Chemistry of Iron, Cobalt and Nickel (eBook)
199 Seiten
Elsevier Science (Verlag)
978-1-4831-4643-0 (ISBN)
The Chemistry of Iron, Cobalt and Nickel deals with the chemistry of iron, cobalt, and nickel and covers topics ranging from the occurrence and distribution of all three elements to their properties, allotropy, and analytical chemistry. Compounds of iron, cobalt, and nickel in both low and high oxidation states are also discussed. This book is divided into three sections and begins with the history of iron, along with its occurrence and distribution, allotropy, and preparation and industrial production. The nuclear, physical, and chemical properties of iron, as well as the biological importance of iron compounds, are also considered. Compounds of iron are discussed, including carbonyls and nitric oxide complexes. The next two sections deal with the history, occurrence and distribution, allotropy, analytical chemistry, and preparation and industrial production of cobalt and nickel, along with their nuclear, physical, and chemical properties. Compounds of cobalt and nickel are examined, from carbonyls and nitrosyls to cyanides and organometallic compounds. This monograph will be a useful resource for inorganic chemists.
Front Cover 1
The Chemistry of Iron, Cobalt and Nickel 4
Copyright Page 5
Table of Contents 6
PREFACE 8
INDEX 10
PART 40:
14
CHAPTER 1. THE ELEMENT 14
1.1. HISTORY 14
1.2. OCCURRENCE AND DISTRIBUTION 14
1.3. IRON AND STEEL MANUFACTURE 15
1.4. PREPARATION OF PURE IRON 17
1.5. ALLOTROPY OF IRON 17
1.6. NUCLEAR PROPERTIES 18
1.7. PHYSICAL PROPERTIES 19
1.8. CHEMICAL PROPERTIES 20
1.9. BIOLOGICAL IMPORTANCE OF IRON COMPOUNDS
21
1.10. ANALYTICAL CHEMISTRY OF IRON 22
1.11. ALLOYS OF IRON 23
CHAPTER 2. COMPOUNDS OF IRON IN LOW OXIDATION STATES ( -2 , -1 , 0, +1) 24
2.1. IRON CARBONYLS 24
2.2. NITRIC OXIDE COMPLEXES OF IRON 35
2.3. OTHER COMPOUNDS OF IRON IN LOW OXIDATION STATES 40
CHAPTER 3. COMPOUNDS OF IRON (II) 40
3.1. GENERAL AND REDOX CONSIDERATIONS 40
3.2. SIMPLE SALTS OF IRON(II) 42
3.3. ORGANOMETALLIC COMPOUNDS OF IRON 46
3.4. COMPLEXES OF IRON(II) 61
CHAPTER 4. COMPOUNDS OF IRON(III) 73
4.1. SIMPLE COMPOUNDS AND SALTS OF IRON(III) 73
4.2. COMPLEX COMPOUNDS OF IRON(III) 77
4.3. ELECTRONIC STRUCTURES OF IRON(III) COMPLEXES 83
CHAPTER 5. COMPOUNDS OF IRON IN HIGH OXIDATION STATES (+4, +5, +6) 84
5.1. IRON(IV) COMPOUNDS 84
5.2. IRON(V) COMPOUNDS 85
5.3. IRON(VI) COMPOUNDS 85
PART
88
CHAPTER 1. THE ELEMENT 88
1.1. HISTORY 88
1.2. OCCURRENCE AND DISTRIBUTION 88
1.3. INDUSTRIAL PRODUCTION OF COBALT 88
1.4. ALLOTROPY OF COBALT 89
1.5. NUCLEAR PROPERTIES
89
1.6. PHYSICAL PROPERTIES 90
1.7. CHEMICAL PROPERTIES 91
1.8. BIOLOGICAL IMPORTANCE OF COBALT COMPOUNDS 91
1.9. THE ANALYTICAL CHEMISTRY OF COBALT 92
1.10. ALLOYS OF COBALT 93
CHAPTER 2. COMPOUNDS OF COBALT IN LOW OXIDATION STATES ( -1 , 0 , +1) 94
2.1. COBALT CARBONYLS 94
2.2. COBALT NITROSYLS 99
2.3. OTHER COMPLEXES OF COBALT IN LOW OXIDATION STATES 102
CHAPTER 3. COMPOUNDS OF COBALT(II) 103
3.1. GENERAL AND REDOX CONSIDERATIONS 103
3.2. SIMPLE COMPOUNDS OF COBALT(II) 104
3.3. ORGANOMETALLIC COMPOUNDS OF COBALT 108
3.4. COMPLEXES OF COBALT(II) 115
CHAPTER 4. COMPOUNDS OF COBALT(III) 128
4.1. SIMPLE COMPOUNDS AND SALTS OF COBALT(III) 128
4.2. COMPLEX COMPOUNDS OF COBALT(III) 130
CHAPTER 5. COMPOUNDS OF COBALT IN HIGH OXIDATION STATES (+4, +5) 142
PART 42:
144
CHAPTER 1. THE ELEMENT 144
1.1. HISTORY
144
1.2. OCCURRENCE AND DISTRIBUTION 144
1.3. INDUSTRIAL PRODUCTION OF NICKEL 145
1.4. PREPARATION OF PURE NICKEL 145
1.5. NUCLEAR PROPERTIES 146
1.6. PHYSICAL PROPERTIES 146
1.7. CHEMICAL PROPERTIES 147
1.8. ANALYTICAL CHEMISTRY 148
1.9. ALLOYS OF NICKEL 149
CHAPTER 2. COMPOUNDS OF NICKEL IN LOW OXIDATION STATES ( -1, 0, +1) 150
2.1. NICKEL CARBONYL, Ni(CO) 150
2.2. NICKEL NITROSYLS30 154
2.3. COMPLEX CYANIDES AND ISOCYANIDES 156
2.4. PHOSPHINE COMPLEXES 158
CHAPTER 3. COMPOUNDS OF NICKEL(II) 159
3.1. GENERAL AND REDOX CONSIDERATIONS 159
3.2. SIMPLE COMPOUNDS OF NICKEL(II) 160
3.3. ORGANOMETALLIC COMPOUNDS OF NICKEL
166
3.4. COMPLEXES OF NICKEL(II) 174
CHAPTER 4. COMPOUNDS OF NICKEL IN HIGH OXIDATION STATES ( +3, +4) 194
4.1. SIMPLE COMPOUNDS OF NICKEL(III) AND NICKEL(IV) 194
4.2. COMPLEXES OF NICKEL(III) 195
4.3. COMPLEXES OF NICKEL(IV) 195
INDEX 10
Contents of Comprehensive Inorganic Chemistry 198
INDEPENDENT OPINION 200
| Erscheint lt. Verlag | 2.10.2013 |
|---|---|
| Sprache | englisch |
| Themenwelt | Naturwissenschaften ► Chemie ► Anorganische Chemie |
| Technik | |
| ISBN-10 | 1-4831-4643-X / 148314643X |
| ISBN-13 | 978-1-4831-4643-0 / 9781483146430 |
| Haben Sie eine Frage zum Produkt? |
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