Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules

Buch | Hardcover
X, 296 Seiten
2002 | 2002
Springer Berlin (Verlag)
978-3-540-41037-9 (ISBN)

Lese- und Medienproben

Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules - J. Demaison, H. Hübner, W. Hüttner, J. Vogt, G. Wlodarczak
2.664,30 inkl. MwSt
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Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. In addition, gas phase data have been included derived from methods related to microwave spectroscopy by employing a coherent radiation source. These are molecular beam techniques, radio frequency spectroscopy, electron resonance spectroscopy, laser spectroscopy, double resonance and saturation techniques. Some other methods are considered if the accuracy of the derived molecular parameters is comparable to that of microwave spectroscopy owing to a good statistics in the analysis of data, and no microwave data are available. Examples would be Fourier infrared spectroscopy or laser induced fluorescence.

The present subvolume II/24 C contains the parameters of diamagnetic molecules suited for the prediction of line splittings of rotational transitions caused by other than rotational-vibrational interactions. This includes external-field effects causing the removal of M-degeneracies. In detail, in II/24 C are listed the electric dipole moments (sometimes also static polarizability anisotropies in case the Stark effect was observed up to very high field strengths), the quadrupole coupling constants, the parameters drawn from the analysis of hindered rotation of methyl groups or other internal motions (potential barriers, moments of inertia of atomic groups), and magnetic interaction constants. The latter are meant to include zero-field parameters such as spin-rotation and direct nuclear spin-nuclear spin interaction strengths as well as Zeeman effect parameters.

Erscheint lt. Verlag 21.8.2002
Reihe/Serie Landolt-Börnstein: Numerical Data and Functional Relationships in Science and Technology - New Series
Molecules and Radicals
Zusatzinfo X, 296 p. With CD-ROM.
Verlagsort Berlin
Sprache englisch
Maße 193 x 270 mm
Gewicht 1180 g
Themenwelt Naturwissenschaften Physik / Astronomie Allgemeines / Lexika
Naturwissenschaften Physik / Astronomie Atom- / Kern- / Molekularphysik
Schlagworte asZeeman effect parameters • atoms • electric dipole moments • Hardcover, Softcover / Physik, Astronomie/Allgemeines, Lexika • HC/Physik, Astronomie/Allgemeines, Lexika • hindered rotation • line splittings • magnetic-interaction constants • Molecule • Molecules and Cluster • Physical Chemistry • quadrupole coupling constants • rotational constants • rotational transitions • Zeeman effect
ISBN-10 3-540-41037-6 / 3540410376
ISBN-13 978-3-540-41037-9 / 9783540410379
Zustand Neuware
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