Inorganic Syntheses V33

DIMITRI COUCOUVANIS, PhD, is Professor of Chemistry at the University of Michigan.

Chapter One. SYNTHESES OF SELECTED SUPRAMOLECULES. 1. Toward Magnetic Building Blocks: Synthesis of a Planar Co(III)?cation Radical?cobalt(III) Complex of the Binucleating Ligand 1,2,4,5--Tetrakis(2--hydroxy--2--methylpropanamido)benzene.2. A Luminescent Decanuclear Ruthenium(II) Polypyridine Complex: A Convergent Approach to a Dendritic Structure Employing the ??Complexes as Metals/Complexes as Ligands?? Synthetic Strategy.3. Dodecatungstoaluminic Acid and Its Monolacunary and Mixed--Addendum Derivatives.Supramolecular Complexes of BisBis(2,2'--bipyridine)osmium(II) and Ruthenium(II).5. Binuclear Oxomolybdenum?Metalloporphyrin Complexes.6. Iron Sandwich Polyoxoanion Compounds.7. Dipyrryl and Porphyrinic Precursors to Supramolecular Conjugated (Porphinato)metal Arrays: Syntheses of Dipyrrylmethane and (5,15--diphenylporphinato)zinc(II).8. Synthesis of Dodecaoxohexadecacarboxylatotetraaquo--dodecamanganese [Mn12 O12 (O2 CR)16 (H2 O)4 ] (R ? Me,Et,Ph,Cr) Complexes.9. Use of Picolinehydroximate Complexes in Preparation of Uranyl and Lanthanide 15--Metallacrown--5: UO2 (NO3 )2 [15--MCCu(II)N(pic)--15] and {Eu(NO3 )2 [15--MCCu(II)N(pic)--15]}NO3.10. Use of Salicyl-- and Naphthoylhydroximate Complexes in Preparation of Manganese and Copper 12--Metallacrown--4 Complexes: Mn(II)(Acetate)2 [Mn(III)(salicylhydroximate)]4 and (Tetramethylammonium)2 [Cu(II)5 (naphthoylhydroximate)4 ].Chapter Two. USEFUL REAGENTS AND LIGANDS.11. Homoleptic Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions.12. Synthesis of [M II (NCMe)6 ] 2 ? (M ? V,Cr,Mn,Fe,Co,Ni) Salts of Tetra[3,5--bis(trifluoromethyl)phenyl]borate.13. Transition Metal p--Toluenesulfonates.14. Salts of Binuclear Iron(II) and Iron(III) Dianions [(Fe2 Cl6 ) 2 and (Fe2 OCl6 ) 2 ].15. Tetraethylammonium--Tetrathioperrhenate Et4 N(ReS4 ).16. Large--Scale Synthesis of Methyltrioxorhenium (CH3 ReO3 ).17. 4,5--Diaminocatechol: A Useful Building Block in Synthesis of Multimetallic Complexes.18. A Convenient Synthesis of 1,5,9--Trithiacyclododecane (S3 C9 H18 ). Chapter Three. SOLID--STATE MATERIALS AND CLUSTERSP.19. Synthesis of Quaternary Selenophosphates using Molten Salt Fluxes: Rb8 Hg4 (Se2 )2 (PSe4 )4 ,K4 In2 (PSe5 )2 (P2 Se6 ), Rb4 Ti2 (P2 Se7 )(P2 Se9 )2 ,Rb4 U4 (Se)2 (Se2 )4 (PSe4 )4.20. Hydrothermal Synthesis of Sulfosalts: Ag3 AsS3 ,Ag3 SbS3 , Ag7 SbS6 ,Cu12 Sb4 S13 , CuInS2 , FeIn2 S4.21. Open--Framework Solids of the Vanadium Oxide?Phosphate System. 22. Sulfur--Bridged Incomplete Cubane--Type Molybdenum and Tungsten Aqua Ions.23. Sulfur--Bridged Cubane Type Mixed--Metal Clusters with Mo3 MS4 (M ? Fe,Co,Ni,Cu,In,Sn) and W3 NiS4 Cores.24. Molybdenum and Tungsten Clusters as Aqua Ions [M3 Q4 (H2 O)9 ] 4 ? (M ? Mo,W; Q ? S,Se) and Related Chalcogen--Rich Trinuclear Clusters.Chapter Four. COMPOUNDS OF GENERAL INTEREST.25. The Diphenylmethylenethiophosphinate (MTP) Ligand in Gold(I), Platinum(II), Lead(II), Thallium(I), and Mercury(II) Complexes, sym--Au2 (MTP)2 , (PPN)[Au(MTP)2 ], Au2 Pt(MTP)4 ,Au2 Pb(MTP)4 , AuTl(MTP)4 , Hg(MTP)2 , Hg(MTP)2 (AuCl)2 , and Hg II Au I (MTP)Au III Cl4.26. Mesityl--gold(I) Complexes.27. An Improved Synthesis of cis--Dithiocyanato--bis(4,4'--dicarboxy--2,2'--bpy) Ru(II) Sensitizer.28. Dimethylsulfoxide Complexes of Platinum(II): K[PtCl3 (Me2 SO)], cis--[PtCl2 L(Me2 SO)] (L ? Me2 SO,MeCN), [PtCl( --Cl)(Me2 SO)]2 , and [Pt(Me2 SO)4 ](CF3 SO3 )2.29. Tetrasulfur--tetranitride (S4 N4 ).30. Hydrotris(methimazolyl)borate.31. Arsenic(III)bromide.32. Dichlorodioxo--bis(triphenylphosphine oxide)uranium(VI) [UO2 Cl2 (OPPh3 )2 ].33. Chlorohydro--tris(pyrazol--1--yl)borato--bis(triphenylphosphine) ruthenium(II) {RuCl[ 3 --HB(pz)](PPh3 )2 } (pz pyrazol--1--yl).34. Octacarbonyl--di-- --hydridodirhenium [Re2 ( --H)2 (CO)8 ].35. Zero--Valent Binuclear Nickel Complexes.36. Preparation of a Synthetic Ribonuclease: The Europium(III) Complex of 1--(4--nitrobenzyl)--4,7,10--Tris(carbamoylmethyl)--1,4,7,10-- tetraazacyclododecane.37. Carbonyl Halide Tungsten(II) Complexes of Tris(3,5--dimethylpyrazolyl)hydroborate.38. A Luminescent Complex of Re(I): fac--[Re(CO)3 (bpy)(py)](CF3 SO3 ) (bpy ? 2.2'--bipyridine; py=pyridine).39. RSi(OH)3 and RSi(NH2 )3 [R ? 2,6--iPr2 C6 H3 N(SiMe3 )]: Synthesis of Stable Organosilanes with Three Functional Groups.40. Fluorination with Me3 SnF: Synthesis of Cyclopentadienyl--Substituted Group 4 Metal Fluoride Complexes.41. Seven--Coordinate [MI2 (CO)3 (NCMe)2 ], [MI2 (CO)3 (NCMe)(PPh3 )], and Alkyne [MI2 (CO)(NCMe)( 2 --RC2 R)2 ] Complexes of Molybdenum(II) and Tungsten(II).42. Chlorothiocarbonyl--bis(triphenylphosphine)iridium(I) [IrCl(CS)(PPh3)2].Contributor Index. Subject Index.Formula Index.