New Developments in Selective Oxidation (eBook)

Front Cover 1
New Development in Selective Oxidation 4
Copyright Page 5
Contents 6
Preface 14
International Advisory Board, Organizing Committee and Financial Support 15
Part I: Prospectives in Selective Liquid-Phase Oxidation with H2O2 and O2 16
Chapter 1. Catalytic oxidations in the manufacture of fine chemicals 16
Chapter 2. Selective oxidation with Ti-Silicalite 48
Chapter 3. Cyclohexanone ammoximation: a break-through in the 6-caprolactam production process 58
Chapter 4. Modified zeolites for oxidation reactions 68
Chapter 5. Mn(III)-tetraarylporphyrins bearing a covalently anchored axial ligand: efficient catalysts in olefin epoxidations under two-phase conditions 78
Chapter 6. Alkene epoxidation with hydrogen peroxide catalyzed by metalloporphyrins 86
Chapter 7. Use of bimetallic systems for the selective oxidation of olefins with hydrogen peroxide 96
Chapter 8. Platinum catalysts for cyclohexene epoxidation with an oxygen- hydrogen mixture 104
Chapter 9. Selective oxidation of alcohols to carbonyl compounds by manganese (III) µ-0X0 carboxylato complexes 112
Chapter 10. Selective oxidations catalyzed by dioxo(porphyrinato) Ru(VI) species Rajnpnkse. 124
Chapter 11. Ruthenium (ll) catalysts for the homogeneous oxygenation of aliphatic hydrocarbons and ethers 134
Chapter 12. Direct conversion of benzene to phenols under ambient conditions 140
Chapter 13. A novel and effective oxygenation of 2,3,6-trimethylphenol to trimethyl-p-benzoquinone by dioxygen with copper(II) chloridelamine hydrochloride system catalyst 148
Chapter 14. Phenol oxidation with molecular O2 in the presence of metallic copper 154
Chapter 15. Platinum catalyzed oxidation of 5-hydroxymethylfurfural 162
Chapter 16. The use of precious metal catalysts supported on activated carbon in oxidation reactions for the synthesis of fine chemicals, especially for the selective oxidation of glucose to gluconic acid 174
Chapter 17. Liquid-phase oxidation of hydrocarbons and alcohols catalyzed by heterogeneous palladium and platinum catalysts 184
Chapter 18. Catalytic oxidation of 1-alkenes with molecular oxygen and palladium nitro complexes 192
Chapter 19. Selective cyclohexane oxidation catalyzed by the GIF system 200
Chapter 20. Metallonporplhyrin-catalyzed oxidation of cyclohexane with dioxygen 210
Chapter 21. Oxometalates and dioxygen in catalytic oxidation 220
Chapter 22. 1H NMR study of the mechanism of ethyleneglycol monoacetate formation in oxidative acetoxylation of ethylene catalyzed by Pd(II) complexes 228
Chapter 23. Perspective in improvement of selectivity in liquid phase oxidation by dioxygen. New models of enzymatic oxidation 236
Part II: Nontraditional Approaches to Reactions of Heterogeneous Selective Oxidation 244
Chapter 24. Catalytic nitroxidation of aliphatic and aromatic hydrocarbons by NO 244
Chapter 25. Selective oxidation of hydrocarbons by nitric oxide to nitriles 254
Chapter 26. Selective oxidation of anthracene 262
Chapter 27. Vopour-phase oxidation of a-methylstyrene to phenylacrolein 272
Chapter 28. Partial oxidation of o-xylene to phthalic anhydride in a structured fixed bed containing a sequence of catalysts 282
Chapter 29. YBa2Cu3O6 - A selective ammoxidation catalyst 290
Chapter 30. Catalytic properties of the high-temperature superconductor Y-Ba-Cu-Ag-O towards the oxidation of methanol 302
Chapter 31. Selective oxidation of propylene over rare earth-molybdate catalysts 310
Chapter 32. Oxyesterification of methanol to methylformate over V-Ti oxide catalysts 320
Chapter 33. Oxidative transformation of methanol to higher aldehydes over zeolite-oxide catalysts 332
Chapter 34. Tin-germanium phosphates as selective catalysts for the oxidative dehydrogenation of ethylbenzene to styrene 342
Part III: Advances in C1-C5 Alkane Selective Transformation 350
Chapter 35. Selective photochemical conversion of methane into worthier compounds 350
Chapter 36. Working principle of Li-doped MgO applied for the oxidative coupling of methane 358
Chapter 37. Investigations on the heterogeneously catalyzed oxidative coupling of methane over alkali doped metal oxides 368
Chapter 38. Oxidative coupling of methane over LnLiO2 Catalysts. (Ln = Sm, Nd, La). Promoting effect of MgO and CaO 380
Chapter 39. Behavior of metallic oxides supported on Li/MgO in the methane oligomerization 388
Chapter 40. Oxidative coupling of methane, the effect of gas composition and process conditions 396
Chapter 41. Role of some experimental parameters in the catalytic conversion of methane by oxidative coupling 408
Chapter 42. Models of the direct catalytic partial oxidation of light alkanes 420
Chapter 43. General mechanism for the oxidative coupling of methane 432
Chapter 44. The mechanism of the oxidative coupling of methane: evidence that ethylene is a primary product 442
Chapter 45. Heterolytic mechanism of methane activation in oxidative dehydrodimerization 452
Chapter 46. SERS - In-situ study of the surface species formed in methane oxidative coupling 462
Chapter 47. In-situ studies of the oxidative coupling of methane over Li-Ni-O catalysts 468
Chapter 48. Selective oxidation of methane to formaldehyde at ambient pressure: the role of dopants in determining optimum carrier loading for the molybdena/silica system 474
Chapter 49. Oxidative dimerizatwn of methane in high temperature eletrochemical devices 484
Part IV: C2-C3 Alkane Selective Oxidation 492
Chapter 50. Selective dehydrogenation of ethane by CO2 over Fe-Mn oxide catalyst. An in-situ study of catalyst phase composition and structure 492
Chapter 51. Role of active oxygen forms and acidity in oxidative conversion of ethane on zeolites 498
Chapter 52. Selective oxidation of propane to acrolein and ammoxidation to acrylonitrile over Ag-doped bismuth vanadomolybdate catalysts 506
Chapter 53. Oxidative dehydrogenation of alkanes over alkali and alkaline earth orthovanadates 520
Chapter 54. Propane ammoxidation on V-antimnate based mixed oxide 530
Chapter 55. Selective catalytic oxidation of propane by sulphur dioxide 542
Part V: n-Butane niid n-Pentane Oxidation 552
Chapter 56. Fluidized bed oxidation of n-butane: a new commercial process for maleic anhydride 552
Chapter 57. Butane oxidation in a transport bed reactor -Redox characteristics of the vanadium phosphorus oxide catalyst 568
Chapter 58. Reactivity and structure of vanadyl pyrophosphate as a butane oxidation catalyst 578
Chapter 59. investigation of active and selective oxygen in V-P-O catalysts for n-butane conversion to maleic anhydride 588
Chapter 60. Comparative study of structure-sensitive oxidations of n-butane and I-butene in maleic anhydride on two kinds of catalysts 600
Chapter 61. Identification of a catalytically active copper oxychloride phase for the synthesis of maleic anhydride 610
Chapter 62. Selective oxidation of n-butane to maleic anhydride over well-characterized vanadium-phosphorus mixed oxide 620
Chapter 63. Product distribution in the V-P-O catalyst bed and an effect of reaction products on the catalyst in C4 oxidation 632
Chapter 64. A dynamic model of the oxidation of n-butane and I -butene on various crystalline faces of (VO)2P2O7 640
Chapter 65. Oxi-condensation of n-pentane to phthalic anhydride: a new type of heterogeneous oxidation reaction 650
Part VI: Electro- and Photo-Oxidation 658
Chapter 66. Non-faradaic electrochemical modification of catalytic activity: partial oxidation of C2H4 on Ag and CH4OH on Pt 658
Chapter 67. Electrogenerative oxidation of ethanol on platinized-carbon electrodes 668
Chapter 68. Oxidation of L-phenylalanine and related reactions: preparation of L-DOPA 676
Chapter 69. Selective electrooxidation of 4 - (di-n1-propylsulfamyl)toluene to 4 di-n- propylsulfamyl)benzoic acid 682
Chapter 70. Photocatalytic oxidations at room temperature in various media 690
Chapter 71. Dynamic studies of photocatalytic oxidation of C3H6 with O 2 on vanudim oxide supported on porous Vycor glass 698
Part VII: New Aspects of the Mechanism and Surface Reactivity of Selective Oxidation Catalysta 708
Chapter 72. On principles of catalyst choice for selective oxidation 708
Chapter 73. Mutual orientation of oxygen and hydrocarbon molecules as factor determining the reaction pathway 716
Chapter 74. Characterizing oxygen adspecies for ethylene epoxidation over silver with the TAP reactor system 722
Chapter 75. Ethylene oxdotion over a-alumina supported silver-gold catalysts 732
Chapter 76. Ethylene epoxidation on silver-based alloy catalysts 740
Chapter 77. Ethylene oxidation over hydrophobic thin layer catalysts 748
Chapter 78. The mechanism of alkene epoxidation and epoxide conversion on single crystal silver surfaces 754
Chapter 79. Active sites in propylene mild oxidation as studied on new [100] oriented MOO3 catalyst 762
Chapter 80. Effects of added SnO2, WO3 , MOO3 and a-Sb204 on the catalytic properties of BiMoO6 in selective oxidation of isobutene to methacrolein 772
Chapter 81. MoO3 on anatase and rutile low-surface-area TiO2: characterization andoxidaton of o-xyhne and butene-1 782
Chapter 82. The role of the distribution of double bondedoxygen on surface of V-Mo-O catalysts inselective oxidation of benzene to maleic anhydride 794
Chapter 83. Effect of promoters on activity and selectivity of benzene oxidation on V2O5 catalysts: study by well-defined V2O5 catalysts 804
Chapter 84. Cooperation between phases in mixed SnSbO selective oxidation catalysts 812
Chapter 85. IR spectroscopic identification of adsorbed surface species on oxidation catalysts exposed to propene and ethene in air 822
Chapter 86. Oxidation of propene and toluene on CoO-MgO solid solutions: a spectroscopic study 832
Chapter 87. FT-IR study of selective oxidation intermediates of benzene on the surface of vanadia-titania "monolayer" catalysts 840
Chapter 88. Proposal for active sites of iron phosphates in isobutyric oxidative dehydrogenation reaction 848
Chapter 89. Heteropolyacid catalysts for oxydehydrogenation of isobutyric acid: kinetics and deactivation 858
Chapter 90. A study of the catalytic oxydehydrogenation of ethylbenzene using nitrobenzene 868
Chapter 91. The adsorption of aliphatic nitrocompounds on oxides investigated by FT-IR spectroscopy 876
Chapter 92. The model of active centers for partial oxidation in the structure of heteropoly compounds 884
Author Index 896
Subject Index 900
Studies in Surface Science and Catalysis 904