Physical Chemistry of Polyelectrolyte Solutions, Volume 158

MITSURU NAGASAWA, PhD, is Professor Emeritus of Nagoya University, Japan. He has served as Honorary President of the Toyota Technological Institute since 2010. His accolades include the Japan Academy Award (1977). STUART A. RICE, PhD,received his master’s degree and doctorate from Harvard University and was a junior fellow at Harvard for two years before joining the faculty of The University of Chicago in 1957, where he is currently the Frank P. Hixon Distinguished Service Professor Emeritus. AARON R. DINNER, PhD,received his bachelor’s degree and doctorate from Harvard University, after which he conducted postdoctoral research at the University of Oxford and the University of California, Berkeley. He joined the faculty at The University of Chicago in 2003.

Preface to the Series vii

Preface ix

Introductory Remarks 1

Thermodynamic Properties of Polyelectrolyte Solutions 21

Ionization Equilibrium and Potentiometric Titration of Weak

Polyelectrolytes 67

Molecular Conformation of Linear Polyelectrolytes 115

Radius of Gyration and Intrinsic Viscosity of Linear

Polyelectrolytes 153

Transport Phenomena of Linear Polyelectrolytes 193

Ion-Binding 241

Author Index 277

Subject Index 281