Organometallic Chemistry (eBook)

Chapter 1: Theoretical Organometallic Chemistry; 1: Introduction; 2: s- and p-Block Metals; 3: d- and f-Block Metals; Chapter 2: Groups 1 and 11: The Alkali and Coinage Metals; 1: Alkali Metals; 2: Copper, Silver and Gold; Chapter 3: Group 2 (Be-Ba) and Group 12 (Zn-Hg); 1: Scope and Organisation of the Review; 2: Group 2; 3: Group 12; Chapter 4: Scandium, Yttrium and the Lanthanides; 1: Introduction; 2: New Compounds - Structure and Reactivity; 3: Theoretical Studies; 4: Gas Phase Chemistry; 5: Polymerization Catalysis; 6: Applications in Organic Synthesis; Chapter 5: Carboranes, Including Their Metal Complexes; 1: Introduction; 2: Theoretical and Computational Studies; 3: Carboranes; 4: Metallacarbaboranes; 5: Biological Carborane Chemistry and BNCT; 6: Crystal Engineered Supramolecular and Polymeric (Metalla)carborane Materials; Chapter 6: Group III - B, Al, Ga, In and Tl; 1: General; 2: Boron; 3: Aluminium; 4: Gallium; 5: Indium; 6: Thallium; Chapter 7: Group 14: Silicon, Germanium, Tin and Lead; 1: Overview; 2: Silylenes; 3: Germylenes, Stannylenes and Plumbylenes; 4: Multiple Bonds to Main Group Elements; 5: Homoaromatics and Related Copmpounds; 6: ?-Bonded Compounds; 7:Transition and Main Group Metal Complexes; Chapter 8: Group 15: Phosphorus, Arsenic, Antimony and Bismut; 1: Phosphorus; 2: Arsenic; 3: Antimony; 4: Bismuth; Chapter 9: Organo-Transition Metal Cluster Complexes; 1: Introduction; 2: General Reviews; 3: Spectroscopic Studies; 4: Theory; 5: Structural Studies; 6: Large Clusters; 7: Group 6; 8: Group 7; 9:Group 8; 10: Group 9; 11: Group 10; 12: Group 11; 13: Group 12; 14: Mixed Metal Clusters; Chapter 10: Complexes Containing Metal-Carbon ?-Bonds of the Groups Iron, Cobalt and Nickel, Including Carbenes and Carbynes; 1: Introduction; 2: Reviews and Articles of General Interest; 3: Metal-Carbon ?-Bonds Involving Group 8, 9 and 10 Metals; 4: Carbene and Carbyne Complexes of Groups 8, 9 and 10; Chapter 11: Reactions of Transition Metal ?-Complexes of Alkenes, Alkynes and Dienes; 1: Introduction; 2: Reviews; 3: Complexes Containing ?-Coordinated Alkenes; 4: Complexes Containing ?-Coordinated Alkynes; 5: Complexes Containing ?-Coordinated Dienes (Chain and Cyclic); 6: Bimetallic Complexes Containing ?-Coordinated Alkenes, Alkynes or Dienes; Chapter 12: Transition Metal Complexes of Cyclopentadienyl Ligands; 1: General Introduction; 2: Main Group, Lanthanides and Actinides; 3: Titanium, Zirconium and Hafnium; 4: Vanadium, Niobium and Tantalum; 5: Chromium, Molybdenum and Tungsten; 6: Manganese, Rhenium and Technetium; 7: Iron, Ruthenium and Osmium; 8: Cobalt; 9: Nickel; Chapter 13: Organic Aspects of Organometallic Chemistry; 1: Introduction; 2: Methods for C-C Bond Formation; 3: Methods for C-X Bond Formation; 4: Metathesis Reactions; 5: Metal Mediated Cyclisation and Cycloisomerisation Reactions; 6: Metal Mediated Cycloadditions; 7: Pauson-Khand Type Reactions; 8: Nicholas Reactions