodology developed by the author and presented in this book is aimed at evaluation of formation processes for complex, multi-component systems and is based on the understanding of spatial-energy parameter (P-parameter). Such a criterion is introduced when analyzing several physical and chemical regularities, including Lagrangian equations and consideration of the most important atomic characteristics. Specific application of such an approach to estimate the degree and direction of structural intercations, phase-formation processes, isomorphism and solubility in numerous systems, including molecular ones, is given. In particular, the distribution of phases and boundary layers in multi-component conglomerate of polymeric composite is analyzed.
The monograph contains a lot of methodological, computation and informative material to be used in practical science in the process of theoretical studies and research of structural interactions in condensed systems.
Grigory A. Korablev, Dr.Chem.Sc. (2004, Institute of Applied Mechanics, UrD, RAS, Izhevsk), Professor of Physics Department at Izhevsk State Agricultural Academy, Scientific advisor at Basic research-educational center, UrD, RAS. Latest publications in journals Chemical physics and mesoscopy (2004-2005).
Preface
Introduction
Chapter 1. Problems of isomorphism and phase-formation
Chapter 2. Spatial-energy parameter (P-parameter)
Chapter 3. Experimental evidence of spatial-energy criterion of isomorphism and solubility
Chapter 4. Temperature characteristics of solid solution expansion with the help of P-parameter (at given temperature)
Chapter 5. Spatial-energy criterion of compound formation
Chapter 6. Other applications of P-parameter in inorganic chemistry and chemistry of solids
Chapter 7. Kinetics and phase-formation in fast physic-chemical processes
Conclusion
General conclusions
References
Appendix I. P-parameter additive properties
Appendix II. Isomorphism of elementary systems
Appendix III. P0-parameters of valence orbitals of neutral atoms in basic state (calculated via atom ionization energy)
Appendix IV. P-parameters of some atoms calculated via electron bond energy according to Fischer
Appendix V. Calculations of P0-parameters of some atoms using electron bond energy by ESCA
Appendix VI. Calculations of errors when estimation solubility of components using Parameter method
Appendix VII. Methods of experiments conducted for determining the solubility boundaries of complex system components
Appendix VIII. Analog comparisons of Lagrangian and Hamilton functions with spatial-energy parameter
Erscheint lt. Verlag | 18.4.2005 |
---|---|
Verlagsort | Zeist |
Sprache | englisch |
Gewicht | 799 g |
Themenwelt | Mathematik / Informatik ► Mathematik ► Analysis |
Naturwissenschaften ► Chemie ► Physikalische Chemie | |
ISBN-10 | 90-6764-423-4 / 9067644234 |
ISBN-13 | 978-90-6764-423-5 / 9789067644235 |
Zustand | Neuware |
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