Principles of Inorganic Materials Design (eBook)

eBook Download: PDF
2005 | 1. Auflage
440 Seiten
John Wiley & Sons (Verlag)
978-0-471-71488-0 (ISBN)

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Principles of Inorganic Materials Design - John N. Lalena, David A. Cleary
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A unique interdisciplinary approach to inorganic materials
design

Textbooks intended for the training of chemists in the inorganic
materials field often omit many relevant topics. With its
interdisciplinary approach, this book fills that gap by presenting
concepts from chemistry, physics, materials science, metallurgy,
and ceramics in a unified treatment targeted towards the chemistry
audience. Semiconductors, metal alloys and intermetallics, as well
as ceramic substances are covered. Accordingly, the book should
also be useful to students and working professionals in a variety
of other disciplines.

This book discusses a number of topics that are pertinent to the
design of new inorganic materials but are typically not covered in
standard solid-state chemistry books. The authors start with an
introduction to structure at the mesoscopic level and progress to
smaller-length scales. Next, detailed consideration is given to
both phenomenological and atomistic-level descriptions of transport
properties, the metal-nonmetal transition, magnetic and dielectric
properties, optical properties, and mechanical properties. Finally,
the authors present introductions to phase equilibria, synthesis,
and nanomaterials.

Other features include:

* Worked examples demonstrating concepts unfamiliar to the
chemist

* Extensive references to related literature, leading readers to
more in-depth coverage of particular topics

* Biographies introducing the reader to great contributors to the
field of inorganic materials science in the twentieth century

With their interdisciplinary approach, the authors have set the
groundwork for communication and understanding among professionals
in varied disciplines who are involved with inorganic materials
engineering. Armed with this publication, students and researchers
in inorganic and physical chemistry, physics, materials science,
and engineering will be better equipped to face today's complex
design challenges. This textbook is appropriate for senior-level
undergraduate and graduate course work.

JOHN N. LALENA, PhD, is a private consultant. He was formerly a senior research scientist for Honeywell Electronic Materials, and a semiconductor fabrication process/product engineer for Texas Instruments. He also has served as a visiting professor of chemistry at Gonzaga University. DAVID A. CLEARY, PhD, is Professor of Chemistry and Chair of the Department of Chemistry at Gonzaga University. His courses have included physical chemistry and solid-state chemistry. His research interests range from nonlinear optical materials to chemical sensors and ionic conductors.

Foreword.

Preface.

1. The Mesoscale.

1.1 Interfaces in Polycrystals.

1.2 Solidified Metals and Alloys.

1.3 Ceramic Powder Aggregates.

1.4 Thin-Film Microstructure.

2. Crystal Structure and Bonding.

2.1 Structure Description Methods.

2.2 Cohesive Forces in Solids.

2.3 Structural Energetics.

2.4 Common Structure Types.

2.5 Structural Disturbances.

2.6 Structural Control and Synthetic Strategies.

3. The Electronic Level, I: An Overview of Band
Theory.

3.1 The Many-Body Schro¨dinger Equation.

3.2 Bloch's Theorem.

3.3 Reciprocal Space.

3.4 A Choice of Basis Sets.

3.5 Understanding Band-Structure Diagrams.

3.6 Breakdown of the Independent Electron Approximation.

3.7 Density Functional Theory: An Alternative to the
Hartree-Fock Approach.

4. The Electronic Structure, II: The Tight-Binding
Approximation.

4.1 The General LCAO Method.

4.2 Extension of the LCAO Method to Crystalline Solids.

4.3 Orbital Interactions in Monatomic Solids.

4.4 Tight-Binding Assumptions.

4.5 Qualitative LCAO Band Structures.

4.6 Total Energy Tight-Binding Calculations.

5. Transport Properties.

5.1 An Introduction to Tensors.

5.2 Thermal Conductivity.

5.3 Electronic Conductivity.

5.4 Atomic Transport.

6. Metal-Nonmetal Transitions.

6.1 Correlated Systems.

6.2 Anderson Localization.

6.3 Experimentally Distinguishing Electron Correlation from
Disorder.

6.4 Tuning the Metal-Nonmetal Transition.

6.5 Other Types of Electronic Transitions.

7. Magnetic and Dielectric Properties.

7.1 Macroscopic Magnetic Behavior.

7.2 Atomic Origin of Paramagnetism.

7.3 Spontaneous Magnetic Ordering.

7.4 Magnetotransport Properties.

7.5 Magnetostriction.

7.6 Dielectric Properties.

8. Optical Properties of Materials.

8.1 Maxwell's Equations.

8.2 Refractive Index.

8.3 Absorption.

8.4 Nonlinear Effects.

8.5 Summary.

9. Mechanical Properties.

9.1 Basic Definitions.

9.2 Elasticity.

9.3 Plasticity.

9.4 Fracture.

10. Phase Equilibria, Phase Diagrams, and Phase
Modeling.

10.1 Thermodynamic Systems, Phases, and Components.

10.2 The First and Second Laws of Thermodynamics.

10.3 Understanding Phase Diagrams.

10.4 Experimental Phase-Diagram Determinations.

10.5 Phase-Diagram Modeling.

11. An Introduction to Nanomaterials.

11.1 History of Nanotechnology.

11.2 Properties of Matter at the Nanoscale.

12. Synthetic Strategies.

12.1 Synthetic Strategies.

12.2 Summary.

Index.

"...very insightful and would serve as a text for graduate
students in physics, chemistry, or materials sciences. Researchers
in these fields would benefit by owning this book." (Materials
and Manufacturing Processes, February 2006)

"...an excellent resource for libraries supporting programs
in chemistry, materials science, and solid-state science. It can
also be an effective resource for senior undergraduate and gradate
course work." (CHOICE, October 2005)

Erscheint lt. Verlag 13.5.2005
Sprache englisch
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
Technik Maschinenbau
Schlagworte Anorganische Chemie • construction materials • Konstruktionswerkstoffe • Materials Science • Materials Science Special Topics • Materialwissenschaften • Spezialthemen Materialwissenschaften
ISBN-10 0-471-71488-7 / 0471714887
ISBN-13 978-0-471-71488-0 / 9780471714880
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